Analysis for sulfur compounds in lipid extracts from the orgueil meteorite

Solvent extracts of the Orgueil carbonaceous meteorite were investigated by thin-layer chromatography, ultraviolet, infrared, and mass spectrometry, and by ultramicro elemental analysis for sulfur. Long chain thiols were absent but trace amounts of open-chain sulfides and some heterocyclic compounds containing sulfur appear to be present in the meteorite lipid fraction. The conditions for the formation of the sulfur compounds are in agreement with the generally accepted concepts regarding the environment of the meteorite parent body (ies). The meteorite lipid fraction appears to differ in part from petroleum.

[1]  G. Mamikunian,et al.  Organic constituents of the carbonaceous chondrites , 1963, Life sciences and space research.

[2]  W. Meinschein,et al.  AQUEOUS, LOW TEMPERATURE ENVIRONMENT OF THE ORGUEIL METEORITE PARENT BODY , 1963, Annals of the New York Academy of Sciences.

[3]  A. W. Horton THE MECHANISM OF THE REACTIONS OF HYDROCARBONS WITH SULFUR1 , 1949 .

[4]  U. Colombo,et al.  Optical Activity in Saponified Organic Matter Isolated from the Interior of the Orgueil Meteorite , 1964, Nature.

[5]  R. Hayatsu,et al.  Optical ActivitY in the Orgueil Meteorite , 1965, Science.

[6]  J. Oró,et al.  Free Amino-Acids on Human Fingers: The Question of Contamination in Microanalysis , 1965, Nature.

[7]  L. Gustafsson Determination of ultramicro amounts of sulphate as methylene blue—I: The colour reaction , 1960 .

[8]  Egon T. Degens,et al.  Organic compounds in stony meteorites , 1963 .

[9]  I. Lorant Über eine neue colorimetrische Mikromethode zur Bestimmung des Schwefels in Sulfiden, Sulfaten usw. , 1929 .

[10]  E. H. Farmer Certain fundamental concepts relating to non-polar mechanisms in oleflnic systems , 1947 .

[11]  G. Boato THE ISOTOPIC COMPOSITION OF HYDROGEN AND CARBON IN THE CARBONACEOUS CHONDRITES , 1954 .

[12]  B. Nagy,et al.  Long-chain fatty acids from the orgueil meteorite , 1963 .

[13]  C. J. Thompson,et al.  Identification of Low-Boiling Sulfur Compounds in Agha Jari Crude Oil by Gas-Liquid Chromatography , 1958 .

[14]  C. J. Thompson,et al.  Identification of some chain sulfides in a Wasson, Texas, crude oil distillate boiling from 111/sup 0/ to 150/sup 0/C , 1964 .

[15]  C. J. Thompson,et al.  Separation of Sulfur Compounds from Petroleum , 1955 .

[16]  C. Hinshelwood,et al.  707. The reaction between paraffin hydrocarbons and sulphur vapour , 1949 .

[17]  B. Vallee,et al.  INSTRUMENTATION AND PRINCIPLES OF FLAME SPECTROMETRY I. MULTICHANNEL FLAME SPECTROMETER , 1956 .

[18]  E. Anders ON THE ORIGIN OF CARBONACEOUS CHONDRITES * , 1963, Annals of the New York Academy of Sciences.

[19]  R. Elofson,et al.  Electron spin resonance studies of organic matter in the Orgueil meteorite , 1965 .

[20]  H. Urey Meteorites and the Moon , 1965, Science.

[21]  P. Hamilton Amino-acids on Hands , 1965, Nature.

[22]  K. Turekian,et al.  The investigation of the geographical and vertical distribution of several trace elements in sea water using neutron activation analysis , 1965 .

[23]  C. J. Thompson,et al.  Analytical Separation and Identification of Sulfur Compounds in Petroleum Distillate Boiling to 100° C. , 1956 .

[24]  H. Nishita,et al.  Microestimation of Sulfur in Plant Materials, Soils, and Irrigation Waters , 1952 .

[25]  H. B. Wiik,et al.  The chemical composition of some stony meteorites , 1956 .

[26]  B. Nagy,et al.  Identification of elementary sulfur and sulfur compounds in lipid extracts by thin-layer chromatography , 1965, Journal of the American Oil Chemists' Society.

[27]  G. Hodgson,et al.  Evidence for Porphyrins in the Orgueil Meteorite , 1964, Nature.

[28]  B. Nagy,et al.  MASS SPECTROSCOPIC ANALYSIS OF THE ORGUEIL METEORITE: EVIDENCE FOR BIOGENIC HYDROCARBONS , 1961 .

[29]  J. Vallentyne Two aspects of the geochemistry of amino acids. , 1965 .

[30]  H. M. Smith,et al.  Elemental Sulfur in Crude Oil , 1952 .

[31]  W. Meinschein,et al.  EVIDENCE IN METEORITES OF FORMER LIFE: THE ORGANIC COMPOUNDS IN CARBONACEOUS CHONDRITES ARE SIMILAR TO THOSE FOUND IN MARINE SEDIMENTS , 1963, Annals of the New York Academy of Sciences.

[32]  Ryoichi Hayatsu,et al.  Orgueil Meteorite: Organic Nitrogen Contents , 1964, Science.

[33]  H. Urey On the Dissipation of Gas and Volatilized Elements from Protoplanets. , 1954 .

[34]  E. Anders,et al.  Chemical Evolution of the Carbonaceous Chondrites , 1962 .

[35]  G. Varsányi,et al.  Absorption spectra in the ultraviolet and visible region : a theoretical and technical introduction , 1962 .