The NBS triple quadrupole tandem mass spectrometer

A detailed description is provided of a triple quadrupole (QQQ) tandem mass spectrometer (MS/MS) which is kinetically well behaved and can be configured to use either a molecular beam target (type A) or collision chamber (type B) configuration. Its unique capabilities are being used to explore design criteria essential for (i) absolute cross‐section measurements, and for (ii) the development of standardized operating conditions for generic, instrument‐independent spectral databases for collisionally activated dissociation (CAD).

[1]  R. Martinez,et al.  Instrument-Independent CAD Spectral Databases: Absolute Cross-Section Measurements In QQQ Instruments , 1987, Journal of Research of the National Bureau of Standards.

[2]  R. Martinez,et al.  Validation of absolute target thickness calibrations in a QQQ instrument by measuring absolute total cross-sections of Ne+ (Ne, Ne) Ne+ , 1986 .

[3]  P. Dawson,et al.  A round robin on the reproducibility of standard operating conditions for the acquisition of library MS/MS spectra using triple quadrupoles , 1984 .

[4]  Richard A. Yost,et al.  Tandem mass spectrometry (MS/MS) instrumentation , 1983 .

[5]  D. J. Douglas,et al.  The use of triple quadrupoles for sequential mass spectrometry: 1—The instrument parameters , 1982 .

[6]  D. J. Douglas,et al.  The use of triple quadrupoles for sequential mass spectrometry: 2—A detailed case study , 1982 .

[7]  P. Dawson,et al.  The effective containment of parent ions and daughter ions in triple quadrupoles used for collisional dissociation , 1982 .

[8]  P. Dawson Ion Optical Properties of Quadrupole Mass Filters , 1980 .

[9]  P. Dawson Energetics of ions in quadrupole fields , 1976 .

[10]  W. E. Falconer,et al.  Crossed‐molecular‐beam study of the kinematics and dynamics of charge‐transfer collisions , 1974 .

[11]  J. Paulson,et al.  Study of ion—neutral reactions with a time-of-flight double mass spectrometer☆ , 1970 .

[12]  R. Amme,et al.  Ion‐Beam Excitation Effects on the Single Charge Transfer between Argon and Nitrogen , 1965 .