Industrial age anthropogenic inputs of heavy metals into the pedosphere

Abstract. Heavy metals have been increasingly released into our environment. We present here, for the first time, the global industrial age production of Cd, Cu, Cr, Hg, Ni, Pb, and Zn, and their potential accumulation and environmental effects in the pedosphere. World soils have been seriously polluted by Pb and Cd and slightly by Zn. The potential industrial age anthropogenic Pb, Hg, and Cd inputs in the pedosphere are 9.6, 6.1, and 5.2 times those in the lithosphere, respectively. The potential anthropogenic heavy metal inputs in the pedosphere increased tremendously after the 1950s, especially for Cr and Ni. In 2000, the cumulative industrial age anthropogenic global production of Cd, Cr, Cu, Hg, Ni, Pb, and Zn was 1.1, 105, 451, 0.64, 36, 235, and 354 million tonnes, respectively. The global industrial age metal burdens per capita (in 2000) were 0.18, 17.3, 74.2, 0.10, 5.9, 38.6, and 58.2 kg for Cd, Cr, Cu, Hg, Ni, Pb, and Zn, respectively. Acidification may increase the bioavailability and toxicity of heavy metals in the pedosphere. The improvement of industrial processing technology reducing the metal dispersion rate, the recycling of metal-containing outdated products, by-products and wastes, and the development of new substitute materials for heavy metals are possible strategies to minimize the effects of heavy metals on our environment.

[1]  J. Nriagu.  Global inventory of natural and anthropogenic emissions of trace metals to the atmosphere , 1979, Nature.

[2]  J. Nriagu,et al.  Quantitative assessment of worldwide contamination of air, water and soils by trace metals , 1988, Nature.

[3]  A. Banin,et al.  Global N2O cycles--terrestrial emissions, atmospheric accumulation and biospheric effects. , 1984, Advances in space research : the official journal of the Committee on Space Research.

[4]  S. Taylor.  The continental crust , 1985 .

[5]  D. Adriano.  Trace Elements in the Terrestrial Environment , 1986 .

[6]  S. Taylor,et al.  The continental crust: Its composition and evolution , 1985 .

[7]  H. Aubert,et al.  Trace elements in soils , 1978 .

[8]  D. Schindler,et al.  Interaction of acid rain and global changes: Effects on terrestrial and aquatic ecosystems , 1995 .

[9]  Christopher J. Zygarlicke,et al.  Mercury Speciation in Coal Combustion and Gasification Flue Gases , 1996 .

[10]  S. Norton,et al.  Summary of the Workshop on Peat Bog Archives of Atmospheric Metal Deposition , 1997 .

[11]  Lars Håkanson,et al.  Mercury in the Swedish environment — Recent research on causes, consequences and corrective methods , 1991 .

[12]  D. Keeney,et al.  Cadmium and zinc additions to wisconsin soils by commercial fertilizers and wastewater sludge application , 1975 .

[13]  I. Singh,et al.  Status of anthropogenically induced metal pollution in the Kanpur-Unnao industrial region of the Ganga Plain, India , 1999 .

[14]  B. E. Davies.  Applied soil trace elements , 1980 .

[15]  I. Renberg,et al.  Pre-industrial atmospheric lead contamination detected in Swedish lake sediments , 1994, Nature.

[16]  R. Brooks.  Pollution through Trace Elements , 1977 .

[17]  H. Bowen,et al.  The elemental constituents of soils , 1982 .

[18]  Chen Huamain,et al.  HEAVY METAL POLLUTION IN SOILS IN CHINA : STATUS AND COUNTERMEASURES , 1999 .

[19]  Sungmin Hong,et al.  Past and recent changes in the large-scale tropospheric cycles of lead and other heavy metals as documented in Antarctic and Greenland snow and ice: A review , 1994 .

[20]  Sungmin Hong,et al.  Greenland Ice Evidence of Hemispheric Lead Pollution Two Millennia Ago by Greek and Roman Civilizations , 1994, Science.

[21]  F. Han,et al.  Accumulation, distribution, and toxicity of copper in sediments of catfish ponds receiving periodic copper sulfate applications. , 2001, Journal of environmental quality.

[22]  T. Pačes.  Sources of acidification in Central Europe estimated from elemental budgets in small basins , 1985, Nature.

[23]  C. Patterson,et al.  Lead in albacore: guide to lead pollution in Americans. , 1980, Science.

[24]  M. Kirkham,et al.  Accumulation, Redistribution, Transport and Bioavailability of Heavy Metals in Waste-Amended Soils , 2001 .

[25]  T. Hutchinson,et al.  The effects of acid rainfall and heavy metal particulates on a boreal Forest ecosystem near the sudbury smelting region of Canada , 1977 .

[26]  Robert B. Finkelman,et al.  U.S. Geological Survey coal quality (COALQUAL) database; version 2.0 , 1997 .

[27]  Humphrey John Moule Bowen,et al.  Environmental chemistry of the elements , 1979 .

[28]  G. Wetherill,et al.  Identifying sources of lead contamination by stable isotope techniques , 1972 .

[29]  F. Han,et al.  Accumulation of heavy metals in a long-term poultry waste-amended soil , 2000 .

[30]  Joseph Lerner,et al.  Energy in the American economy, 1850-1975 : an economic study of its history and prospects , 1961 .

[31]  Rufus L. Chaney,et al.  Cadmium, Lead, Zinc, Copper, and Nickel in Agricultural Soils of the United States of America , 1993 .

[32]  M. McBride,et al.  Solubility and lability of cadmium and zinc in two soils treated with organic matter. , 2000 .