Reactivity of 3‐Substituted Fluorobenzenes in Palladium‐ Catalysed Direct Arylations with Aryl Bromides

[1]  R. Rossi,et al.  Cross‐Coupling of Heteroarenes by CH Functionalization: Recent Progress towards Direct Arylation and Heteroarylation Reactions Involving Heteroarenes Containing One Heteroatom , 2014 .

[2]  H. Doucet,et al.  Benzenesulfonyl chlorides: new reagents for access to alternative regioisomers in palladium-catalysed direct arylations of thiophenes , 2014 .

[3]  H. Doucet,et al.  Access to Alternative Regioisomers for Palladium‐Catalysed Direct Arylations of (Benzo)thiophenes , 2013 .

[4]  Tao Yan,et al.  Influence of 1,3‐Difluorobenzene Substituents for Palladium‐Catalyzed Direct Arylations , 2013 .

[5]  I. Larrosa,et al.  Arene-metal π-complexation as a traceless reactivity enhancer for C-H arylation. , 2013, Journal of the American Chemical Society.

[6]  C. Bruneau,et al.  A straightforward access to guaiazulene derivatives using palladium-catalysed sp2 or sp3 C-H bond functionalisation. , 2013, Chemical communications.

[7]  Pixu Li,et al.  Visible-light photoredox in homolytic aromatic substitution: direct arylation of arenes with aryl halides. , 2013, Organic letters.

[8]  Frank Glorius,et al.  C-H bond activation enables the rapid construction and late-stage diversification of functional molecules. , 2013, Nature chemistry.

[9]  G. Aullón,et al.  Highly fluorescent complexes with gold, palladium or platinum linked to perylene through a tetrafluorophenyl group. , 2013, Dalton transactions.

[10]  Huaiqing Zhao,et al.  A macrocyclic aromatic pyridone pentamer as a highly efficient organocatalyst for the direct arylations of unactivated arenes. , 2013, Chemical communications.

[11]  C. Arróniz,et al.  Direct ortho-arylation of ortho-substituted benzoic acids: overriding Pd-catalyzed protodecarboxylation. , 2013, Organic letters.

[12]  F. Ozawa,et al.  A Highly Efficient Catalytic System for Polycondensation of 2,7-Dibromo-9,9-dioctylfluorene and 1,2,4,5-Tetrafluorobenzene via Direct Arylation , 2013 .

[13]  S. Gorelsky Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation , 2013 .

[14]  F. Glorius,et al.  Rhodium(III) und Hexabrombenzol – ein Katalysatorsystem zur gekreuzten dehydrierenden Kupplung einfacher Arene und Heterocyclen mit Arenen mit dirigierenden Gruppen , 2012 .

[15]  F. Glorius,et al.  Rhodium(III) and hexabromobenzene-a catalyst system for the cross-dehydrogenative coupling of simple arenes and heterocycles with arenes bearing directing groups. , 2012, Angewandte Chemie.

[16]  V. Guerchais,et al.  A straightforward access to photochromic diarylethene derivatives via palladium-catalysed direct heteroarylation of 1,2-dichloroperfluorocyclopentene. , 2012, Chemical communications.

[17]  F. Glorius,et al.  Ohne dirigierende Gruppen: übergangsmetallkatalysierte C-H-Aktivierung einfacher Arene , 2012 .

[18]  F. Glorius,et al.  Beyond directing groups: transition-metal-catalyzed C-H activation of simple arenes. , 2012, Angewandte Chemie.

[19]  X. Hou,et al.  Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance. , 2012, Chemical communications.

[20]  J. C. Bernhammer,et al.  Pyrazolin-5-ylidene Palladium(II) Complexes: Synthesis, Characterization, and Application in the Direct Arylation of Pentafluorobenzene , 2012 .

[21]  Abdellah Miloudi,et al.  Palladium‐Based Catalytic System for the Direct C3‐Arylation of Furan‐2‐carboxamides and Thiophene‐2‐carboxamides , 2012 .

[22]  Xingang Zhang,et al.  Pd-catalyzed direct arylation of polyfluoroarenes on water under mild conditions using PPh3 ligand. , 2012, The Journal of organic chemistry.

