3D Printing of MXenes-Based Electrodes for Energy Storage Applications

Energy storage devices (ESD) including batteries, and supercapacitors are becoming progressively imperative in the transition to a renewable energy future, as they enable the integration of intermittent renewable sources into the grid and provide backup power during outages. There are already reviews available on various energy storage materials and systems. However, the challenges in the choice of suitable materials and fabrication technology are yet to establish for the commercialization of affordable and efficient ESDs in every aspect of practical needs. Therefore, we realize that the review on the newly developed two-dimensional (2D) MXenes-based energy storage electrodes and devices fabricated through suitably advanced 3D printing technology is the need of the hour, and will be able to attract broad audiences of the related field. MXenes are a class of 2D materials having lamella structures that have shown great promise for energy storage applications due to their versatile redox behavior, high surface area, high electrical conductivity, and ability to accommodate intercalated ions. However, the processing of 2D MXenes suffers from serious agglomeration due to weak Van der Waals attraction and reduces its actual energy storage performances. In a few recent studies, it is observed that advanced 3D printing has enabled the fabrication of MXenes with complex and customized geometries, opening up new possibilities for developing high-performance energy storage devices. Therefore, this review is important for a comprehensive discussion on this topic. So, in this review, we discuss the recent breakthroughs in 3D printed MXene-based batteries and supercapacitors, the advantages of using 3D printing for the fabrication of tailor-designed MXenes-based ESDs, existing challenges, and the opportunities available for further exploration towards the successful commercialization of ESDs. Overall, this review is an insightful articulation for the future seeking to stay at the forefront of this exciting and rapidly-expanding field.

[1]  Zhongxue Chen,et al.  MXene-Based Materials for Multivalent Metal-Ion Batteries , 2023, Batteries.

[2]  P. Samorí,et al.  MXenes: from past to future perspectives , 2023, Chemical Engineering Journal.

[3]  Chuankai Fu,et al.  Tailoring electronic-ionic local environment for solid-state Li-O2 battery by engineering crystal structure , 2022, Science advances.

[4]  Prativa Das,et al.  A Self-powered Triboelectric MXene-based 3D-printed Wearable Physiological Biosignal Sensing System for On-demand, Wireless, and Real-time Health Monitoring , 2022, Nano Energy.

[5]  A. Al-Gheethi,et al.  Prospects of MXenes in energy storage applications. , 2022, Chemosphere.

[6]  H. Park,et al.  A New Era of Integrative Ice Frozen Assembly into Multiscale Architecturing of Energy Materials , 2022, Advanced Functional Materials.

[7]  N. Dunne,et al.  3D Printing of a Graphene-Modified Photopolymer Using Stereolithography for Biomedical Applications: A Study of the Polymerization Reaction , 2022, International journal of bioprinting.

[8]  M. I. Ul Haq,et al.  3D printing – A review of processes, materials and applications in industry 4.0 , 2022, Sustainable Operations and Computers.

[9]  Jingyu Sun,et al.  Concurrent realization of dendrite-free anode and high-loading cathode via 3D printed N-Ti3C2 MXene framework toward advanced Li–S full batteries , 2021 .

[10]  Dong Yang,et al.  A Multi‐Scale Structural Engineering Strategy for High‐Performance MXene Hydrogel Supercapacitor Electrode , 2021, Advanced science.

[11]  Randy Joy Magno Ventayen,et al.  3d Printing: Basic principals and applications , 2021, Materials Today: Proceedings.

[12]  M. Pumera,et al.  MXene and MoS3−x Coated 3D‐Printed Hybrid Electrode for Solid‐State Asymmetric Supercapacitor , 2021, Small methods.

[13]  Hao Li,et al.  Progress and Perspective: MXene and MXene‐Based Nanomaterials for High‐Performance Energy Storage Devices , 2021, Advanced Electronic Materials.

[14]  Mohd Javaid,et al.  Impact of 3D Printing on the environment: A literature-based study , 2021 .

[15]  Jingyu Sun,et al.  Universal in Situ Crafted MOx-MXene Heterostructures as Heavy and Multifunctional Hosts for 3D-Printed Li-S Batteries. , 2020, ACS nano.

