Alcohol-solvothermal syntheses, crystal structures and photocatalytic properties of tin selenides with polyselenide ligands

New polyselenidostannates with Se22− or Se42− polyselenide ligands, [TM(en)3]Sn3Se6(Se2) (1–3), [Ni(en)3]Sn3Se7.5 (4) and [TM(en)3][Sn(Se4)3] (5–8), were prepared by alcohol-solvothermal methods.

[1]  Wei Li,et al.  Growing crystalline selenidostannates in deep eutectic solvent , 2019, Inorganica Chimica Acta.

[2]  P. Sun,et al.  Solvothermal syntheses, crystal structures, and optical and thermal properties of transition metal selenidostannates , 2017, Transition Metal Chemistry.

[3]  Xiaoping Shen,et al.  Fe3O4‐Decorated Co9S8 Nanoparticles In Situ Grown on Reduced Graphene Oxide: A New and Efficient Electrocatalyst for Oxygen Evolution Reaction , 2016 .

[4]  Xiaoying Huang,et al.  Two novel selenidostannates from mixed structure-directing systems: the large ten-membered ring of [Sn3Se4] semicubes and the 3D [Sn4Se9]n(2n-) with multi-channels. , 2016, Dalton transactions.

[5]  C. Zheng,et al.  Solvothermal synthesis, structure and physical properties of Cs[Cr(en)2MSe4] (M = Ge, Sn) with [MSe4](4-) tetrahedra as chelating ligand. , 2016, Dalton transactions.

[6]  Xiaoying Huang,et al.  Synthesizing 2D and 3D Selenidostannates in Ionic Liquids: The Synergistic Structure-Directing Effects of Ionic Liquids and Metal-Amine Complexes. , 2016, Chemistry, an Asian journal.

[7]  A. Jindal,et al.  Synthesis and Characterization of ReS2 and ReSe2 Layered Chalcogenide Single Crystals , 2016 .

[8]  S. Dehnen,et al.  Synthesis of Crystalline Chalcogenides in Ionic Liquids. , 2016, Angewandte Chemie.

[9]  D. Scanlon,et al.  The electronic structure of sulvanite structured semiconductors Cu3MCh4 (M = V, Nb, Ta; Ch = S, Se, Te): prospects for optoelectronic applications , 2015 .

[10]  Qichun Zhang,et al.  Surfactants as Promising Media for the Preparation of Crystalline Inorganic Materials. , 2015, Angewandte Chemie.

[11]  T. Ding,et al.  Synthesis of Cu2SnSe3-Au heteronanostructures with optoelectronic and photocatalytic properties. , 2015, Nanoscale.

[12]  Z. Ismagilov,et al.  Nitrogen-doped carbon nanomaterials: To the mechanism of growth, electrical conductivity and application in catalysis , 2015 .

[13]  H. Alshareef,et al.  Self-templating Scheme for the Synthesis of Nanostructured Transition-Metal Chalcogenide Electrodes for Capacitive Energy Storage , 2015 .

[14]  C. Zheng,et al.  Synthesis, Structure, Multiband Optical, and Electrical Conductive Properties of a 3D Open Cubic Framework Based on [Cu8Sn6S24](z-) Clusters. , 2015, Inorganic chemistry.

[15]  Y. Surendranath,et al.  Metal Chalcogenide Nanofilms: Platforms for Mechanistic Studies of Electrocatalysis , 2015 .

[16]  Xiaoying Huang,et al.  Varied forms of lamellar [Sn3Se7]n(2n-) anion: the competitive and synergistic structure-directing effects of metal-amine complex and imidazolium cations. , 2015, Dalton transactions.

[17]  Bin Zhang,et al.  Nanoporous hollow transition metal chalcogenide nanosheets synthesized via the anion-exchange reaction of metal hydroxides with chalcogenide ions. , 2014, ACS nano.

[18]  M. Wasielewski,et al.  Enhanced photochemical hydrogen evolution from Fe4S4-based biomimetic chalcogels containing M2+ (M = Pt, Zn, Co, Ni, Sn) centers. , 2014, Journal of the American Chemical Society.

[19]  F. Wang,et al.  Novel one-, two-, and three-dimensional selenidostannates templated by iron(II) complex cation. , 2014, Inorganic chemistry.

[20]  C. Näther,et al.  Influence of the synthesis parameters onto nucleation and crystallization of five new tin-sulfur containing compounds. , 2014, Inorganic chemistry.

[21]  Qichun Zhang,et al.  New strategies to prepare crystalline chalcogenides , 2014 .

