Fuel cell systems with reforming of petroleum-based and synthetic-based diesel and kerosene fuels for APU applications

Abstract This work deals with the theoretical and experimental analysis of fuel-cell-based auxiliary power units operated with reformate from diesel and kerosene reforming for trucks and aircraft. In the theoretical part, a PEFC and an HT-PEFC system were analyzed using process simulation software. In the experimental part, a fuel processor consisting of an autothermal reformer, a water-gas shift reactor and a catalytic burner with 28 kW thermal power was characterized using different diesel and kerosene fuels. These fuels included desulfurized Jet A-1 and Aral Ultimate diesel as petroleum-based fuels and GTL kerosene, GTL diesel (winter and summer grades) and BTL diesel as non-petroleum-based synthetic fuels. The PEFC system showed a calculated electrical net efficiency of 28.5%, whereas 22.3% was calculated for the HT-PEFC system. A high-quality reformate was produced using various diesel and kerosene fuel qualities in the reformer with a relevant technical power class for the APU application. Although a performance loss of the shift reactor was observed, it was kept at an acceptable level at the end of experiments.

[1]  Melanie Grote,et al.  Further development of a microchannel steam reformer for diesel fuel , 2012 .

[2]  A. Ersöz,et al.  Reforming options for hydrogen production from fossil fuels for PEM fuel cells , 2006 .

[3]  R. C. Samsun,et al.  Fuel Processing of Diesel and Kerosene for Auxiliary Power Unit Applications , 2013 .

[4]  Josef Kallo,et al.  Multifunctional fuel cell system in an aircraft environment: An investigation focusing on fuel tank inerting and water generation , 2013 .

[5]  D. L. Daggett,et al.  Fuel cell APU for commercial aircraft , 2003 .

[6]  Josef Kallo,et al.  Fuel cells for civil aircraft application: On-board production of power, water and inert gas , 2012 .

[8]  Detlef Stolten,et al.  Start‐Up and Load‐Change Behavior of a Catalytic Burner for a Fuel‐Cell‐Based APU for Diesel Fuel , 2015 .

[9]  Christie-Joy Brodrick,et al.  Analysis of potential fuel consumption and emissions reductions from fuel cell auxiliary power units (APUs) in long-haul trucks , 2007 .

[10]  Joachim Pasel,et al.  Catalytic burner with internal steam generation for a fuel-cell-based auxiliary power unit for middle distillates , 2014 .

[11]  Peiwen Li,et al.  Small-scale reforming of diesel and jet fuels to make hydrogen and syngas for fuel cells: A review , 2013 .

[12]  Semant Jain,et al.  Techno-economic analysis of fuel cell auxiliary power units as alternative to idling , 2006 .

[13]  Detlef Stolten,et al.  Fuel Processing of Low-Sulfur Diesel for Fuel Cell Systems , 2015 .

[14]  T. Schmidt Durability and Degradation in High-Temperature Polymer Electrolyte Fuel Cells , 2006 .

[15]  Robert J. Braun,et al.  System Architectures for Solid Oxide Fuel Cell-Based Auxiliary Power Units in Future Commercial Aircraft Applications , 2009 .

[16]  Michael Reissig,et al.  AVL SOFC Systems on the Way of Industrialization , 2013 .

[17]  Ludger Blum,et al.  Fuel Cell Auxiliary Power Units for Heavy Duty Truck Anti-Idling , 2013 .

[18]  H. Vesala,et al.  Experimental Study of an SOFC Stack Operated With Autothermally Reformed Diesel Fuel , 2013 .

[19]  Roland Peters,et al.  Enhancing the Efficiency of SOFC‐Based Auxiliary Power Units by Intermediate Methanation , 2012 .

[20]  S. Baek,et al.  A diesel-driven, metal-based solid oxide fuel cell , 2014 .

[21]  D. Stolten,et al.  Development of HT-PEFC stacks in the kW range , 2013 .

[22]  R. Peters,et al.  Chapter 4:Large Auxiliary Power Units for Vessels and Airplanes , 2010 .

[23]  A. Lindermeir,et al.  On-board diesel fuel processing for an SOFC–APU—Technical challenges for catalysis and reactor design , 2007 .

[24]  Marius Maximini,et al.  Coupled operation of a diesel steam reformer and an LT- and HT-PEFC , 2014 .

[25]  Jeremy Lawrence,et al.  Auxiliary power unit based on a solid oxide fuel cell and fuelled with diesel , 2006 .

[26]  Gunther Kolb,et al.  Microchannel Fuel Processors as a Hydrogen Source for Fuel Cells in Distributed Energy Supply Systems , 2013 .

[27]  Remzi Can Samsun,et al.  Evaluation of multifunctional fuel cell systems in aviation using a multistep process analysis methodology , 2013 .

[28]  Younghoon Cho,et al.  High-Efficiency Multiphase DC–DC Converter for Fuel-Cell-Powered Truck Auxiliary Power Unit , 2013, IEEE Transactions on Vehicular Technology.

[29]  Detlef Stolten,et al.  Long-term stability at fuel processing of diesel and kerosene , 2014 .

[30]  Pedro Nehter,et al.  A techno-economic comparison of fuel processors utilizing diesel for solid oxide fuel cell auxiliary power units , 2011 .

[31]  Joel Berry,et al.  Diesel reformer — a key component for a truck fuel cell APU , 2010 .

[32]  Päivi Aakko,et al.  NExBTL - Biodiesel Fuel of the Second Generation , 2005 .

[33]  Sangho Lee,et al.  Development of a self-sustaining kWe-class integrated diesel fuel processing system for solid oxide fuel cells , 2011 .

[34]  Joachim Pasel,et al.  Autothermal Reforming of Jet A-1 and Diesel: General Aspects and Experimental Results , 2008 .

[35]  Remzi Can Samsun,et al.  Methodologies for Fuel Cell Process Engineering , 2012 .

[36]  Callie W. Babbitt,et al.  Assessment of bio-fuel options for solid oxide fuel cell-based auxiliary power units , 2011, Proceedings of the 2011 IEEE International Symposium on Sustainable Systems and Technology.

[37]  Werner Lehnert,et al.  Design and test of a 5kWe high-temperature polymer electrolyte fuel cell system operated with diesel and kerosene , 2014 .

[38]  S. Specchia Fuel processing activities at European level: A panoramic overview , 2014 .

[39]  M. Nilsson,et al.  Characterization and optimization of an autothermal diesel and jet fuel reformer for 5 kWe mobile fuel cell applications , 2010 .

[40]  Roland Peters,et al.  Analysis and optimization of solid oxide fuel cell-based auxiliary power units using a generic zero-dimensional fuel cell model , 2011 .