[16]  James O. Thostenson,et al.  Ti3C2Tx MXene-Reduced Graphene Oxide Composite Electrodes for Stretchable Supercapacitors. , 2020, ACS nano.

[17]  R. Deivanayagam,et al.  3D Printing of Electrochemical Energy Storage Devices: A Review of Printing Techniques and Electrode/Electrolyte Architectures , 2020 .

[18]  Xiaowei Yin,et al.  Phase Transition Induced Unusual Electrochemical Performance of V2CTX MXene for Aqueous Zinc Hybrid-Ion Battery. , 2020, ACS nano.

[19]  Shubin Yang,et al.  Single Zinc Atoms Immobilized on MXene (Ti3C2Clx) Layers toward Dendrite-Free Lithium Metal Anodes. , 2020, ACS nano.

[20]  Zhengnan Tian,et al.  3D Printing of Porous Nitrogen-Doped Ti3C2 MXene Scaffolds for High-Performance Sodium-Ion Hybrid Capacitors. , 2020, ACS nano.

[21]  J. Orangi,et al.  3D Printing of Additive-Free 2D Ti3C2Tx (MXene) Ink for Fabrication of Micro-Supercapacitors with Ultra-High Energy Densities. , 2019, ACS nano.

[22]  Peng Zhang,et al.  Flexible 3D Porous MXene Foam for High-Performance Lithium-Ion Batteries. , 2019, Small.

[23]  Haodong Shi,et al.  Conducting and Lithiophilic MXene/Graphene Frameworks for High-Capacity, Dendrite-Free Lithium-Metal Anodes. , 2019, ACS nano.

[24]  P. Bhattacharya,et al.  Carambola-shaped SnO2 wrapped in carbon nanotube network for high volumetric capacity and improved rate and cycle stability of lithium ion battery , 2019, Chemical Engineering Journal.

[25]  Yuanlong Shao,et al.  Versatile N‐Doped MXene Ink for Printed Electrochemical Energy Storage Application , 2019, Advanced Energy Materials.

[26]  S. Haigh,et al.  3D Printing of Freestanding MXene Architectures for Current‐Collector‐Free Supercapacitors , 2019, Advanced materials.

[27]  Yang Gao,et al.  Highly Stretchable and Self‐Healable MXene/Polyvinyl Alcohol Hydrogel Electrode for Wearable Capacitive Electronic Skin , 2019, Advanced Electronic Materials.

[28]  J. Coleman,et al.  Additive-free MXene inks and direct printing of micro-supercapacitors , 2019, Nature Communications.

[29]  Xiaolong Li,et al.  Engineering 3D Ion Transport Channels for Flexible MXene Films with Superior Capacitive Performance , 2019, Advanced Functional Materials.

[30]  Y. Gogotsi,et al.  Control of MXenes’ electronic properties through termination and intercalation , 2019, Nature Communications.

[31]  Guoxiu Wang,et al.  2D Metal Carbides and Nitrides (MXenes) as High‐Performance Electrode Materials for Lithium‐Based Batteries , 2018, Advanced Energy Materials.

[32]  Mingjie Liu,et al.  Conductive Hydrogels as Smart Materials for Flexible Electronic Devices. , 2018, Chemistry.

[33]  Zhe Wang,et al.  Laminated Object Manufacturing of 3D‐Printed Laser‐Induced Graphene Foams , 2018, Advanced materials.

[34]  Micah J. Green,et al.  Surface-agnostic highly stretchable and bendable conductive MXene multilayers , 2018, Science Advances.

[35]  Feng Zhang,et al.  3D printing technologies for electrochemical energy storage , 2017 .

[36]  E. Toyserkani,et al.  Binder-jet powder-bed additive manufacturing (3D printing) of thick graphene-based electrodes , 2017 .

[37]  X. Bao,et al.  Ti3C2 MXene-Derived Sodium/Potassium Titanate Nanoribbons for High-Performance Sodium/Potassium Ion Batteries with Enhanced Capacities. , 2017, ACS nano.

[38]  Ananth Dodabalapur,et al.  Inkjet-Printed Lithium-Sulfur Microcathodes for All-Printed, Integrated Nanomanufacturing. , 2017, Small.