[22]  Ke-zhao Du,et al.  Assembly and structural transformation of organic-decorated manganese selenidostannates. , 2014, Dalton transactions.

[23]  Qichun Zhang,et al.  Surfactant-thermal method to synthesize a novel two-dimensional oxochalcogenide. , 2014, Chemistry, an Asian journal.

[24]  C. Näther,et al.  A new synthetic approach to force bond formation between a transition metal complex and a thiostannate anion: solvothermal synthesis and crystal structure of [Co2(cyclam)2Sn2S6]·2H2O , 2013 .

[25]  F. Wang,et al.  Clusters [Co(As3S3)2]2-, [Ni(As3S3)2]2-, and [{Co(en)}6(μ3-S)4(AsS3)4]2- with Co-As or Ni-As bonds: solvothermal syntheses and characterizations of thioarsenates containing transition-metal complexes. , 2013, Inorganic chemistry.

[26]  Qichun Zhang,et al.  Syntheses, crystal structures, and properties of two new one-dimensional heterometallic selenides: [DBNH]4[M3Sn4Se11(Se2)2] (M = Cd, Hg) , 2013 .

[27]  L. Mayrhofer,et al.  Changes in the structural dimensionality of selenidostannates in ionic liquids: formation, structures, stability, and photoconductivity. , 2013, Chemistry.

[28]  M. Kanatzidis,et al.  Lattice-matched transition metal disulfide intergrowths: the metallic conductors Ag2Te(MS2)3 (M = V, Nb). , 2013, Inorganic chemistry.

[29]  Qichun Zhang,et al.  Kinetically controlling phase transformations of crystalline mercury selenidostannates through surfactant media. , 2013, Inorganic chemistry.

[30]  A. Rogach,et al.  Narrow bandgap colloidal metal chalcogenide quantum dots: synthetic methods, heterostructures, assemblies, electronic and infrared optical properties. , 2013, Chemical Society reviews.

[31]  Qichun Zhang,et al.  Growing crystalline chalcogenidoarsenates in surfactants: from zero-dimensional cluster to three-dimensional framework. , 2013, Journal of the American Chemical Society.

[32]  Xiaoying Huang,et al.  From selenidostannates to silver-selenidostannate: structural variation of chalcogenidometallates synthesized in ionic liquids. , 2013, Chemical communications.

[33]  M. Kanatzidis,et al.  CsHgInS3: a New Quaternary Semiconductor for γ-ray Detection , 2012 .

[34]  S. Dehnen,et al.  Controlling the assembly of chalcogenide anions in ionic liquids: from binary Ge/Se through ternary Ge/Sn/Se to binary Sn/Se frameworks. , 2012, Chemistry.

[35]  S. Margadonna,et al.  Structure-properties correlations in Fe chalcogenide superconductors. , 2012, Chemical Society reviews.

[36]  Xiaoying Huang,et al.  Largest discrete supertetrahedral clusters synthesized in ionic liquids , 2012 .

[37]  S. Dehnen,et al.  "Zeoball" [Sn36Ge24Se132]24-: a molecular anion with zeolite-related composition and spherical shape. , 2012, Journal of the American Chemical Society.

[38]  C. Näther,et al.  New Thiostannates Synthesized Under Solvothermal Conditions: Crystal Structures of (trenH)2Sn3S7 and {[Mn(tren)]2Sn2S6} , 2012 .

[39]  Xiaoying Huang,et al.  Crystalline open-framework selenidostannates synthesized in ionic liquids. , 2011, Angewandte Chemie.

[40]  G. Guo,et al.  Different effects of a cotemplate and [(transition-metal)(1,10-phenanthroline)(m)]2+ (m = 1-3) complex cations on the self-assembly of a series of hybrid selenidostannates showing combined optical properties of organic and inorganic components. , 2011, Inorganic chemistry.

[41]  S. Dehnen,et al.  [BMIm]4[Sn9Se20]: ionothermal synthesis of a selenidostannate with a 3D open-framework structure. , 2011, Inorganic chemistry.

[42]  Jing Zhao,et al.  Solvothermal synthesis and characterization of polyselenidoarsenate salts of transition metal complex cations. , 2011, Inorganic chemistry.

[43]  J. Zhao,et al.  Solvothermal Syntheses, Crystal Structures, and Thermal Properties of the First Example of Selenidostannates with Mixed Ethylene Polyamine-Coordinated Transition Metal Complexes as Counterions , 2011 .

[44]  J. Zhao,et al.  Novel polyselenidoarsenate and selenidoarsenate: solvothermal synthesis and characterization of [Co(phen)3][As2Se2(μ-Se3)(μ-Se5)] and [Co(phen)3]2[As8Se14]. , 2011, Inorganic chemistry.

