Contributions of Professor Pier Giorgio Zambonin to analytical chemistry

On the occasion of his 72nd birthday it is our pleasure to congratulate Professor Pier Giorgio Zambonin for his outstanding scientific achievements and significant contributions to the growth of analytical chemistry. Pier Giorgio Zambonin, born in Castelguglielmo in 1935, received his doctorate in chemistry at the University of Padova in 1959. In 1963 he became assistente ordinario (Assistant Professor) at the University of Bari where he was among the founders of the local “Institute of Analytical Chemistry”. In 1966 he joined the laboratory of Professor Joseph Jordan at the Pennsylvania State University where he spent a three-year period as research associate. In 1971, he received the “libera docenza”, and in 1974 he became Full Professor at the University of Bari and, soon after he became Head of the Institute of Analytical Chemistry, a position held until 1981 when the Institute merged with the newly established Department of Chemistry. He is presently Head of the University Research Centre for Analytical Mass Spectrometry. As a member of the Italian Chemical Society, Pier Giorgio Zambonin was President of the Apulian Section for a total of nine years and President of the Division of Analytical Chemistry for three years. Since 1988 he has served as representative of the Italian Chemical Society in the Working Party for Analytical Chemistry—WPAC (now Division of Analytical Chemistry) of the Federation of European Chemical Societies (now EuCheMS). In 1996 he was Chairman of the ninth edition of the Euroanalysis conference held in Bologna (involving about 1,000 participants from all over the world and more than 900 scientific contributions). On that occasion he was awarded the Sigillum Magnum of the University of Bologna. The accompanying photo shows Professor Pier Giorgio Zambonin at Euroanalyis IX receiving an award of merit from Professor Arnaldo Liberti, dean of the Italian analytical chemists. As a member of the WPAC Study Group on “Education in Analytical Chemistry” he worked on the harmonization of teaching the discipline in European universities (the “Eurocurriculum”), contributing a chapter to the textbook Analytical Chemistry (Kellner R, Mermet J-M, Otto M, Valcarcel M, Widmer HM (eds) Wiley-VCH, Weinheim). The scientific career of Pier Giorgio Zambonin which started with enthalpimetric studies [1] moved soon to the field of molten salts, at that time, an appealing research area with large potential applications in fields such as nuclear energy, fuel cells, refractory metal deposition and heat transfer/storage. In this field Professor Zambonin rapidly became an internationally acknowledged leader creating the well-known Italian school [2]. A complete survey of his contribution to molten salt chemistry (fundamental aspects, electrochemistry, reaction mechanisms, gas–solute interactions, kinetic studies, etc.) would take a review article, so we purposely will focus on a very limited number of issues. Anal Bioanal Chem (2007) 389:2051–2053 DOI 10.1007/s00216-007-1280-5

[1]  G. Smith,et al.  Advances in Molten Salt Chemistry: Volume 1 , 1971 .

[2]  P. Zambonin Electron paramagnetic resonance identification of molten salt produced superoxide ions , 1974 .

[3]  P. Zambonin Voltammetric behavior of the carbon dioxide-oxygen-carbonate system in molten alkali nitrates. , 1972, Analytical chemistry.

[4]  P. Zambonin,et al.  Chemistry of electron transfer and oxygen transfer in fused salts , 1967 .

[5]  Pier Giorgio Zambonin,et al.  A disposable, reagentless, third-generation glucose biosensor based on overoxidized poly(pyrrole)/tetrathiafulvalene-tetracyanoquinodimethane composite. , 2002, Analytical chemistry.

[6]  P. Zambonin,et al.  Ion-beam sputtered palladium-fluoropolymer nano-composites as active layers for organic vapours sensors , 2003 .

[7]  P. Zambonin,et al.  Voltammetric behavior of the chlorine/chloride system and detection of chloride ions in molten nitrates , 1979 .

[8]  P. Zambonin,et al.  XPS and SIMS surface chemical analysis of some important classes of polymeric biomaterials , 1996 .

[9]  P. Zambonin Superoxide electrodes in nitrate melts. Comment , 1975 .

[10]  P. Zambonin,et al.  Redox chemistry of the system O2-O2--O22--O2- in fused salts , 1969 .

[11]  M. Blander Molten salt chemistry , 1964 .

[12]  P. Zambonin,et al.  Redox mechanism in an ionic matrix. IV. Catalytic effects of peroxide and superoxide on the oxidation of nitrite by molecular oxygen in molten alkali nitrates , 1974 .

[13]  W. L. Jolly,et al.  X-RAY PHOTOELECTRON SPECTROSCOPY , 1970 .

[14]  P. Zambonin Voltammetric behavior and analytical detection of oxygen, superoxide, hydroxide, and water present together in an ionic solvent , 1971 .

[15]  C. Malitesta,et al.  Glucose fast-response amperometric sensor based on glucose oxidase immobilized in an electropolymerized poly(o-phenylenediamine) film. , 1990, Analytical chemistry.

[16]  P. Zambonin,et al.  Redox mechanisms in an ionic matrix. Autocatalysis in the process superoxide + nitrite .dbr. peroxide + nitrate in fused salts , 1971 .

[17]  P. Zambonin,et al.  Redox mechanisms in an ionic matrix. Kinetics of the reaction 202- + H2O = 2OH- + 1.502 in molten alkali nitrates , 1972 .

[18]  P. Zambonin,et al.  Redox mechanisms in an ionic matrix. III. Kinetics of the reaction nitrite ion + molecular oxygen = nitrate ion in molten alkali nitrates , 1973 .

[19]  Thermodynamics of the systems NO–3= NO–2+½O2 and NO–3+½O2–2= NO–2+ O–2 in molten alkali nitrates , 1976 .

[20]  C. Malitesta,et al.  Molecularly imprinted electrosynthesized polymers:  new materials for biomimetic sensors. , 1999, Analytical chemistry.

[21]  P. Zambonin Controlled atmosphere cell for rotating disk electrode voltammetry in fused salts , 1969 .

[22]  P. Zambonin,et al.  Solubility and detection (down to 30 p.p.b.) of oxygen in molten alkali nitrates , 1972 .

[23]  G. Mamantov,et al.  Electroanalytical Chemistry in Molten Salts—A Review of Recent Developments , 1973 .

[24]  P. Zambonin,et al.  X-Ray Photoelectron Spectroscopy: Principles, Instrumentation, Data Processing and Molten Salt Applications , 1987 .

[25]  P. Zambonin,et al.  Surface Characterization of Advanced Polymers , 1993 .

[26]  P. Zambonin,et al.  Electrosynthesized poly(pyrrole)/poly(2-naphthol) bilayer membrane as an effective anti-interference layer for simultaneous determination of acethylcholine and choline by a dual electrode amperometric biosensor. , 2006, Biosensors & bioelectronics.