Charge motion and trapping in insulators: surface and bulk effects

The electrical currents that flow in and on insulators are small, but they may be important in applications and they may indicate the mechanism of carrier motion. The processes which come into play include mobility and ionization, trapping and detrapping, and injection and blocking. Some of these phenomena are intrinsic to the material, while others depend on the amount and nature of the impurities. This paper concentrates on problems in data analysis and on the interpretation of charge measurements in the bulk and on surfaces. Some materials and some processes are well understood, while others remain obscure, particularly the identities of carriers and traps. A considerable investment of time and money will be required to solve these problems.

[1]  R. Young A law of corresponding states for hopping transport in disordered materials , 1994 .

[2]  S. Onari Vacuum Ultraviolet Absorption Spectra of Synthesized Polymer Films , 1969 .

[3]  Y. Onodera Breakdown of Debye's Model for Dielectric Relaxation in High Frequencies , 1993 .

[4]  J. Macdonald The impedance of a galvanic cell with two plane-parallel electrodes at a short distance , 1971 .

[5]  A. R. Hepburn,et al.  The influence of inter-oligomer separation distance on observed hopping mobilities in terthiophene-doped polycarbonate , 1993 .

[6]  J. Weese A reliable and fast method for the solution of Fredhol integral equations of the first kind based on Tikhonov regularization , 1992 .

[7]  T. C. Chapman,et al.  Dielectric absorption currents and surface charge on polymeric insulators , 1980 .

[8]  B. Gross,et al.  Short‐Circuit Currents in Charged Dielectrics and Motion of Zero‐Field Planes , 1972 .

[9]  Gérard Dreyfus,et al.  Stress-Wave Probing of Electric Field Distributions in Dielectrics , 1981 .

[10]  Thomas L. Szabo,et al.  Causal theories and data for acoustic attenuation obeying a frequency power law , 1995 .

[11]  V. Halpern Dielectric relaxation, the superposition principle, and age-dependent transition rates , 1992 .

[12]  H. Wintle Kramers-Kronig analysis of polymer acoustic data , 1999 .

[13]  Surface spreading of charge due to ohmic conduction , 1985, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[15]  M. Lock,et al.  Migration and trapping of extrinsic charge carriers in polymer films , 1969 .

[16]  A. Rose Recombination Processes in Insulators and Semiconductors , 1955 .

[17]  Wolfgang Eisenmenger,et al.  Observation of charge compensated polarization zones in polyvinylindenfluoride (PVDF) films by piezoelectric acoustic step wave response , 1982 .

[18]  Dunlap Explanation for the sqrt E -dependent mobilities of charge transport in molecularly doped polymers. , 1995, Physical review. B, Condensed matter.

[19]  Mario Bertero,et al.  On the recovery and resolution of exponential relaxation rates from experimental data II. The optimum choice of experimental sampling points for Laplace transform inversion , 1984, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[20]  Teruo Miyamoto,et al.  Free‐volume model for ionic conductivity in polymers , 1973 .

[21]  K. Hillier A Method of Measuring some Dynamic Elastic Constants and its Application to the Study of High Polymers , 1949 .

[22]  H. Wintle Discharge currents following space‐charge‐limited current conditions in insulators , 1987 .

[23]  P. Jacobs,et al.  Polarization in potassium chloride crystals , 1966 .

[24]  T. C. Chapman,et al.  Surface‐charge‐limited transient currents on insulating surfaces , 1982 .

[25]  J. Macdonald Analysis of dispersed, conducting-system frequency-response data , 1996 .

[26]  J. Ross Macdonald,et al.  Simplified impedance/frequency‐response results for intrinsically conducting solids and liquids , 1974 .

[27]  D. Clark Some Experimental and Theoretical Aspects of Structure, Bonding and Reactivity of Organic and Polymeric Systems as Revealed by ESCA , 1977 .

[28]  J. Y. Kim,et al.  Interfacial charge in polyethylene/ethylene vinylacetate laminates , 1996 .

[29]  H. Wintle Surface conduction on insulators: Analysis and interpretation of the Faraday cage experiment , 1997 .

[30]  Y. Jayet,et al.  Ultrasonic spectroscopy in polymeric materials. Application of the Kramers–Kronig relations , 1996 .

[31]  H. Wintle,et al.  Charge injection and conduction on the surface of insulators , 1998 .

[32]  S. Provencher CONTIN: A general purpose constrained regularization program for inverting noisy linear algebraic and integral equations , 1984 .

[33]  H. Sasabe,et al.  Effects of Catalysts on Dielectric Properties and D. C. Conduction in Poly(ethylene terephthalate) , 1971 .

[34]  J. Noolandi Multiple-trapping model of anomalous transit-time dispersion in a − S e , 1977 .

[35]  G. Arlt,et al.  A numerical method for the determination of first-order kinetics relaxation time spectra , 1988 .

[36]  Gerhard M. Sessler,et al.  Charge dynamics in irradiated polymers , 1992, [Proceedings] 1992 Annual Report: Conference on Electrical Insulation and Dielectric Phenomena.

[37]  Takashi Maeno,et al.  Measurement of spatial charge distribution in thick dielectrics using the pulsed electroacoustic method , 1988 .

[38]  H. Bässler Charge Transport in Disordered Organic Photoconductors a Monte Carlo Simulation Study , 1993 .

[39]  K. L. Kliewer Space Charge in Ionic Crystals. II. The Electron Affinity and Impurity Accumulation , 1965 .

[40]  D. Pai,et al.  Electric‐field‐enhanced conductivity in solids , 1975 .

[41]  Teruyoshi Mizutani,et al.  Space charge measurement techniques and space charge in polyethylene , 1994 .

[42]  H. Kiess,et al.  Electric conduction in amorphous polymers , 1980 .