Interface tension-induced synthesis of monodispersed mesoporous carbon hemispheres.

Here we report a novel interface tension-induced shrinkage approach to realize the synthesis of monodispersed asymmetrical mesoporous carbon nanohemispheres. We demonstrate that the products exhibit very uniform hemispherical morphology (130 × 60 nm) and are full of ordered mesopores, endowing them high surface areas and uniform pore sizes. These monodispersed mesoporous carbon hemispheres display excellent dispersibility in water for a long period without any aggregation. Moreover, a brand new feature of the mesoporous carbon materials has been observed for the first time: these monodispersed mesoporous carbon hemispheres show excellent thermal generation property under a NIR irradiation.

[1]  Xin Du,et al.  Label-free dendrimer-like silica nanohybrids for traceable and controlled gene delivery. , 2014, Biomaterials.

[2]  Y. Yamauchi,et al.  Tailored design of functional nanoporous carbon materials toward fuel cell applications , 2014 .

[3]  Abdullah M. Asiri,et al.  Dual-pore mesoporous carbon@silica composite core-shell nanospheres for multidrug delivery. , 2014, Angewandte Chemie.

[4]  Yu Chen,et al.  Construction of homogenous/heterogeneous hollow mesoporous silica nanostructures by silica-etching chemistry: principles, synthesis, and applications. , 2014, Accounts of chemical research.

[5]  Qiang Sun,et al.  Design of three-dimensional porous carbon materials: from static to dynamic skeletons. , 2013, Angewandte Chemie.

[6]  D. Zhao,et al.  Spatially Confined Fabrication of Core−Shell Gold Nanocages@Mesoporous Silica for Near-Infrared Controlled Photothermal Drug Release , 2013 .

[7]  S. Gruner,et al.  Multicompartment Mesoporous Silica Nanoparticles with Branched Shapes: An Epitaxial Growth Mechanism , 2013, Science.

[8]  Nicholas D. Petkovich,et al.  Controlling macro- and mesostructures with hierarchical porosity through combined hard and soft templating. , 2013, Chemical Society reviews.

[9]  Lei Liu,et al.  Direct synthesis of ordered mesoporous carbons. , 2013, Chemical Society reviews.

[10]  Andreas Walther,et al.  Janus particles: synthesis, self-assembly, physical properties, and applications. , 2013, Chemical reviews.

[11]  Rongqin Huang,et al.  Multifunctional mesoporous silica-coated graphene nanosheet used for chemo-photothermal synergistic targeted therapy of glioma. , 2013, Journal of the American Chemical Society.

[12]  S. Qiao,et al.  pH-responsive nutraceutical-mesoporous silica nanoconjugates with enhanced colloidal stability. , 2013, Angewandte Chemie.

[13]  Andrew J. Binder,et al.  Controlled synthesis of mesoporous carbon nanostructures via a "silica-assisted" strategy. , 2013, Nano letters.

[14]  Fong-Yu Cheng,et al.  Near‐Infrared Light‐Responsive Intracellular Drug and siRNA Release Using Au Nanoensembles with Oligonucleotide‐Capped Silica Shell , 2012, Advanced materials.

[15]  Qiang Sun,et al.  Chemical Synthesis of Carbon Materials with Intriguing Nanostructure and Morphology , 2012 .

[16]  Limin Wu,et al.  Fabrication, properties and applications of Janus particles. , 2012, Chemical Society reviews.

[17]  Zongxi Li,et al.  Mesoporous silica nanoparticles in biomedical applications. , 2012, Chemical Society reviews.

[18]  D. Zhao,et al.  Carbon Materials for Chemical Capacitive Energy Storage , 2011, Advanced materials.

[19]  Qiang Sun,et al.  Temperature-programmed precise control over the sizes of carbon nanospheres based on benzoxazine chemistry. , 2011, Journal of the American Chemical Society.

[20]  D. Zhao,et al.  A low-concentration hydrothermal synthesis of biocompatible ordered mesoporous carbon nanospheres with tunable and uniform size. , 2010, Angewandte Chemie.

[21]  O. Terasaki,et al.  Spatially and size selective synthesis of Fe-based nanoparticles on ordered mesoporous supports as highly active and stable catalysts for ammonia decomposition. , 2010, Journal of the American Chemical Society.

[22]  D. Zhao,et al.  Growth of Single-Crystal Mesoporous Carbons with Im3̄m Symmetry , 2010 .

[23]  A. B. Fuertes,et al.  Synthesis of Uniform Mesoporous Carbon Capsules by Carbonization of Organosilica Nanospheres , 2010 .

[24]  L. J. Mueller,et al.  pH-responsive nanogated ensemble based on gold-capped mesoporous silica through an acid-labile acetal linker. , 2010, Journal of the American Chemical Society.

[25]  A. Stein,et al.  Site-specific functionalization of anisotropic nanoparticles: from colloidal atoms to colloidal molecules. , 2009, Journal of the American Chemical Society.

[26]  C. Liang,et al.  Mesoporous carbon materials: synthesis and modification. , 2008, Angewandte Chemie.

[27]  Ying Wan,et al.  On the controllable soft-templating approach to mesoporous silicates. , 2007, Chemical reviews.

[28]  Yiying Wu,et al.  Composite mesostructures by nano-confinement , 2004, Nature materials.

[29]  Bozhi Tian,et al.  Morphology development of mesoporous materials: a colloidal phase separation mechanism , 2004 .

[30]  Mark E. Davis Ordered porous materials for emerging applications , 2002, Nature.

[31]  D. Gu,et al.  Synthesis of non-siliceous mesoporous oxides. , 2014, Chemical Society reviews.