Self-assembling resists for nanolithography

In this paper we present our approach for integrating block copolymers into the lithographic process so as to enable molecular-level control over the dimensions and shapes of nanoscale patterned resist features and simultaneously retain essential process attributes such as pattern perfection, registration, and the ability to create non-regular device-oriented structures. Combining self-assembling materials with advanced lithographic tools may allow current manufacturing techniques to be extended to the scale of 10 nm and below and meet the long-term requirements detailed in the International Technology Roadmap for Semiconductors (2004)

[1]  Paul F. Nealey,et al.  Using Self-Assembled Monolayers Exposed to X-rays To Control the Wetting Behavior of Thin Films of Diblock Copolymers , 2000 .

[2]  Juan J. de Pablo,et al.  Symmetric diblock copolymer thin films confined between homogeneous and patterned surfaces: Simulations and theory , 2000 .

[3]  裕幸 飯田,et al.  International Technology Roadmap for Semiconductors 2003の要求清浄度について - シリコンウエハ表面と雰囲気環境に要求される清浄度, 分析方法の現状について - , 2004 .

[4]  Grant D. Smith,et al.  Phase separation in binary mixtures containing polymers: A quantitative comparison of single‐chain‐in‐mean‐field simulations and computer simulations of the corresponding multichain systems , 2005 .

[5]  E. W. Edwards,et al.  Precise Control over Molecular Dimensions of Block‐Copolymer Domains Using the Interfacial Energy of Chemically Nanopatterned Substrates , 2004 .

[6]  P. Nealey,et al.  Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates , 2003, Nature.

[7]  Chemical Modification of Self-Assembled Monolayers by Exposure to Soft X-rays in Air , 2000 .

[8]  C. Hawker,et al.  Controlling Polymer-Surface Interactions with Random Copolymer Brushes , 1997, Science.

[9]  Franco Cerrina,et al.  Guided Self-Assembly of Symmetric Diblock Copolymer Films on Chemically Nanopatterned Substrates , 2000 .

[10]  Harun H. Solak,et al.  Sub-50 nm period patterns with EUV interference lithography , 2003 .

[11]  E. W. Edwards,et al.  Directed Assembly of Block Copolymer Blends into Nonregular Device-Oriented Structures , 2005, Science.