Detection and Identification of Sub-Millimeter Films of Organic Compounds on Environmental Surfaces Using Short-Wave Infrared Hyperspectral Imaging: Algorithm Development Using a Synthetic Set of Targets

An algorithm for identifying organic materials using a short-wave infrared hyperspectral imager is presented. The main achievement of this algorithm is to automatically locate a clear reference within the scene, without any prior knowledge regarding the scene, and use it to extract the spectral signature of the target material. This step is required for sub-millimeter organic films since they absorb only a small fraction of the light. Therefore, the obtained spectral signature is a product of the target material and the clean background spectral signature. Detection rate as high as 90% was achieved for three model compounds in a controlled scene with false alarm rate lower than 1% in our model scene, containing a set of synthetic targets (ST). These findings lay the groundwork for further study of real (and probably more complex compared to the ST) cases and materials, required for the development of a detection system that will be capable of locating trace amounts of polluting chemicals to enable improved prevention, regulation, and mitigation acts.

[1]  Maddalena Illario,et al.  Environmental Pollution from Illegal Waste Disposal and Health Effects: A Review on the “Triangle of Death” , 2015, International journal of environmental research and public health.

[2]  Guangming Zeng,et al.  Chlorinated volatile organic compounds (Cl-VOCs) in environment - sources, potential human health impacts, and current remediation technologies. , 2014, Environment international.

[3]  G. Ferrier,et al.  Application of Imaging Spectrometer Data in Identifying Environmental Pollution Caused by Mining at Rodaquilar, Spain , 1999 .

[4]  Freek D. van der Meer,et al.  Mapping of heavy metal pollution in stream sediments using combined geochemistry, field spectroscopy, and hyperspectral remote sensing: A case study of the Rodalquilar mining area, SE Spain , 2008 .

[5]  Colm P. O'Donnell,et al.  Hyperspectral imaging – an emerging process analytical tool for food quality and safety control , 2007 .

[6]  Dimitris G. Manolakis,et al.  Detection algorithms for hyperspectral imaging applications , 2002, IEEE Signal Process. Mag..

[7]  Luisa Verdoliva,et al.  Detection of environmental hazards through the feature-based fusion of optical and SAR data: a case study in southern Italy , 2015 .

[8]  Alessandro Ulrici,et al.  Practical comparison of sparse methods for classification of Arabica and Robusta coffee species using near infrared hyperspectral imaging , 2015 .

[9]  Eyal Ben-Dor,et al.  Supervised Vicarious Calibration (SVC) of hyperspectral remote-sensing data , 2011, 2011 3rd Workshop on Hyperspectral Image and Signal Processing: Evolution in Remote Sensing (WHISPERS).

[10]  M. Manley Near-infrared spectroscopy and hyperspectral imaging: non-destructive analysis of biological materials. , 2014, Chemical Society reviews.

[11]  E. Bouwer,et al.  Bioremediation of organic compounds--putting microbial metabolism to work. , 1993, Trends in biotechnology.

[12]  Fenella G. France Advanced Spectral Imaging for Noninvasive Microanalysis of Cultural Heritage Materials: Review of Application to Documents in the U.S. Library of Congress , 2011, Applied spectroscopy.

[13]  Alon Manor,et al.  Real-time stand-off spatial detection and identification of gases and vapor using external-cavity quantum cascade laser open-path spectrometer , 2015 .

[14]  S. Jørgensen,et al.  Occurrence, fate and effects of pharmaceutical substances in the environment--a review. , 1998, Chemosphere.

[15]  K. Jones,et al.  Persistent organic pollutants (POPs): state of the science. , 1999, Environmental pollution.

[16]  D. Monteith,et al.  Long-term increases in surface water dissolved organic carbon: observations, possible causes and environmental impacts. , 2005, Environmental pollution.

[17]  K. Semple,et al.  Impact of composting strategies on the treatment of soils contaminated with organic pollutants. , 2001, Environmental pollution.

[18]  A F Goetz,et al.  Imaging Spectrometry for Earth Remote Sensing , 1985, Science.

[19]  Thomas D. Nielsen,et al.  Hyperspectral imaging: a novel approach for microscopic analysis. , 2001, Cytometry.

[20]  D. Rondinelli,et al.  Proactive corporate environmental management: A new industrial revolution , 1998 .

[21]  D. Mackay,et al.  Temperature dependence of atmospheric concentrations of semivolatile organic compounds , 1998 .

[22]  R. Jenssen,et al.  1 THE HYMAP TM AIRBORNE HYPERSPECTRAL SENSOR : THE SYSTEM , CALIBRATION AND PERFORMANCE , 1998 .

[23]  Antonio J. Plaza,et al.  Hyperspectral Unmixing Overview: Geometrical, Statistical, and Sparse Regression-Based Approaches , 2012, IEEE Journal of Selected Topics in Applied Earth Observations and Remote Sensing.

[24]  Eyal Agassi,et al.  Detection of gaseous plumes in IR hyperspectral images using hierarchical clustering. , 2007, Applied optics.