Growth of nanostructured thin films of poly(p-xylylene) derivatives by vapor deposition

Nanostructured thin films of poly(p-xylylene) derivatives are deposited by oblique angle vapor deposition method under low-vacuum conditions. We showed deposition of columnar nanostructured poly(chloro-p-xylylene) and poly(bromo-p-xylylene) thin films, and co-deposition of nanostructured poly(o-trifluoroacetyl-p-xylylene-co-p-xylylene) thin film. Characterization of both the nanostructured and planar thin films of poly(p-xylylene) are performed with different experimental methods. We developed a generalized strategy towards depositing nanostructured poly(p-xylylene) derivatives and thus promise a new generation of thin films suitable for biomedical and antifouling applications.

[1]  H. A. Carter The chemistry of paper preservation: part 1. The aging of paper and conservation techniques , 1996 .

[2]  Gang-yu Liu,et al.  Nanometer-scale fabrication by simultaneous nanoshaving and molecular self-assembly , 1997 .

[3]  A. Kuprat,et al.  Bridging simulations and experiments in microstructure evolution. , 2003, Physical review letters.

[4]  W. F. Gorham A New, General Synthetic Method for the Preparation of Linear Poly‐p‐xylylenes , 1966 .

[5]  C. Brown,et al.  Preparation and Structure of Di-p-Xylylene , 1949, Nature.

[6]  Donald J. Cram,et al.  Macro rings. XXXVII. Multiple electrophilic substitution reactions of [2.2]paracyclophanes and interconversions of polysubstituted derivatives , 1969 .

[7]  Ting Xu,et al.  The influence of molecular weight on nanoporous polymer films , 2001 .

[8]  R. Gleiter,et al.  Modern cyclophane chemistry , 2004 .

[9]  S. Naidu,et al.  Fibroblast cell attachment and growth on nanoengineered sculptured thin films. , 2007, Journal of biomedical materials research. Part B, Applied biomaterials.

[10]  W. Dressick,et al.  Covalent Binding of Pd Catalysts to Ligating Self‐Assembled Monolayer Films for Selective Electroless Metal Deposition , 1994 .

[11]  M. Ulbricht Advanced functional polymer membranes , 2006 .

[12]  NIELS O. YOUNG,et al.  Optically Active Fluorite Films , 1959, Nature.

[13]  J. Buriak,et al.  Chemical and Biological Applications of Porous Silicon Technology , 2000 .

[14]  Ark L. Lew,et al.  Miniaturization of Space Electronics with Chip-on-Board Technology , 1999 .

[15]  Akhlesh Lakhtakia,et al.  Growth of sculptured polymer submicronwire assemblies by vapor deposition , 2005 .

[16]  M. Fröba,et al.  Periodic mesoporous organosilicas (PMOs): past, present, and future. , 2006, Journal of nanoscience and nanotechnology.

[17]  Dilip K. Paul,et al.  Sculptured Thin Films: Nanoengineered Morphology and Optics , 2005 .

[18]  M. Demirel,et al.  Spatially organized free-standing poly(p-xylylene) nanowires fabricated by vapor deposition. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[19]  D. Klee,et al.  Chemical vapour deposition polymerization of substituted [2.2]paracyclophanes , 1998 .