论文信息 - (η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

(η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P212121 and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N′-bidentate chelating ligand, leading to the formation of the chiral [Pd(η3-allyl)(pmp)]+ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

J. Davies | Matthew D. Jones | F. Paz | B. Johnson

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(η3-Allyl)[(S)-(+)-(2-pyrrolidinyl­methyl)­pyrrolidine]­palladium(II) trifluoro­methane­sulfonate

(η3-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate