DBD plasma‐assisted coating of metal alkoxides on sulfur powder for Li–S batteries

Sulfur particles coated by activation of metal alkoxide precursors, aluminum–sulfur (Alu–S) and vanadium–sulfur (Van–S), were produced by dielectric barrier discharge (DBD) plasma technology under low temperature and ambient pressure conditions. We report a safe, solvent‐free, low‐cost, and low‐energy consumption coating process that is compatible for sustainable technology up‐scaling. NMR, XPS, SEM, and XRD characterization methods were used to determine the chemical characteristics and the superior behavior of Li–S cells using metal oxide‐based coated sulfur materials. The chemical composition of the coatings is a mixture of the different elements present in the metal alkoxide precursor. The presence of alumina Al2O3 within the coating was confirmed. Multi‐C rate and long‐term galvanostatic cycling at rate C/10 showed that the rate capability losses and capacity fade could be highly mitigated for the Li–S cells containing the coated sulfur materials in comparison to the references uncoated (raw) sulfur. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) confirm the lower charge‐transfer resistance and potential hysteresis in the electrodes containing the coated sulfur particles. Our results show that the electrochemical performance of the Li–S cells based on the different coating materials can be ranked as Alu‐S > Van‐S > Raw sulfur.

[1]  M. Safari,et al.  Impact of Different Conductive Polymers on the Performance of the Sulfur Positive Electrode in Li–S Batteries , 2022, ACS Applied Energy Materials.

[2]  M. Safari,et al.  Dielectric Barrier Discharge (DBD) Plasma Coating of Sulfur for Mitigation of Capacity Fade in Lithium-Sulfur Batteries. , 2021, ACS applied materials & interfaces.

[3]  Qiang Zhang,et al.  Advances in Lithium–Sulfur Batteries: From Academic Research to Commercial Viability , 2021, Advanced materials.

[4]  A. Ramazani,et al.  Using of various metal species for improvement of electrochemical performances of lithium sulfur batteries , 2020 .

[5]  Guang-bo Zhao,et al.  Vapor deposition of aluminium oxide into N-rich mesoporous carbon framework as a reversible sulfur host for lithium-sulfur battery cathode , 2020, Nano Research.

[6]  X. Tao,et al.  12 years roadmap of the sulfur cathode for lithium sulfur batteries (2009–2020) , 2020 .

[7]  M. Safari,et al.  The impact of polymeric binder on the morphology and performances of sulfur electrodes in lithium–sulfur batteries , 2020 .

[8]  Michel Noussan,et al.  Li-Ion Batteries: A Review of a Key Technology for Transport Decarbonization , 2020, Energies.

[9]  Xianfu Wang,et al.  Strategies toward High‐Loading Lithium–Sulfur Battery , 2020, Advanced Energy Materials.

[10]  H. Althues,et al.  Challenges and Key Parameters of Lithium-Sulfur Batteries on Pouch Cell Level , 2020, Joule.

[11]  C. Barbero,et al.  LiV3O8-Based Functional Separator Coating as Effective Polysulfide Mediator for Lithium–Sulfur Batteries , 2020 .

[12]  Kunlei Zhu,et al.  How Far Away Are Lithium-Sulfur Batteries From Commercialization? , 2019, Front. Energy Res..

[13]  C. Capiglia,et al.  A Comprehensive Understanding of Lithium–Sulfur Battery Technology , 2019, Advanced Functional Materials.

[14]  Yan Zhao,et al.  Carbon nanotubes/SiC prepared by catalytic chemical vapor deposition as scaffold for improved lithium-sulfur batteries , 2019, Journal of Nanoparticle Research.

[15]  Jianhua Liu,et al.  Promoting polysulfide conversion by V2O3 hollow sphere for enhanced lithium-sulfur battery , 2019, Applied Surface Science.

[16]  Xiangwu Zhang,et al.  Recent progress in polymer materials for advanced lithium-sulfur batteries , 2019, Progress in Polymer Science.

[17]  L. Giebeler,et al.  Metal-based nanostructured materials for advanced lithium–sulfur batteries , 2018 .

[18]  Brij Kishore,et al.  Composites of Sulfur-Titania Nanotubes Prepared by a Facile Solution Infiltration Route as Cathode Material in Lithium-Sulfur Battery. , 2018, Journal of nanoscience and nanotechnology.

[19]  Yayuan Liu,et al.  Quantitative investigation of polysulfide adsorption capability of candidate materials for Li-S batteries , 2018, Energy Storage Materials.

[20]  Arumugam Manthiram,et al.  Progress on the Critical Parameters for Lithium–Sulfur Batteries to be Practically Viable , 2018, Advanced Functional Materials.

[21]  Xingxing Gu,et al.  Recent development of metal compound applications in lithium–sulphur batteries , 2018 .

[22]  Qiang Zhang,et al.  Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries , 2017 .

[23]  Xiaofei Yang,et al.  LiNO3-free electrolyte for Li-S battery: A solvent of choice with low Ksp of polysulfide and low dendrite of lithium , 2017 .

[24]  Jiehua Liu,et al.  Advanced chemical strategies for lithium-sulfur batteries: A review , 2017 .

[25]  Huan-Huan Li,et al.  Sulfur/alumina/polypyrrole ternary hybrid material as cathode for lithium-sulfur batteries , 2017 .

