Unraveling Photostability of Mixed Cation Perovskite Films in Extreme Environment

Organometal halide perovskites exhibit a bright future for applications in solar cells, as efficiency has achieved over 22%. The long-term stability remains a major obstacle for commercialization. ...

[1]  M. Roeffaers,et al.  Degradation of Methylammonium Lead Iodide Perovskite Structures through Light and Electron Beam Driven Ion Migration , 2016, The journal of physical chemistry letters.

[2]  Sang Il Seok,et al.  Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells. , 2014, Nature materials.

[3]  Y. Qi,et al.  Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions. , 2017, ACS applied materials & interfaces.

[4]  A. Pucci,et al.  Infrared Spectroscopic Study of Vibrational Modes in Methylammonium Lead Halide Perovskites. , 2015, The journal of physical chemistry letters.

[5]  T. Buonassisi,et al.  Promises and challenges of perovskite solar cells , 2017, Science.

[6]  Meng-Che Tsai,et al.  Organometal halide perovskite solar cells: degradation and stability , 2016 .

[7]  Neha Arora,et al.  Perovskite solar cells with CuSCN hole extraction layers yield stabilized efficiencies greater than 20% , 2017, Science.

[8]  Wei Zhang,et al.  Photo-induced halide redistribution in organic–inorganic perovskite films , 2016, Nature Communications.

[9]  Dieter Neher,et al.  Approaching the fill factor Shockley–Queisser limit in stable, dopant-free triple cation perovskite solar cells , 2017 .

[10]  M. Johnston,et al.  Charge‐Carrier Dynamics and Mobilities in Formamidinium Lead Mixed‐Halide Perovskites , 2015, Advanced materials.

[11]  Yang Yang,et al.  The Emergence of the Mixed Perovskites and Their Applications as Solar Cells , 2017 .

[12]  U. Rothlisberger,et al.  Stabilization of the Perovskite Phase of Formamidinium Lead Triiodide by Methylammonium, Cs, and/or Rb Doping. , 2017, The journal of physical chemistry letters.

[13]  Laura M Herz,et al.  High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites , 2013, Advanced materials.

[14]  Dan Oron,et al.  Self‐Healing Inside APbBr3 Halide Perovskite Crystals , 2018, Advances in Materials.

[15]  Yang Yang,et al.  Make perovskite solar cells stable , 2017, Nature.

[16]  T. Bein,et al.  Stabilization of the Trigonal High-Temperature Phase of Formamidinium Lead Iodide. , 2015, The journal of physical chemistry letters.

[17]  Q. Gong,et al.  Dual‐Source Precursor Approach for Highly Efficient Inverted Planar Heterojunction Perovskite Solar Cells , 2017, Advanced materials.

[18]  Lijia Liu,et al.  Tracking the formation of methylammonium lead triiodide perovskite , 2015 .

[19]  Yongli Gao,et al.  Light-Induced Degradation of CH3NH3PbI3 Hybrid Perovskite Thin Film , 2017 .

[20]  N. Koch,et al.  Impact of White Light Illumination on the Electronic and Chemical Structures of Mixed Halide and Single Crystal Perovskites , 2017 .

[21]  E. Sargent,et al.  Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals , 2015, Science.

[22]  Iris Visoly-Fisher,et al.  Temperature- and Component-Dependent Degradation of Perovskite Photovoltaic Materials under Concentrated Sunlight. , 2015, The journal of physical chemistry letters.

[23]  M. Grätzel.  The light and shade of perovskite solar cells. , 2014, Nature materials.

[24]  Mohammad Khaja Nazeeruddin,et al.  One-Year stable perovskite solar cells by 2D/3D interface engineering , 2017, Nature Communications.

[25]  Aslihan Babayigit,et al.  Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite , 2015 .

[26]  Jinsong Huang,et al.  Grain boundary dominated ion migration in polycrystalline organic–inorganic halide perovskite films , 2016 .

[27]  T. Miyasaka,et al.  Stabilizing the Efficiency Beyond 20% with a Mixed Cation Perovskite Solar Cell Fabricated in Ambient Air under Controlled Humidity , 2018 .

[28]  Anders Hagfeldt,et al.  Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5ee03874j Click here for additional data file. , 2016, Energy & environmental science.

[29]  T. Bein,et al.  Impact of Rubidium and Cesium Cations on the Moisture Stability of Multiple-Cation Mixed-Halide Perovskites , 2017 .

[30]  Joshua M. Pearce,et al.  A Review of Solar Photovoltaic Levelized Cost of Electricity , 2011 .

[31]  C. O’Carroll,et al.  In Situ Observation of Light Illumination-Induced Degradation in Organometal Mixed-Halide Perovskite Films. , 2018, ACS applied materials & interfaces.

[32]  Ullrich Steiner,et al.  Perovskite Solar Cell Stability in Humid Air: Partially Reversible Phase Transitions in the PbI2‐CH3NH3I‐H2O System , 2016 .

[33]  Dong Uk Lee,et al.  Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells , 2017, Science.

[34]  C. Brabec,et al.  Photoinduced degradation of methylammonium lead triiodide perovskite semiconductors , 2016 .

[35]  Claudine Katan,et al.  Light-activated photocurrent degradation and self-healing in perovskite solar cells , 2016, Nature Communications.

[36]  Weixin Huang,et al.  Heat- and Gas-Induced Transformation in CH3NH3PbI3 Perovskites and Its Effect on the Efficiency of Solar Cells , 2017 .

[37]  Ursula Rothlisberger,et al.  Entropic stabilization of mixed A-cation ABX3 metal halide perovskites for high performance perovskite solar cells , 2016 .

[38]  J. Zhang,et al.  Mechanisms for light induced degradation in MAPbI3 perovskite thin films and solar cells , 2016 .

[39]  Liuyang Sun,et al.  Impact of grain boundaries on efficiency and stability of organic-inorganic trihalide perovskites , 2017, Nature Communications.

[40]  J. Rappich,et al.  Unraveling the Light‐Induced Degradation Mechanisms of CH3NH3PbI3 Perovskite Films , 2017 .

[41]  Anders Hagfeldt,et al.  Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance , 2016, Science.

[42]  Henry J Snaith,et al.  Metal-halide perovskites for photovoltaic and light-emitting devices. , 2015, Nature nanotechnology.

[43]  M. Grätzel,et al.  Title: Long-Range Balanced Electron and Hole Transport Lengths in Organic-Inorganic CH3NH3PbI3 , 2017 .

[44]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[45]  H. Boyen,et al.  A Universal Deposition Protocol for Planar Heterojunction Solar Cells with High Efficiency Based on Hybrid Lead Halide Perovskite Families , 2016, Advanced materials.

[46]  Nripan Mathews,et al.  Formamidinium-Containing Metal-Halide: An Alternative Material for Near-IR Absorption Perovskite Solar Cells , 2014 .

[47]  Thomas Rath,et al.  The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers. , 2015, Angewandte Chemie.