[39]  Y. Gogotsi,et al.  Dispersions of Two-Dimensional Titanium Carbide MXene in Organic Solvents , 2017 .

[40]  Hang Zhou,et al.  3D Printing of Carbon Nanotubes-Based Microsupercapacitors. , 2017, ACS applied materials & interfaces.

[41]  Kejie Zhao,et al.  Printing 3D Gel Polymer Electrolyte in Lithium-Ion Microbattery Using Stereolithography , 2017 .

[42]  Peter Enoksson,et al.  Solidification of 3D Printed Nanofibril Hydrogels into Functional 3D Cellulose Structures , 2016 .

[43]  Jinbao Guo,et al.  Fabrication of highly conductive graphene flexible circuits by 3D printing , 2016 .

[44]  Ricky D. Wildman,et al.  Inkjet printing of polyimide insulators for the 3D printing of dielectric materials for microelectronic applications , 2016 .

[45]  Wei Liu,et al.  3D Porous Sponge‐Inspired Electrode for Stretchable Lithium‐Ion Batteries , 2016, Advanced materials.

[46]  Qifa Zhou,et al.  Three dimensional printing of high dielectric capacitor using projection based stereolithography method , 2016 .

[47]  Feng Zhang,et al.  3D Printing of Graphene Aerogels. , 2016, Small.

[48]  K. Zaghib,et al.  Smart materials for energy storage in Li-ion batteries , 2016 .

[49]  Z. Eckel,et al.  Additive manufacturing of polymer-derived ceramics , 2016, Science.

[50]  Eric Coatanéa,et al.  Comparative environmental impacts of additive and subtractive manufacturing technologies , 2016 .

[51]  Nicolas Gardan,et al.  Topological optimization of internal patterns and support in additive manufacturing , 2015 .

[52]  John A Rogers,et al.  Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries , 2015, Proceedings of the National Academy of Sciences.

[53]  Rong Cheng,et al.  Laminated fabrication of 3D queue micro-electrode and its application in micro-EDM , 2015 .

[54]  Jürgen Groll,et al.  Fiber reinforcement during 3D printing , 2015 .

[55]  P. Azimi,et al.  Ultrafine particle emissions from desktop 3D printers , 2013 .

[56]  Ryan B. Wicker,et al.  3D printer selection: A decision-making evaluation and ranking model , 2013 .

[57]  Ratnadeep Paul,et al.  Error Minimization in Layered Manufacturing Parts by Stereolithography File Modification Using a Vertex Translation Algorithm , 2013 .

[58]  S. S. Pande,et al.  Optimum part orientation in Rapid Prototyping using genetic algorithm , 2012 .

[59]  Andreas Winter,et al.  Three‐Dimensional Nitrogen and Boron Co‐doped Graphene for High‐Performance All‐Solid‐State Supercapacitors , 2012, Advanced materials.

[60]  Shuhong Yu,et al.  Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. , 2012, ACS nano.

[61]  Igor Drstvenšek,et al.  Speed and accuracy evaluation of additive manufacturing machines , 2011 .

[62]  G. Jabbour,et al.  Inkjet Printing—Process and Its Applications , 2010, Advanced materials.

[63]  Daniel A. Steingart,et al.  A super ink jet printed zinc–silver 3D microbattery , 2009 .

[64]  J. Czyżewski,et al.  Rapid prototyping of electrically conductive components using 3D printing technology , 2009 .

[65]  Zhiyu Jiang,et al.  Electrochemical properties of LiCoO2 thin film electrode prepared by ink-jet printing technique , 2008 .

[66]  Luigi Maria Galantucci,et al.  Study of compression properties of topologically optimized FDM made structured parts , 2008 .

[67]  N. Venkata Reddy,et al.  Part deposition orientation studies in layered manufacturing , 2007 .

[68]  X. Y. Kou,et al.  Heterogeneous object modeling: A review , 2007, Comput. Aided Des..

[69]  Sanjay B. Joshi,et al.  Parametric error modeling and software error compensation for rapid prototyping , 2003 .

[70]  Debasish Dutta,et al.  A review of process planning techniques in layered manufacturing , 2000 .