[26]  Martin Winter,et al.  Lithium ion, lithium metal, and alternative rechargeable battery technologies: the odyssey for high energy density , 2017, Journal of Solid State Electrochemistry.

[27]  B. Satpati,et al.  Hydrothermal synthesis of polyaniline intercalated vanadium oxide xerogel hybrid nanocomposites: effective control of morphology and structural characterization , 2017 .

[28]  Qiang Zhang,et al.  Nanostructured Metal Oxides and Sulfides for Lithium–Sulfur Batteries , 2017, Advanced materials.

[29]  Yan‐Bing He,et al.  Suppressing Self-Discharge and Shuttle Effect of Lithium-Sulfur Batteries with V2 O5 -Decorated Carbon Nanofiber Interlayer. , 2017, Small.

[30]  Fumin Zhang,et al.  Facile assembly of a S@carbon nanotubes/polyaniline/graphene composite for lithium–sulfur batteries , 2017 .

[31]  Shi-gang Lu,et al.  A review of atomic layer deposition providing high performance lithium sulfur batteries , 2017 .

[32]  Ke Li,et al.  Advanced Separators for Lithium-Ion and Lithium-Sulfur Batteries: A Review of Recent Progress. , 2016, ChemSusChem.

[33]  M. Naebe,et al.  A review of recent developments in rechargeable lithium-sulfur batteries. , 2016, Nanoscale.

[34]  Yan Xu,et al.  Hollow porous SiO2 nanobelts containing sulfur for long-life lithium–sulfur batteries , 2016 .

[35]  Guangyuan Zheng,et al.  Balancing surface adsorption and diffusion of lithium-polysulfides on nonconductive oxides for lithium–sulfur battery design , 2016, Nature Communications.

[36]  J. Janek,et al.  Tuning Transition Metal Oxide–Sulfur Interactions for Long Life Lithium Sulfur Batteries: The “Goldilocks” Principle , 2016 .

[37]  D. Aurbach,et al.  Review on Li‐Sulfur Battery Systems: an Integral Perspective , 2015 .

[38]  Q. Qu,et al.  Strong Surface‐Bound Sulfur in Conductive MoO2 Matrix for Enhancing Li–S Battery Performance , 2015 .

[39]  Shaogang Wang,et al.  A high-density graphene-sulfur assembly: a promising cathode for compact Li-S batteries. , 2015, Nanoscale.

[40]  R. Li,et al.  Nanoscale stabilization of Li–sulfur batteries by atomic layer deposited Al2O3 , 2014 .

[41]  G. Shi,et al.  Performance enhancement of a graphene–sulfur composite as a lithium–sulfur battery electrode by coating with an ultrathin Al2O3 film via atomic layer deposition , 2014 .

[42]  Li-Jun Wan,et al.  Lithium-sulfur batteries: electrochemistry, materials, and prospects. , 2013, Angewandte Chemie.

[43]  Xiaogang Han,et al.  Reactivation of dissolved polysulfides in Li–S batteries based on atomic layer deposition of Al2O3 in nanoporous carbon cloth , 2013 .

[44]  Jung Tae Lee,et al.  Plasma‐Enhanced Atomic Layer Deposition of Ultrathin Oxide Coatings for Stabilized Lithium–Sulfur Batteries , 2013 .

[45]  Shengping Wang,et al.  Preparation and electrochemical performance of sulfur-alumina cathode material for lithium-sulfur batteries , 2013 .

[46]  Yan Zhao,et al.  One-step synthesis of branched sulfur/polypyrrole nanocomposite cathode for lithium rechargeable batteries , 2012 .

[47]  Qian Zhang,et al.  A hierarchical architecture S/MWCNT nanomicrosphere with large pores for lithium sulfur batteries. , 2012, Physical chemistry chemical physics : PCCP.

[48]  Chunsheng Wang,et al.  Sulfur-impregnated disordered carbon nanotubes cathode for lithium-sulfur batteries. , 2011, Nano letters.

[49]  Xingcheng Xiao,et al.  Ultrathin Multifunctional Oxide Coatings for Lithium Ion Batteries , 2011, Advanced materials.

[50]  Li Li,et al.  Sulfur/Polythiophene with a Core/Shell Structure: Synthesis and Electrochemical Properties of the Cathode for Rechargeable Lithium Batteries , 2011 .

[51]  K. W. Kim,et al.  Electrochemical properties of sulfur electrode containing nano Al2O3 for lithium/sulfur cell , 2007 .

[52]  L. O’Dell,et al.  A 27Al MAS NMR study of a sol–gel produced alumina: Identification of the NMR parameters of the θ-Al2O3 transition alumina phase , 2007 .

[53]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[54]  I. Sobrados,et al.  Thermal Evolution of Transitional Aluminas Followed by NMR and IR Spectroscopies , 1999 .

[55]  S. Heřmánek,et al.  27Al NMR behavior of aluminum alkoxides , 1984 .

[56]  J. Shapter,et al.  Recent progress in sulfur cathodes for application to lithium–sulfur batteries , 2021 .

[57]  Meenakshi,et al.  Synthesis, spectroscopic [IR, (1H, 13C, 27Al) NMR] and mass spectrometric studies of aluminium(III) complexes containing O- and N-chelating Schiff bases , 2015 .

[58]  J. Tarascon,et al.  Towards greener and more sustainable batteries for electrical energy storage. , 2015, Nature chemistry.