[23]  L. Ackermann,et al.  Ruthenium-catalyzed C-H bond arylations of arenes bearing removable directing groups via six-membered ruthenacycles. , 2012, Organic letters.

[24]  Zhi Wang,et al.  Discovery of a full-color-tunable fluorescent core framework through direct C-H (hetero)arylation of N-heterocycles. , 2012, Chemistry.

[25]  I. Larrosa,et al.  Carboxylic acids as traceless directing groups for formal meta-selective direct arylation. , 2011, Angewandte Chemie.

[26]  Z. Yao,et al.  Palladium-catalyzed direct CH arylation of unactivated arenes with aryl Halides , 2011 .

[27]  Cédric Fischmeister,et al.  Greener solvents for ruthenium and palladium-catalysed aromatic C–H bond functionalisation , 2011 .

[28]  Da‐Gang Yu,et al.  The catalytic ability of various transition metals in the direct functionalization of aromatic C-H bonds. , 2011, Chemistry.

[29]  David Lapointe,et al.  Predictable and site-selective functionalization of poly(hetero)arene compounds by palladium catalysis. , 2011, The Journal of organic chemistry.

[30]  Hu Li,et al.  Palladium-catalyzed cross-coupling of polyfluoroarenes with simple arenes. , 2011, Organic letters.

[31]  Ye Wei,et al.  Pd(OAc)(2)-catalyzed oxidative C-H/C-H cross-coupling of electron-deficient polyfluoroarenes with simple arenes. , 2010, Journal of the American Chemical Society.

[32]  L. Ackermann,et al.  Mechanistic insight into direct arylations with ruthenium(II) carboxylate catalysts. , 2010, Organic letters.

[33]  Olivier René,et al.  Room-temperature direct arylation of polyfluorinated arenes under biphasic conditions. , 2010, Organic letters.

[34]  Lei Liu,et al.  Pd-catalyzed decarboxylative cross coupling of potassium polyfluorobenzoates with aryl bromides, chlorides, and triflates. , 2010, Organic letters.

[35]  Chang-Liang Sun,et al.  Pd-catalyzed oxidative coupling with organometallic reagents via C-H activation. , 2010, Chemical communications.

[36]  H. Doucet,et al.  Palladium‐Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation , 2010 .

[37]  L. Ackermann,et al.  Übergangsmetallkatalysierte direkte Arylierungen von (Hetero)Arenen durch C‐H‐Bindungsbruch , 2009 .

[38]  A. Kapdi,et al.  Transition-metal-catalyzed direct arylation of (hetero)arenes by C-H bond cleavage. , 2009, Angewandte Chemie.

[39]  R. Rossi,et al.  Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates , 2009 .

[40]  X. Chen,et al.  Palladium(II)‐katalysierte C‐H‐Aktivierung/C‐C‐Kreuzkupplung: Vielseitigkeit und Anwendbarkeit , 2009 .

[41]  jin-quan yu,et al.  Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality. , 2009, Angewandte Chemie.

[42]  O. Daugulis,et al.  Copper-catalyzed arylation and alkenylation of polyfluoroarene C-H bonds. , 2008, Journal of the American Chemical Society.

[43]  O. Daugulis,et al.  Two methods for direct ortho-arylation of benzoic acids. , 2007, Journal of the American Chemical Society.

[44]  V. Gevorgyan,et al.  Direct transition metal-catalyzed functionalization of heteroaromatic compounds. , 2007, Chemical Society reviews.

[45]  T. Satoh,et al.  Catalytic Direct Arylation of Heteroaromatic Compounds , 2007 .

[46]  K. Fagnou,et al.  Mild and general conditions for the cross-coupling of aryl halides with pentafluorobenzene and other perfluoroaromatics. , 2006, Organic letters.

[47]  C. Rowley,et al.  Catalytic intermolecular direct arylation of perfluorobenzenes. , 2006, Journal of the American Chemical Society.

[48]  Delano P. Chong,et al.  Estimation of Hammett sigma constants of substituted benzenes through accurate density-functional calculation of core-electron binding energy shifts , 2005 .

[49]  T. Cantat,et al.  Structural and kinetic effects of chloride ions in the palladium-catalyzed allylic substitutions , 2003 .

[50]  Corwin Hansch,et al.  A survey of Hammett substituent constants and resonance and field parameters , 1991 .