Crystal structures and spectral properties of five-coordinate copper(II) complexes with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdt) and α-diamines: Approximately regular trigonal bipyramidal [Cu(en)(pmdt)](ClO4)2 and highly distorted [Cu(SS-chxn(pmdt)](ClO4)2 (en 1,2-diaminoethane and SS-chxn