Spin-coated silver nanocomposite resistive switching devices

A simple two-terminal resistive switching device is fabricated on the basis of a silver-based nanocomposite by means of direct processing through spin-coating technique. This work mainly focuses on the role of Ag in inducing a resistive switching in response to an applied electric field. Characterization results confirm the field-induced formation of a conductive filament along the silver clusters bridging two electrodes, which evidences the microscopic origin of bipolar resistive switching behaviour observed in our device. The morphological and electrical characterizations performed on the device support the hypothesis of field induced filament formation. The present study evidences a simple and low-cost material, easily processable to realize logic devices exhibiting a bipolar non-volatile switching behaviour that is controllable by means of the current compliance level.

[1]  Cheng-Kang Lee,et al.  Magnetic antimicrobial nanocomposite based on bacterial cellulose and silver nanoparticles , 2010 .

[2]  Masakazu Aono,et al.  Mechanism for Conducting Filament Growth in Self‐Assembled Polymer Thin Films for Redox‐Based Atomic Switches , 2016, Advanced materials.

[3]  R. Dittmann,et al.  Resistive Switching Mechanisms on TaOx and SrRuO3 Thin-Film Surfaces Probed by Scanning Tunneling Microscopy. , 2016, ACS nano.

[4]  Xiaohua Huang,et al.  Noble metals on the nanoscale: optical and photothermal properties and some applications in imaging, sensing, biology, and medicine. , 2008, Accounts of chemical research.

[5]  D. Stewart,et al.  The missing memristor found , 2008, Nature.

[6]  A. Chiolerio,et al.  In situ synthesis of Ag-acrylic nanocomposites: Tomography-based percolation model, irreversible photoinduced electromigration and reversible electromigration , 2012 .

[7]  L. Chua Memristor-The missing circuit element , 1971 .

[8]  H. Takagi,et al.  Inhomogeneous chemical states in resistance-switching devices with a planar-type Pt/CuO/Pt structure , 2009 .

[9]  Switching speed in resistive random access memories (RRAMS) based on plastic semiconductor , 2011 .

[10]  J. M. Kikkawa,et al.  Resistive switching in silver/polystyrene/silver nano-gap devices , 2013 .

[11]  Haifeng Cheng,et al.  Nonvolatile bipolar resistive switching in amorphous Sr-doped LaMnO3 thin films deposited by radio frequency magnetron sputtering , 2013 .

[12]  A. Bonfiglio,et al.  Air-stable, non-volatile resistive memory based on hybrid organic/inorganic nanocomposites , 2015 .

[13]  Eric J. Sandouk,et al.  Multistate resistive switching in silver nanoparticle films , 2015, Science and technology of advanced materials.

[14]  Planar non-volatile memory based on metal nanoparticles , 2011 .

[15]  Qi Liu,et al.  Direct Observation of Conversion Between Threshold Switching and Memory Switching Induced by Conductive Filament Morphology , 2014 .

[16]  T. Hasegawa,et al.  Short-term plasticity and long-term potentiation mimicked in single inorganic synapses. , 2011, Nature materials.

[17]  I. Bloom,et al.  CRITICAL BEHAVIOR OF THE ELECTRICAL TRANSPORT PROPERTIES IN A TUNNELING-PERCOLATION SYSTEM , 1999 .

[18]  Xingyi Huang,et al.  Ferroelectric polymer/silver nanocomposites with high dielectric constant and high thermal conductivity , 2009 .

[19]  A. Chiolerio,et al.  Impedance Hyperbolicity in Inkjet‐Printed Graphene Nanocomposites: Tunable Capacitors for Advanced Devices , 2016 .

[20]  Yi-Jen Chan,et al.  Carrier Transport Mechanism in a Nanoparticle-Incorporated Organic Bistable Memory Device , 2007, IEEE Electron Device Letters.

[21]  A. Chiolerio,et al.  Enhanced Performance of Graphene–Epoxy Flexible Capacitors by Means of Ceramic Fillers , 2015 .

[22]  P. Ajayan,et al.  Nanocomposite Science And Technology , 2003 .

[23]  A. Chiolerio,et al.  Dual step irradiation process for in situ generation and patterning of silver nanoparticles in a photocured film , 2016 .

[24]  A. Requicha,et al.  Plasmonics—A Route to Nanoscale Optical Devices , 2001 .

[25]  Karen I. Winey,et al.  Resistive Switching in Bulk Silver Nanowire–Polystyrene Composites , 2011 .

[26]  B. Mukherjee,et al.  Nonvolatile memory device based on Ag nanoparticle: Characteristics improvement , 2009 .

[27]  R. Dittmann,et al.  Redox‐Based Resistive Switching Memories – Nanoionic Mechanisms, Prospects, and Challenges , 2009, Advanced materials.

[28]  A. Chiolerio,et al.  Towards a quantitative analysis of magnetic force microscopy data matrices , 2012 .

[29]  D. Hirst,et al.  Gold nanoparticles as novel agents for cancer therapy. , 2012, The British journal of radiology.

[30]  Alessandro Chiolerio,et al.  Ionic liquid-enhanced soft resistive switching devices , 2016 .

[31]  A. Chiolerio,et al.  Evidence of Negative Capacitance in Piezoelectric ZnO Thin Films Sputtered on Interdigital Electrodes. , 2015, ACS applied materials & interfaces.

[32]  S. Porro,et al.  Memristive behaviour in inkjet printed graphene oxide thin layers , 2015 .

[33]  Paola Tiberto,et al.  Enhanced imaging of magnetic structures in micropatterned arrays of Co dots and antidots. , 2007 .