Adsorption of Phosphate from Aqueous Solution by Calcination of Silicified Coal: Kinetic and Isotherm Studies

Silicified coal (SC) consisting of SiO2 is promising raw material for adsorbent. The present study aimed to utilize the adsorbent of silicified coal bottom ash (SCBA) by calcination of the SC at the temperature of 600, 800 and 1000 oC for 1 hour. The FTIR result showed that the SCBA-600, SCBA-800 and SCBA-1000 had chemical functional groups such as the asymmetric Si-O-Si, the symmetric Si-O-Si and Si-O-Si bond rocking for adsorption of phosphate (PO43−) with the lowest percentage of transmittance of SCBA-1000. The adsorption test showed that a rapid adsorption occurred in the first 10-min of contact time, and it did not change significantly for the rest of contact time until reaching an equilibrium time of 30 min. The PO43− adsorption efficiency and capacity fluctuated over initial PO43− in solution in the range of 60.02–480.29 mg/L. The highest PO43− adsorption efficiency and capacity was at 480.29 mg/L, which was 95.49 % and 45.86 mg/g, respectively using the SCBA-1000. The adsorption kinetic fitted better to pseudo second-order kinetics model (average R2 = 0.999) with the adsorption capacity of 45.454, 45.662 and 45.872 for the SCBA_600, SCBA_800 and SCBA_1000, respectively, and the PO43− adsorption rate was 0.0007, 0.0008 and 0.001 g/mg.min, respectively. The adsorption isotherm followed Langmuir model (average R2 = 0.873) with the adsorption capacity being 2.357, 1.198 and 8.196 mg/g, respectively, and the pore volume being 0.0316, 0.0364 and 0.2103 L/mg, respectively

[1]  Ade I. Agipa,et al.  Phospate Release Study on Silica Gel and Amino Silica Hybrid Sorbent from Lapindo Mud , 2022, Jurnal Akademika Kimia.

[2]  Zaheer Ahmed,et al.  Formulation, characterization and sensory evaluation of Bio‐Cal instant Jelly fortified with chicken bone based nano‐biogenic hydroxyapatite , 2022, International Journal of Food Science & Technology.

[3]  T. Hadibarata,et al.  Silicified coal adsorbents for adsorption of Cu(II) from the aqueous Solution: Non-Linear kinetic and isotherm studies , 2022, Materials Today: Proceedings.

[4]  P. Show,et al.  A review on conventional and novel materials towards heavy metal adsorption in wastewater treatment application , 2021 .

[5]  G. Krouk,et al.  Nitrogen and Phosphorus interactions in plants: from agronomic to physiological and molecular insights. , 2020, Current opinion in plant biology.

[6]  Marlina,et al.  Polyurethane film prepared from ball-milled algal polyol particle and activated carbon filler for NH3–N removal , 2020, Heliyon.

[7]  Priyadarshi Roy Chowdhury,et al.  Kinetics of Aqueous Cu(II) Biosorption onto Thevetia peruviana Leaf Powder , 2020, ACS omega.

[8]  Sheila M. Olmstead,et al.  Trends in nutrient-related pollution as a source of potential water quality damages: A case study of Texas, USA. , 2020, The Science of the total environment.

[9]  D. Graham,et al.  A Review of Phosphorus Removal Technologies and Their Applicability to Small-Scale Domestic Wastewater Treatment Systems , 2018, Front. Environ. Sci..

[10]  Dan Li,et al.  Adsorptive removal of phosphate from water using mesoporous materials: A review. , 2017, Journal of environmental management.

[11]  Guangming Zeng,et al.  Adsorption of phosphate from aqueous solution using iron-zirconium modified activated carbon nanofiber: Performance and mechanism. , 2017, Journal of colloid and interface science.

[12]  Kamel K. Al-Zboon,et al.  Phosphate removal from aqueous solutions by using natural Jordanian zeolitic tuff , 2017 .

[13]  S. Mor,et al.  Application of agro-waste rice husk ash for the removal of phosphate from the wastewater , 2016 .

[14]  D. Dionysiou,et al.  Phosphate adsorption using modified iron oxide-based sorbents in lake water: Kinetics, equilibrium, and column tests , 2016 .

