Evaluation of the Self-Healing Ability of Mortar Mixtures Containing Superabsorbent Polymers and Nanosilica

Addition of superabsorbent polymers (SAPs) to cementitious mixtures promotes the self-healing ability of the material. When cracking occurs; SAPs present inside the crack will swell upon contact with water and subsequently release this water to stimulate the further hydration of unhydrated cement particles and the calcium carbonate crystallization. However; the inclusion of SAPs affects the mechanical performance of the cementitious material by the creation of macro-pores as water is retracted from the swollen SAP. To counteract the reduction in strength, part of the cement is replaced by nanosilica. In this research, different mixtures containing either SAPs or nanosilica and a combination of both were made. The samples were subjected to wet–dry cycles simulating external conditions, and the self-healing efficiency was evaluated by means of the evolution in crack width, by optical measurements, and a water permeability test. In samples containing SAPs, an immediate sealing effect was observed and visual crack closure was noticed. The smaller influence on the mechanical properties and the good healing characteristics in mixtures containing both nanosilica and SAPs are promising as a future material for use in building applications.

[1]  Marianne Tange Hasholt,et al.  Mechanical properties of Concrete with SAP. Part I: Development of compressive strength , 2010 .

[2]  V. Mechtcherine Use of superabsorbent polymers (SAP) as concrete additive , 2016 .

[3]  Robby Caspeele,et al.  Novel active crack width control technique to reduce the variation on water permeability results for self-healing concrete , 2019, Construction and Building Materials.

[4]  K. Breugel,et al.  Autogenous shrinkage in high-performance cement paste: An evaluation of basic mechanisms , 2003 .

[5]  P. Dubruel,et al.  Alginate biopolymers: Counteracting the impact of superabsorbent polymers on mortar strength , 2016 .

[6]  Didier Snoeck,et al.  Repeated Autogenous Healing in Strain-Hardening Cementitious Composites by Using Superabsorbent Polymers , 2016 .

[7]  Nele De Belie,et al.  Self-Healing in Cementitious Materials—A Review , 2013 .

[8]  N. Belie,et al.  Water penetration through cracks in self-healing cementitious materials with superabsorbent polymers studied by neutron radiography , 2018, Cement and Concrete Research.

[9]  T. L. Brownyard,et al.  Studies of the Physical Properties of Hardened Portland Cement Paste , 1946 .

[10]  D. Snoeck,et al.  Autogenous Healing in Strain-Hardening Cementitious Materials With and Without Superabsorbent Polymers: An 8-Year Study , 2019, Front. Mater..

[11]  Aly Marei Said,et al.  Properties of concrete incorporating nano-silica , 2012 .

[12]  P. Dubruel,et al.  Self-healing cementitious materials by the combination of microfibres and superabsorbent polymers , 2014 .

[13]  S. Van Vlierberghe,et al.  Combined use of superabsorbent polymers and nanosilica for reduction of restrained shrinkage and strength compensation in cementitious mortars , 2020 .

[14]  Veerle Cnudde,et al.  Comparison of different approaches for self-healing concrete in a large-scale lab test , 2016 .

[15]  N. Belie,et al.  The influence of superabsorbent polymers on the autogenous shrinkage properties of cement pastes with supplementary cementitious materials , 2015 .

[16]  P. Freiesleben Hansen,et al.  AUTOGENOUS DEFORMATION AND CHANGE OF THE RELATIVE HUMIDITY IN SILICA FUME-MODIFIED CEMENT PASTE , 1996 .

[17]  Didier Snoeck,et al.  Most recent advances in the field of self-healing cementitious materials , 2013 .

[18]  Chunxiang Qian,et al.  Self-healing in cementitious materials: Materials, methods and service conditions , 2016 .

[19]  Torben C. Hansen,et al.  Physical structure of hardened cement paste. A classical approach , 1986 .

[20]  P. Dubruel,et al.  Visualization of water penetration in cementitious materials with superabsorbent polymers by means of neutron radiography , 2012 .

[21]  Bart Craeye,et al.  Super absorbing polymers as an internal curing agent for mitigation of early-age cracking of high-performance concrete bridge decks , 2011 .

[22]  P. Dubruel,et al.  The use of superabsorbent polymers as a crack sealing and crack healing mechanism in cementitious materials , 2012 .

[23]  Hongjian Du,et al.  Durability performances of concrete with nano-silica , 2014 .

[24]  Nele De Belie,et al.  Self-healing mortar with pH-sensitive superabsorbent polymers: testing of the sealing efficiency by water flow tests , 2016 .