论文信息 - Synthesis and Properties of Germylene-Bridged Diiron Complexes Using t-Butylgermane as a Precursor of Ligands

Synthesis and Properties of Germylene-Bridged Diiron Complexes Using t-Butylgermane as a Precursor of Ligands

Photolysis of CpFe(CO)2SiMe3 (Cp = η-C5H5) in the presence of a new alkylgermane tBuGeH3 afforded a mono(μ-germylene)diiron complex Cp2Fe2(CO)3(μ-GeHtBu) (4) and a bis(μ-germylene)diiron complex Cp2Fe2(CO)2(μ-GeHtBu)2 (5). The structure of 4 was determined by X-ray crystallography.

Y. Kawano | H. Tobita | H. Ogino | K. Sugawara

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