Measured UV spectra compared with discrete ordinate method simulations

A comprehensive radiative transfer model is used to calculate surface spectral ultraviolet irradiance under cloud-free conditions. The results are compared with measurements made at Lauder, New Zealand (45 deg S, 170 deg E) before and after the eruption of Mount Pinatubo and including a snow-covered surface. There is reasonable agreement between measured and calculated diffuse, direct, and global irradiances over the range 300 to 450 nm. Discrepancies may be due to calibration errors in the UV measurements, or in the extra terrestrial irradiances input to the model. Ratios of diffuse/direct irradiances are independent of such calibration uncertainties and therefore provide a sensitive test of the model. If appropriate ozonesonde data, surface albedo, and aerosol optical properties are used, the model ratios are in satisfactory agreement with measurements over a wide range of observing conditions. For cases in which the atmospheric optical properties are best known the agreement is better than 8% in the UV-B range, and for wavelengths 320 to 450 nm the deviation is smaller. The comparison suggests that the ultraviolet radiation exposure can be computed with confidence for clear sky conditions if the appropriate atmospheric molecular density profiles, ozonesonde data, surface albedo, and aerosol optical properties are available.more » The UV radiation model is used to investigate the impact of changes in solar zenith angle, ozone abundance, surface albedo, and aerosol loading on UV radiation reaching the surface of the Earth. The ratios of diffuse to direct irradiance depend critically on solar zenith angle, surface albedo, and aerosol extinction. Ozone changes have pronounced effects on the global UVB irradiance but have only a minor effect on these ratios.« less

[1]  K. Stamnes,et al.  Several-fold enhancement of biologically effective ultraviolet radiation levels at McMurdo Station Antarctica during the 1990 ozone “hole” , 1992 .

[2]  M. Allen,et al.  Enhancement of atmospheric radiation by an aerosol layer. , 1992, Journal of geophysical research.

[3]  M. Molina,et al.  Absolute absorption cross sections of ozone in the 185- to 350-nm wavelength range , 1986 .

[4]  P. Teillet,et al.  Rayleigh optical depth comparisons from various sources. , 1990, Applied optics.

[5]  M. Nicolet Solar spectral irradiances with their diversity between 120 and 900 nm , 1989 .

[6]  John E. Frederick,et al.  SOLAR ULTRAVIOLET RADIATION AT THE EARTH'S SURFACE , 1989 .

[7]  A. E. Green,et al.  ANALYTICAL CHARACTERIZATION OF SPECTRAL ACTINIC FLUX and SPECTRAL IRRADIANCE IN THE MIDDLE ULTRAVIOLET , 1982, Photochemistry and photobiology.

[8]  K. Stamnes,et al.  Ultraviolet radiation in the Arctic : the impact of potential ozone depletions and cloud effects , 1992 .

[9]  R L McKenzie,et al.  Solar ultraviolet spectroradiometry in New Zealand: instrumentation and sample results from 1990. , 1992, Applied optics.

[10]  K. Stamnes,et al.  Numerically stable algorithm for discrete-ordinate-method radiative transfer in multiple scattering and emitting layered media. , 1988, Applied optics.

[11]  J. Rosen,et al.  Backscattersonde: a new instrument for atmospheric aerosol research. , 1991, Applied optics.

[12]  G. Toon,et al.  Post‐Pinatubo optical depth spectra vs. latitude and vortex structure: Airborne tracking sunphotometer measurements in AASE II , 1993 .

[13]  K. Stamnes The stratosphere as a modulator of ultraviolet radiation into the Biosphere , 1993 .

[14]  M. Nicolet,et al.  On the molecular scattering in the terrestrial atmosphere : An empirical formula for its calculation in the homosphere , 1984 .

[15]  R. Davies Increased transmission of ultraviolet radiation to the surface due to stratospheric scattering , 1993 .

[16]  R. McKenzie UV spectral irradiance measurements in New Zealand: Effects of Pinatubo volcanic aerosol , 1994 .

[17]  Paul J. Crutzen,et al.  On the disproportionate role of tropospheric ozone as a filter against solar UV‐B radiation , 1989 .

[18]  K Stamnes,et al.  Derivation of total ozone abundance and cloud effects from spectral irradiance measurements. , 1991, Applied optics.

[19]  J. Deluisi,et al.  On some radiative features of the el chichon volcanic stratospheric dust cloud and a cloud of unknown origin observed at Mauna Loa , 1983 .

[20]  J.-D. F. Bartoe,et al.  Absolute solar spectral irradiance 120 nm-400 nm (results from the solar ultraviolet spectral irradiance monitor-SUSIM-experiment on board Spacelab 2) , 1988 .