[45]  B. Seidlhofer,et al.  Review. Synthesis of Inorganic-Organic Hybrid Thiometallate Materials with a Special Focus on Thioantimonates and Thiostannates and in situ X-Ray Scattering Studies of their Formation , 2010 .

[46]  F. Weigend,et al.  Bistrimethylsilylamide transition-metal complexes as starting reagents in the synthesis of ternary Cd-Mn-Se cluster complexes. , 2010, Inorganic chemistry.

[47]  S. Kulinich,et al.  Photoinduced structural conversions of transition metal chalcogenide materials. , 2010, The journal of physical chemistry. A.

[48]  D. Mitzi,et al.  Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films. , 2009, Dalton transactions.

[49]  J. Dai,et al.  Solvothermal synthesis of Group 13–15 chalcogenidometalates with chelating organic amines , 2009 .

[50]  Yong Zhang,et al.  Hydrothermal syntheses and characterizations of thioarsenates [Fe(phen)3][As3S6] x dien x 7 H2O and [Mn2(phen)4(As2S5)] x phen x 2 H2O: a new coordination mode of the As2S5(4-) anion. , 2009, Inorganic chemistry.

[51]  M. Kanatzidis,et al.  Highly efficient and rapid Cs+ uptake by the layered metal sulfide K(2x)Mn(x)Sn(3-x)S(6) (KMS-1). , 2009, Journal of the American Chemical Society.

[52]  C. Näther,et al.  The Inorganic–Organic Hybrid Compound {[Mn(trien)]2SnS4}·4H2O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS4]4– Tetrahedron , 2009 .

[53]  Jian‐Qiang Wang,et al.  Polytellurides and Polyselenides – Compounds Containing $_{\infty}^{1}\rm [Te_{6}-Te_{4}]^{4-}$ and [Sn(Se4)3]2− Anions , 2008 .

[54]  C. Näther,et al.  Solvothermal Syntheses, Crystal Structures and Selected Optical Properties of [M(C8N5H23)]2Sn2S6 (M = Co, Fe, Ni; C8N5H23 = tetraethylenepentamine)† , 2008 .

[55]  T. Emge,et al.  Designing and tuning properties of a three-dimensional porous quaternary chalcogenide built on a bimetallic tetrahedral cluster [M4Sn3S13]5− (M=Zn/Sn) , 2008 .

[56]  Ayusman Sen,et al.  Controlled assembly of zero-, one-, two-, and three-dimensional metal chalcogenide structures. , 2007, Inorganic chemistry.

[57]  J. Dai,et al.  Direct solvothermal growth, crystal structures, and optical properties of one-dimensional lanthanide selenidoarsenate(v) polymers [Ln(dien)2(micro3-AsSe4)] (Ln = Nd, Sm): the first example of an AsSe4(3-) anion acting as a ligand to a lanthanide complex. , 2007, Dalton transactions.

[58]  S. Dehnen,et al.  A coordination chemistry approach towards ternary M/14/16 anions , 2007 .

[59]  J. Dai,et al.  Synthesis of a selenidostannate(IV), [Mn(tepa).Sn3Se7]n, demonstrating the transformation from achiral to chiral and dimeric to polymeric structure. , 2007, Inorganic chemistry.

[60]  W. Sheldrick,et al.  Tetra‐μ2‐selenido‐diselenidobis[tris(2‐amino­ethyl)amine]dimanganese(II)ditin(IV) , 2006 .

[61]  D. Mitzi.  Synthesis, structure, and thermal properties of soluble hydrazinium germanium(IV) and tin(IV) selenide salts. , 2005 .

[62]  Xintao Wu,et al.  Solvothermal Synthesis and Structure of Two 2D Tin–Selenides with Long Alkyldiamine NH2(CH2)nNH2 (n = 8, 10) , 2003 .

[63]  M. Behrens,et al.  On the Incorporation of Transition Metal Atoms into Thiostannates: Synthesis, Crystal Structures and Spectroscopic Properties of [Ni(en)3]2Sn2S6, [Ni(dap)3]2Sn2S6 · 2 H2O, [Co(tren)]2Sn2S6, and [Ni(tren)]2Sn2S6 , 2003 .

[64]  S. Dehnen,et al.  Syntheses, Crystal Structures, and Reactivity of [enH]4[Sn2Se6]·en, [enH]4[Sn2Te6]·en and [enH]4[Sn2S6]: Known Anions within Novel Coordination Spheres obtained by Novel Synthesis Routes , 2002 .

