The first Australian Synchrotron powder diffraction analysis of pigment from a Wandjina motif in the Kimberley, Western Australia

Abstract We report the identification of minerals in stratified paint layers from a Wandjina motif in the central Kimberley region, Western Australia, via synchrotron powder diffraction. Interpreting our findings with reference to previous pigment characterisations of Wandjina motifs, we outline the potential of this method for rock art investigations. We particularly highlight the implications of successful major and minor phase identification in very small (~3 µg) pigment samples. The results of this pilot study show that crystallographic data is critical in helping to separate environmental/cultural signatures from post-depositional processes within anthropogenically applied pigments. In Wandjina rock art, crystallography facilitates the examination of the cultural context of rock art production within an assemblage ethnographically known to have undergone regular, ritual repainting.

[1]  P. M. O'Neill,et al.  Studies of the composition of pigments used traditionally in Australian Aboriginal bark paintings , 2004 .

[2]  L. Head Unearthing prehistoric cultural landscapes: a view from Australia , 1993 .

[3]  Rhys Jones,et al.  Luminescence dating of rock art and past environments using mud-wasp nests in northern Australia , 1997, Nature.

[4]  B. Schmitt,et al.  The MYTHEN detector for X-ray powder diffraction experiments at the Swiss Light Source , 2010, Journal of synchrotron radiation.

[5]  I. Zizak,et al.  Clay pigment structure characterisation as a guide for provenance determination—a comparison between laboratory powder micro-XRD and synchrotron radiation XRD , 2011, Analytical and bioanalytical chemistry.

[6]  S. O’Connor,et al.  Painting and Repainting in the West Kimberley , 2008 .

[7]  M. Morwood,et al.  The dating potential of rock art in the Kimberley, NW Australia , 1994 .

[8]  J. Clarke TWO ABORIGINAL ROCK ART PIGMENTS FROM WESTERN AUSTRALIA THEIR PROPERTIES, USE, AND DURABILITY , 1976 .

[9]  B. David,et al.  Prehistoric hand stencils at Fern Cave, North Queensland (Australia): environmental and chronological implications of Raman spectroscopy and FT-IR imaging results , 2009 .

[10]  M. Morwood,et al.  AMS RADIOCARBON AGES FOR BEESWAX AND CHARCOAL PIGMENTS IN NORTH KIMBERLEY ROCK ART , 2010 .

[11]  D. Creagh,et al.  On the feasibility of establishing the provenance of Australian Aboriginal artefacts using synchrotron radiation X-ray diffraction and proton-induced X-ray emission , 2007 .

[12]  K. Wallwork,et al.  The High Resolution Powder Diffraction Beamline for the Australian Synchrotron , 2007 .

[13]  I. M. Crawford,et al.  The art of the Wandjina : aboriginal cave paintings in Kimberley, Western Australia , 1970 .

[14]  I. Mcbryde The cultural landscapes of Aboriginal long distance exchange systems: Can they be confined within our heritage registers? , 1997 .

[15]  Guangshan Chen,et al.  Orbital time-scale circulation controls of the Australian summer monsoon: a possible role for mid-latitude Southern Hemisphere forcing? , 2012 .

[16]  Jillian Huntley,et al.  One Colour, (at Least) Two Minerals: A Study of Mulberry Rock Art Pigment and a Mulberry Pigment ‘Quarry’ from the Kimberley, Northern Australia , 2015 .

[17]  George Robert Rapp,et al.  Geoarchaeology: The Earth-Science Approach to Archaeological Interpretation , 1998 .

[18]  Allan Pring,et al.  RIETVELD X-RAY DIFFRACTION AND X-RAY FLUORESCENCE ANALYSIS OF AUSTRALIAN ABORIGINAL OCHRES* , 1998 .

[19]  I. MacLeod,et al.  Effects of water vapour and rock substrates on the microclimates of painted rock art surfaces and their impact on the preservation of the images , 2008 .

[20]  I. MacLeod,et al.  Rock art pigments from Kimberley region of Western Australia: identification of the minerals and conversion mechanisms , 1994 .