[15]  H. Lee,et al.  Molecular Weight and Structural Properties of Biodegradable PLA Synthesized with Different Catalysts by Direct Melt Polycondensation , 2015 .

[16]  N. Popa,et al.  Adsorption of Heavy Metals Cations onto Zeolite Material from Aqueous Solution , 2015 .

[17]  Juan An,et al.  Kinetic and Thermodynamic Studies on the Phosphate Adsorption Removal by Dolomite Mineral , 2015 .

[18]  Pradeep Kumar,et al.  Adsorptive removal of phosphate from aqueous solution using rice husk and fruit juice residue , 2015 .

[19]  Ahmad B. Albadarin,et al.  Removal of ortho-phosphate from aqueous solution by adsorption onto dolomite , 2014 .

[20]  Qi Li,et al.  Strong adsorption of phosphate by amorphous zirconium oxide nanoparticles. , 2013, Water research.

[21]  C. Kroeze,et al.  Nitrogen and phosphorus inputs to the Black Sea in 1970–2050 , 2013, Regional Environmental Change.

[22]  N. Chang,et al.  Phosphate adsorption on hydroxyl–iron–lanthanum doped activated carbon fiber , 2013 .

[23]  A. Seco,et al.  Metabolic shift of polyphosphate-accumulating organisms with different levels of polyphosphate storage. , 2012, Water research.

[24]  Yu-Ting Liu,et al.  Phosphate bonding on noncrystalline Al/Fe-hydroxide coprecipitates. , 2011, Environmental science & technology.

[25]  Liang Yan,et al.  Adsorption of phosphate from aqueous solution by hydroxy-aluminum, hydroxy-iron and hydroxy-iron-aluminum pillared bentonites. , 2010, Journal of hazardous materials.

[26]  P. Moulin,et al.  The effect of antiscalant addition on calcium carbonate precipitation for a simplified synthetic brackish water reverse osmosis concentrate. , 2010, Water research.

[27]  B Jefferson,et al.  Removal and recovery of phosphate from municipal wastewaters using a polymeric anion exchanger bound with hydrated ferric oxide nanoparticles. , 2009, Water science and technology : a journal of the International Association on Water Pollution Research.

[28]  Yanjie Wei,et al.  Characteristics of aerobic granule and nitrogen and phosphorus removal in a SBR. , 2009, Journal of hazardous materials.

[29]  Hao Yu,et al.  Mechanism study on adsorption of acidified multiwalled carbon nanotubes to Pb(II). , 2007, Journal of colloid and interface science.

[30]  Chunlei Zhu,et al.  Phosphate removal from aqueous solutions using raw and activated red mud and fly ash. , 2006, Journal of hazardous materials.

[31]  Bruno Kostura,et al.  Blast furnace slags as sorbents of phosphate from water solutions. , 2005, Water research.

[32]  A. Gürses,et al.  Kinetic modeling of liquid-phase adsorption of phosphate on dolomite. , 2004, Journal of colloid and interface science.

[33]  Jin-dun Liu,et al.  Adsorptive removal of phosphate from aqueous solutions using iron oxide tailings. , 2004, Water research.

[34]  M. Ozacar.  Adsorption of phosphate from aqueous solution onto alunite. , 2003, Chemosphere.

[35]  THE WORLD HEALTH ORGANIZATION , 1954 .

[36]  AUSTRALIAN PINE CONES-BASED ACTIVATED CARBON FOR ADSORPTION OF COPPER IN AQUEOUS SOLUTION MUSLIM , 2017 .

[37]  Ellysa,et al.  Cu(II) Ion Adsorption Using Activated Carbon Prepared from Pithecellobium Jiringa (Jengkol) Shells with Ultrasonic Assistance: Isotherm, Kinetic and Thermodynamic Studies , 2017 .

[38]  Jaspal P. Bange,et al.  Growth and Characterization of Sio 2 Films Deposited by Flame Hydrolysis Deposition System for Photonic Device Application , 2008 .

[39]  N. Kawasaki,et al.  Removal of phosphate by aluminum oxide hydroxide. , 2003, Journal of colloid and interface science.