Study on the spray and combustion characteristics of water–emulsified diesel

Emulsified fuel remains a potential solution to meet the increasingly stringent emission regulations for internal combustion engines due to its capability of simultaneously reducing NOx and particular matter (PM). In this study, emulsified diesels with 10% and 20% water by volume were studied. The stability of the water emulsified diesel was first investigated in terms of the hydrophilic-lipophilic-balance (HLB) value. Based on the stability test, a suitable surfactant composition for the diesel/water interfacial condition was given and the separation tendency of the fuel with different water volumetric ratio was analyzed. The emulsions were later injected and combusted in a pre-burn type constant volume chamber, which is able to provide high ambient temperature and pressure to mimic real engine operation conditions. High speed imaging was used to capture the spray and combustion process under various conditions. Results show longer initial liquid penetration for emulsified diesel under low ambient temperatures. Longer ignition delay of emulsified diesel also provided more air/fuel mixing time, thus significantly lowering the soot luminosity. Although droplet micro-explosion has been intensively studied, its behavior in a burning spray is much less reported. This study in particular focused on micro-explosion in a burning spray. Broadband natural flame images were recorded with intentional overall over-exposure such that the central lift-off region could be illuminated by soot incandescence. Puffing and disruptive droplet combustion was consistently observed at high ambient temperature in the central lift-off region with emulsified diesel indicating the occurrence of micro-explosion in a burning spray flame. It is demonstrated that micro-explosion is not only able to enhance the secondary breakup, but also affect the primary breakup under certain conditions, which to the author’s awareness has not been reported in any previous literature. Lower injection pressure and higher ambient temperature favor the occurrence of micro-explosion before primary breakup as a competition between the micro explosion delay time and the primary breakup time.

[1]  Ingemar Denbratt,et al.  Reduction of soot emissions when combusting water-in-diesel emulsion and microemulsion fuel in a direct injection diesel engine , 2007 .

[2]  Shinji Nakaya,et al.  Microexplosion of an emulsion droplet during Leidenfrost burning , 2007 .

[3]  幸夫 水谷,et al.  軽油-水エマルジョンの噴霧火災におけるミクロ爆発の観測 : 第2報,高速度撮影における時間的・空間的解像度の影響(熱工学,内燃機関,動力など) , 2003 .

[4]  M. Tsue,et al.  Statistical analysis of onset of microexplosion for an emulsion droplet , 1996 .

[5]  Fanhua Ma,et al.  A unified model for the micro-explosion of emulsified droplets of oil and water☆ , 2002 .

[6]  C. Lee,et al.  Combustion Characteristics and Soot Distributions of Neat Butanol and Neat Soybean Biodiesel , 2011 .

[7]  E. Valdmanis,et al.  The Effects of Emulsified Fuels and Water Induction on Diesel Combustion , 1970 .

[8]  Yoshio Matsuoka,et al.  Observation of Micro-Explosions in Spray Flames of Light Oil-Water Emulsions. , 2000 .

[9]  Hai-Ping Lin,et al.  Study on the spray characteristics of methyl esters from waste cooking oil at elevated temperature , 2010 .

[10]  Hiroshi Yamasaki,et al.  Recent advances in the combustion of water fuel emulsion , 2002 .

[11]  C. Lee,et al.  Soot Emissions of Various Oxygenated Biofuels in Conventional Diesel Combustion and Low-Temperature Combustion Conditions , 2012 .

[12]  Ken Okazaki,et al.  Visualization of secondary atomization in emulsified-fuel spray flow by shadow imaging , 2013 .

[13]  Andrew C. Matheaus,et al.  Effects of Water-Fuel Emulsions on Spray and Combustion Processes in a Heavy-Duty DI Diesel Engine , 2002 .

[14]  Mingfa Yao,et al.  Comparison of Ethanol and Butanol as Additives in Soybean Biodiesel Using a Constant Volume Combustion Chamber , 2011 .

[15]  Hirotatsu Watanabe,et al.  An experimental investigation of the breakup characteristics of secondary atomization of emulsified fuel droplet , 2010 .

[16]  Cherng-Yuan Lin,et al.  Effects of emulsification variables on fuel properties of two- and three-phase biodiesel emulsions , 2007 .

[17]  Hirotatsu Watanabe,et al.  The characteristics of puffing of the carbonated emulsified fuel , 2009 .

[18]  M. Kono,et al.  Effect of gravity on onset of microexplosion for an oil-in-water emulsion droplet , 1998 .

[19]  P. Massoli,et al.  Study of the micro-explosion temperature of water in oil emulsion droplets during the Leidenfrost effect , 2012 .

[20]  P. Massoli,et al.  Experimental evidence for microexplosions in water/fuel oil emulsion flames inferred by laser light scattering , 1992 .

[21]  Thomas A. Litzinger,et al.  Effects of Emulsified Fuels on Soot Evolution in an Optically-accessible DI Diesel Engine , 2000 .

[22]  Yoshio Morozumi,et al.  Effect of Physical Properties on Microexplosion Occurrence in Water-in-Oil Emulsion Droplets , 2010 .

[23]  C. Law,et al.  Synergistic combustion of droplets of ethanol, diesel and biodiesel mixtures , 2012 .

[24]  Kang Y. Huh,et al.  Experimental study on the combustion characteristics of emulsified diesel in a rapid compression and expansion machine , 2000 .

[25]  Ingemar Denbratt,et al.  Optical studies of spray development and combustion of water-in-diesel emulsion and microemulsion fuels , 2010 .

[26]  W. Fu,et al.  A study on the effect of more volatile fuel on evaporation and ignition for emulsified oil , 2001 .