[65]  Andreas Fehlker,et al.  [(C2H5)3NH]2Sn3Se7 · 0,25 H2O und [(C3H7)2NH2]4Sn4Se10 · 4 H2O , 2001 .

[66]  R. Blachnik,et al.  Synthese, Struktur und Eigenschaften von [(C4H9)2NH2]4[Sn2Se6], [(C4H9)2NH2]4[Sn4Se10] · 2 H2O und [(C3H7)3NH]2[Sn3Se7] , 2001 .

[67]  M. Kanatzidis,et al.  Cs3AgAs4Se8 and CsAgAs2Se4: selenoarsenates with infinite 1 infinity[AsSe2]- chains in different Ag+ coordination environments. , 2000, Inorganic chemistry.

[68]  Su,et al.  Solving the Sayre equation by simulated annealing , 2000, Acta crystallographica. Section A, Foundations of crystallography.

[69]  D. Proserpio,et al.  Low temperature route towards new materials: solvothermal synthesis of metal chalcogenides in ethylenediamine , 1999 .

[70]  M. Kanatzidis,et al.  RbAg2As3Se6: A Unique Three-Dimensional Silver-Selenoarsenate Framework [Ag2As3Se6]-, Assembled from [As3Se6]3- Rings and “Ag22+” Dumbbell Units , 1999 .

[71]  M. Kanatzidis,et al.  Condensation of Pyramidal [AsSe3]3- Anions for the Construction of Polymeric Networks: Solventothermal Synthesis of K3AgAs2Se5·0.25MeOH, K2AgAs3Se6, and Rb2AgAs3Se6 , 1999 .

[72]  W. Sheldrick,et al.  Chalcogenidometalates of the heavier Group 14 and 15 elements , 1998 .

[73]  T. Emge,et al.  Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)32(Sn2Te6) (M = Mn, Zn) , 1998 .

[74]  G. Ozin,et al.  Intermediates in the formation of microporous layered tin(IV) sulfide materials , 1998 .

[75]  G. Ozin,et al.  New directions in tin sulfide materials chemistry , 1998 .

[76]  B. Marler,et al.  Synthesis, Structure Analysis, and Characterization of a New Thiostannate, (C(12)H(25)NH(3))(4)[Sn(2)S(6)].2H(2)O. , 1997, Inorganic chemistry.

[77]  J. Kolis,et al.  Synthesis of one dimensional tin selenides in supercritical amines , 1997 .

[78]  Christopher J. Warren,et al.  Synthesis and structural characterization of Zintl anions containing the tris(ethylenediamine)-zinc cation: [Zn(N2C2H8)3][Te3]·(0.5en) and [Zn(N2C2H8)3]2[Sn2Te6]·(en) , 1997 .

[79]  M. Kanatzidis,et al.  Isolation of β-Ag3AsSe3, (Me3NH)[Ag3As2Se5], K5Ag2As3Se9, and KAg3As2S5 : Novel solid state silver thio- and selenoarsenates from solvento-thermal synthesis , 1996 .

[80]  J. Yates,et al.  Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results , 1995 .

[81]  W. Sheldrick,et al.  Discrete Crown‐Shaped Te8 Rings in Cs3 Te22 , 1995 .

[82]  W. Sheldrick,et al.  Darstellung und Kristallstruktur von Cs2Sn3Se7, ein Cäsium-selenostannat(IV) mit fünffach koordiniertem Zinn / Preparation and Crystal Structure of Cs2Sn3Se7, a Cesium Selenostannate(IV) with Pentacoordinated Tin , 1990 .

[83]  M. Kanatzidis,et al.  Synthesis, structure and 77Se/119Sn NMR spectroscopy of the new polyselenide, tris(tetraselenido)stannate(IV), [Sn(Se4)3]2− , 1990 .

[84]  I. Dance,et al.  Syntheses and structures of anionic metal polyselenide complexes [(C5H5)Mo(Se4)2]− and [Sn(Se4)3]2−, crystallized with Ph4P+ , 1989 .

[85]  I. Dance,et al.  Syntheses and X-ray structures of molecular metal polyselenide complexes [M(Se4)2]2− M = Zn, Cd, Hg, Ni, Pb , 1989 .

[86]  R. W. Matthews.  An adsorption water purifier with in situ photocatalytic regeneration , 1988 .

[87]  M. Fox,et al.  Kinetics for electron transfer from laser-pulse irradiated colloidal semiconductors to adsorbed methylviologen: dependence of the quantum yield on incident pulse width , 1988 .