Fabrication of conductive human bio-nanoelectrode from graphene oxide modified with polyvinyl alcohol.

It is time for electrodes prepared from graphene oxide (GO) to replace the traditional electrodes. However, GO is an electrically insulating material. However, in this study, a conductive electrode was prepared from GO modification with glycerol (GL) under the esterification reaction at 90°C for 3 h with sulphuric acid as a catalyst under vacuum conditions. Polyvinyl alcohol (PVA) acts as a polymer host. It was mixed with GO and modification was carried out under heating conditions. The mixture of the GO/GL/PVA nanocomposite was rapidly cooled and poured into the electrode mould. Finally, it is placed in a desiccator at room temperature for two days. The characterisation (Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy) proved that the ester bond was formed and a complete distribution of GO/GL into the matrix of PVA was verified. The GO/GL/PVA nanocomposite was tested for electrocardiogram (ECG) electrodes. The biopic instrument was used to compare the behaviour of the GO/GL/PVA plastic electrode and the commercial one. The results indicated that the GO/GL/PVA plastic electrode efficiently detected ECG signals after two months with high conductivity and lower noise than the commercial electrode. The GO/GL/PVA plastic electrode has been reported for the first time in the literature.

[1]  R. Weisman,et al.  Handbook of Carbon Nanomaterials , 2019, World Scientific Series on Carbon Nanoscience.

[2]  Mohamed Salah,et al.  Biosensor of Urine Analysis Based on Graphene Nano Sheet , 2018 .

[3]  A. Dimiev,et al.  New insights into the solubility of graphene oxide in water and alcohols. , 2017, Physical chemistry chemical physics : PCCP.

[4]  Jinlian Hu,et al.  Preparation and Property Evaluation of Conductive Hydrogel Using Poly (Vinyl Alcohol)/Polyethylene Glycol/Graphene Oxide for Human Electrocardiogram Acquisition , 2017, Polymers.

[5]  Flavio Pendolino,et al.  Graphene Oxide in Environmental Remediation Process , 2017 .

[6]  Wang Fang,et al.  Mechanical Properties of Graphene Oxide/Polyvinyl Alcohol Composite Film , 2017 .

[7]  M. Klüppel,et al.  Designing of Elastomer Nanocomposites: From Theory to Applications , 2017 .

[8]  Mahendra Rai,et al.  Nanotechnology for Bioenergy and Biofuel Production , 2017 .

[9]  L. Kong Carbon Nanomaterials Based on Graphene Nanosheets , 2016 .

[10]  S. Eigler,et al.  Graphene Oxide: Fundamentals and Applications , 2016 .

[11]  Chengmeng Chen Structural Evolution of the Thermally Reduced Graphene NanosheetsDuring Annealing , 2016 .

[12]  N. H. Hieu,et al.  Fabrication and Characterization of Graphene/Graphene Oxide-Based Poly(vinyl alcohol) Nanocomposite Membranes , 2016, Journal of Electronic Materials.

[13]  Chengmeng Chen Surface Chemistry and Macroscopic Assembly of Graphene for Application in Energy Storage , 2015 .

[14]  Maheshwar Sharon,et al.  Graphene : an introduction to the fundamentals and industrial applications , 2015 .

[15]  S. Kalia,et al.  Graphene-Based Polymer Nanocomposites in Electronics , 2015 .

[16]  J. Kauppila Graphene from Graphite by Chemical and Physical Techniques. , 2014 .

[17]  V. Georgakilas,et al.  Functionalization of graphene , 2014 .

[18]  Massimo Marcaccio,et al.  Making and Exploiting Fullerenes, Graphene, and Carbon Nanotubes , 2014, Topics in current chemistry.

[19]  Eila,et al.  Graphene Oxide Synthesized by using Modified Hummers Approach , 2014 .

[20]  V. Georgakilas,et al.  Functionalization of Graphene , 2012 .

[21]  C. Rao,et al.  Graphene : synthesis, properties ,and phenomena , 2012 .

[22]  A. Ahmad,et al.  Preparation and modification of poly (vinyl) alcohol membrane: Effect of crosslinking time towards its morphology , 2012 .

[23]  A. G. Kanani,et al.  Effect of chitosan-polyvinyl alcohol blend nanofibrous web on the healing of excision and incision full thickness wounds. , 2010, IET nanobiotechnology.

[24]  B. Bolto,et al.  Crosslinked poly(vinyl alcohol) membranes , 2009 .

[25]  Yan Wang,et al.  Molecular‐Level Dispersion of Graphene into Poly(vinyl alcohol) and Effective Reinforcement of their Nanocomposites , 2009 .

[26]  E. Berardesca,et al.  Glycerol — Just a Moisturizer? Biological and Biophysical Effects , 2005 .