Transition-metal complex catalyzed perfluoroalkylation. A facile synthesis of fluorine-containing esters by carbo-carbonylation of alkynes and alkenes.

Palladium-catalyzed reaction of perfluoroalkyl iodides with terminal alkynes or alkenes in alcohols under carbon monoxide pressure in the presence of potassium carbonate directly gives β-perfluoroalkyl-substituted alkenoates or alkanoates, respectively.

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