Kohlenwasserstoffverbrückte Komplexe, XXV[1] C–C‐Kupplung von anionischen Tricarbonylmangan‐Komplexen cyclischer Polyene mit kationischen Tropylium‐Metallverbindungen; Darstellung und Struktur von (OC)3Mn(μ‐η5:η6‐C7H8–C7H7)M(CO)3, (OC)3Mn(μ‐η5:η6‐C8H10–C7H7)M(CO)3 und (OC)3Mn(μ‐η5:η6‐C8H8–C7H7)M(CO)

Hydrocarbon-Bridged Complexes, XXX. - Nucleophilic Addition of Carbonylmetallates to Cationic Vinyl, Diene, Dienyl and Triene Complexes of Iron, Ruthenium and Cobalt: Di-, Tri-, Tetra- and Pentametallic Complexes with ,- and ,-Hydrocarbon Bridges[Note ][Herrn Professor Ekkehard Lindner zum 60. Geburtstag gewidmet.] The reactions of [Re(CO)5]-, [Ru(CO)2Cp]-, and [Os(CO)4]2- with [Cp2(OC)2Fe2(-CO)(-1:2-CH=CH2)]+, [Cp*Ru(2:4-1,3,7-octatriene)]+, [(OC)Fe(4-diene)(5-cycloheptadienyl)]+, and [CpCo(5-cyclodienyl)]+ give the nucleophilic adducts whereas with [Mn(CO)5]-, [W(CO)3Cp]-, and [Fe(CO)2Cp]- formation of the corresponding C-C coupling products and of the metal-metal-bonded dimers is observed. The structures of Cp*Ru(-1:2:3-1,5-octadienyl)Re(CO)5 (4), [Cp* Ru(-1:2:3-1,5-octadienyl)]2Os(CO)4 (6), and of (OC)-Fe(4-1,3-cyclohexadiene) (-1:4-1,3-cycloheptadiene)Re(CO)5 (9) have been determined by X-ray diffraction.

[1]  S. Geib,et al.  [2 + 2]cyclodimerization of ligated benzene following reductive activation of manganese complex [Mn(.eta.6-C6H6)(CO)3]+ to give [{Mn(CO)3}2{[.mu.(.eta.4-C6H6-.eta.4-C6H6)}]2- , 1991 .

[2]  W. Beck,et al.  Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer-Carben-Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C-Kupplung , 1991 .

[3]  K. Polborn,et al.  Kohlenwasserstoffverbrückte Komplexe XX Nucleophile Addition von Carbonylmetallaten an kationische Hexadienyl‐, Cycloheptadienyl‐, Cycloheptadienyl‐ und Cyclooctadienyl‐Komplexe von Eisen und Ruthenium: Heterodimetall‐Komplexe mit η1:η4‐C6‐, ‐C7‐ und ‐C8‐Kohlenwasserstoffbrücken , 1991 .

[4]  J. Kochi,et al.  Nucleophilic and electron-transfer processes in the ion-pair annihilation of cationic iron complexes (dienyl)Fe(CO)3+ with CpMo(CO)3- , 1991 .

[5]  J. Kochi,et al.  Concurrent one- and two-electron processes in electrophile/nucleophile interactions of organometallic ion pairs , 1990 .

[6]  W. Beck,et al.  New bimetallic hydrocarbon-bridged complexes by nucleophilic attack of carbonylmetallates to coordinated unsaturated hydrocarbons , 1989 .

[7]  K. Polborn,et al.  Addition von metallorganischen Nucleophilen an koordinierte 1,3-Diene, Trimethylenmethan und Cycloheptatrienyl: Heterobimetallische Carbonyl-Molybdän-Rhenium-Komplexe mit σ,π-C4- und -C7-Kohlenwasserstoffbrücken , 1989 .

[8]  M. Zaworotko,et al.  Synthetic applications of trialkylaluminum reagents: alkylation and reduction of transition-metal-complexed .pi.-hydrocarbon ligands , 1989 .

[9]  S. Noh,et al.  Anionic manganese tricarbonyl complexes of C7 and C8 cyclic dienes and polyenes: synthesis and reactions with electrophiles , 1988 .

[10]  W. Beck,et al.  Addition von Pentacarbonylrhenat an koordiniertes Benzol: Ein σ,π‐verbrückter, dynamischer Cyclohexadienyl‐Komplex, (OC)5Re‐μ‐(η1:η5‐C6H6Mn(CO)3 , 1988 .

[11]  R. Jacobson,et al.  Synthesis and structure of [1-5-η-6-exo-Re(CO)5C7H8]Mn(CO)3. The first example of metal carbonyl anion addition to a coordinated cyclic π-hydrocarbon , 1987 .

[12]  W. Beck,et al.  Reaktionen von Carbonylmetall‐Anionen mit kationischen Olefinkomplexen: Ethylen‐verbrückte Komplexe von Molybdän, Wolfram und Rhenium , 1981 .

[13]  G. Deganello,et al.  Reactivity of cycloheptatrienyl tricarbonyl ferrate(−1: synthesis and sterepchemistry of ditropylium metal carbonyl complexes , 1980 .

[14]  R. King,et al.  Organometallic Chemistry of the Transition Metals. XV. New Olefinic and Acetylenic Derivatives of Tungsten , 1966 .

[15]  R. King,et al.  Organometallic Chemistry of the Transition Metals. VI. Some Cycloheptatrienyl Derivatives of Chromium, Molybdenum, and Cobalt , 1964 .

[16]  E. Muetterties,et al.  π-Allyl Derivatives of Transition Metals , 1961 .

[17]  J. Dunitz,et al.  Struktur des Cycloheptatrien-molybdän-tricarbonyls, C7H8Mo(CO)3 , 1960 .

[18]  M. Karplus.  Contact Electron‐Spin Coupling of Nuclear Magnetic Moments , 1959 .

[19]  H. Dauben,et al.  π-TROPENIUM-MOLYBDENUM-TRICARBONYL FLUOROBORATE , 1958 .

[20]  C. Stevens,et al.  Cyclic Polyolefins. V. Preparation of Bromocycloöctadienes and 1,3,5-Cycloöctatriene from 1,5-Cycloöctadiene1 , 1950 .