Route of biofuel production from macadamia nut shells: effect of parameters on the particles mixing index in fluidized beds

Pyrolysis of macadamia nut shells (MNS) in a fluidized bed reactor has excellent potential to produce bio-oil. High heat transfer rates and uniform temperature in the fluidized bed can be achieved due to effective gas-solid contact in the reactor. However, binary mixtures can lead to the segregation of particles, which negatively affects heat and mass transfer in such a reactor. Therefore, a 2³ statistical experimental design was used to assess the effects of parameters (i.e., air velocity, particle diameter ratio, and mass fraction of MNS) on the mixing index of the bed of MNS and sand. Among the analyzed factors, only DMNS/DS and V/VMF influenced the mixing index (Im) within a confidence interval of 95%. Based on statistical data analysis, an air velocity 20% above the minimum fluidization and particle diameter ratio (DMNS/DS) smaller than 3 results in uniform particle mixing in the bed (i.e., reaching ideal mixing index values). Moreover, the experimental results indicate that fluidized be used for biofuel production from Macadamia nut Shells.

[1]  Siming You,et al.  Bioenergy generation from thermochemical conversion of lignocellulosic biomass-based integrated renewable energy systems , 2023, Renewable and Sustainable Energy Reviews.

[2]  M. Materazzi,et al.  Axial segregation behaviour of a reacting biomass particle in fluidized bed reactors: experimental results and model validation , 2023, Fuel.

[3]  Md Musleh Uddin Hasan,et al.  Modeling and process simulation of waste macadamia nutshell pyrolysis using Aspen Plus software , 2022, Energy Reports.

[4]  Jianren Fan,et al.  Multi-scale numerical simulation of fluidized beds: Model applicability assessment , 2022, Particuology.

[5]  K. Moustakas,et al.  Biomass-based micronutrient fertilizers and biofortification of raspberries fruits. , 2022, Environmental research.

[6]  Diunay Zuliani Mantegazini,et al.  PRODUÇÃO DE COMBUSTÍVEL A PARTIR DE RESÍDUOS DE EMBALAGENS TETRA PAK EM LEITO FLUIDIZADO: IDENTIFICAÇÃO DE FATORES QUE AFETAM A MISTURA DE PARTÍCULAS DE AREIA E COMPÓSITO PEBD/AL , 2021, Brazilian Journal of Production Engineering - BJPE.

[7]  Yansong Shen,et al.  Particle-scale study of heat and mass transfer in a bubbling fluidised bed , 2021 .

[8]  T. P. Xavier,et al.  REVIEW ON ADVANCED TECHNOLOGIES FOR ALUMINUM RECOVERY FROM CARTON PACKAGES WASTE USING PYROLYSIS , 2021 .

[9]  Uwe Riedel,et al.  On the characteristic heating and pyrolysis time of thermally small biomass particles in a bubbling fluidized bed reactor , 2020, Renewable Energy.

[10]  Jinsoo Kim,et al.  Hydrodeoxygenation of a bio-oil model compound derived from woody biomass using spray-pyrolysis-derived spherical γ-Al2O3-SiO2 catalysts , 2020 .

[11]  L. Massaro Sousa,et al.  On the performance of a spouted bed type device for feeding spent coffee grounds to a circulating fluidized bed reactor , 2020, Chemical Engineering Research and Design.

[12]  K. G. Santos,et al.  Particle segregation in spouted bed pyrolysis reactor: Sand-coconut shell and sand-cocoa shell mixtures , 2020 .

[13]  F. Johnsson,et al.  A novel experimental method for determining lateral mixing of solids in fluidized beds – Quantification of the splash-zone contribution , 2020, Powder Technology.

[14]  G. Lopez,et al.  Thermochemical routes for the valorization of waste polyolefinic plastics to produce fuels and chemicals. A review , 2017 .

[15]  D. Gidaspow,et al.  CFD modeling of conical spouted beds for processing LDPE/Al composite , 2016 .

[16]  M. A. Barrozo,et al.  Fluid dynamic analysis for pyrolysis of macadamia shell in a conical spouted bed , 2016 .

[17]  Pei Chen,et al.  Reed Black Liquor Combustion in Fluidized Bed for Direct Causticization with Limestone as Bed Material , 2016 .

[18]  Henrik Thunman,et al.  Production of Activated Carbon within the Dual Fluidized Bed Gasification Process , 2015 .

[19]  H. Tabrizi,et al.  Pulsating flow effect on the segregation of binary particles in a gas–solid fluidized bed , 2014 .

[20]  M. Bacelos,et al.  Analysis of conical spouted bed fluid dynamics using carton mixtures , 2013 .

[21]  N. Mostoufi,et al.  Effect of fines on segregation of binary mixtures in gas–solid fluidized beds , 2012 .

[22]  Javier Bilbao,et al.  Continuous pyrolysis of waste tyres in a conical spouted bed reactor , 2010 .

[23]  Javier Bilbao,et al.  Operating Conditions for the Pyrolysis of Poly-(ethylene terephthalate) in a Conical Spouted-Bed Reactor , 2010 .

[24]  M. Patterson,et al.  Fundamental aspects of biomass carbonisation. , 2007 .

[25]  S. Channiwala,et al.  A correlation for calculating HHV from proximate analysis of solid fuels , 2005 .

[26]  Javier Bilbao,et al.  Segregation in conical spouted beds with binary and ternary mixtures of equidensity spherical particles , 1994 .

[27]  R. Fox,et al.  Effect of particle shape on biomass pyrolysis in a bubbling fluidized bed , 2023, Fuel.

[28]  U. Lee,et al.  Role of biomass as low-carbon energy source in the era of net zero emissions , 2022, Fuel.

[29]  D. Gidaspow,et al.  CFD analysis of fluidized beds using wastes from post-consumer carton packaging , 2017 .

[30]  J. T. Freire,et al.  Stability of Spouting Regimes in Conical Spouted Beds with Inert Particle Mixtures , 2006 .