Use of two-photon excitation for erasable-rewritable three-dimensional bit optical data storage in a photorefractive polymer.

We report what is believed to be the first use of a photorefractive polymer in erasable-rewritable three-dimensional bit optical data storage under two-photon excitation. We successfully demonstrate writing, erasing, and rewriting of multilayered information in a photorefractive polymer consisting of 2,5-dimethyl-4-(p-nitrophenylazo)anisole, 2,4,7-trinitro-9-fluorenone, 9-ethylcarbazole, and poly(N-vinylcarbazole). A three-dimensional bit density of 5 Gbits/cm(3) is achieved by two-photon absorption under pulsed beam illumination at an infrared wavelength of 800 nm in the recording process. Complete erasing of the recording information is achieved by use of ultraviolet illumination.

[1]  M. Gu,et al.  Principles Of Three-Dimensional Imaging In Confocal Microscopes , 1996 .

[2]  Ryszard Burzynski,et al.  Photorefractive Polymers and Composites , 1996 .

[3]  P. Prasad,et al.  High-density three-dimensional optical data storage in a stacked compact disk format with two-photon writing and single photon readout , 1999 .

[4]  Peter M. Rentzepis,et al.  Two-photon volume information storage in doped polymer systems , 1990 .

[5]  C. Sheppard,et al.  Three-dimensional transfer functions for high-aperture systems , 1994 .

[6]  S. Kawata,et al.  Three-dimensional microfabrication with two-photon-absorbed photopolymerization. , 1997, Optics letters.

[7]  Takanobu Higuchi,et al.  27.4 Gbyte read-only dual-layer disk for blue laser , 1999, Optical Data Storage.

[8]  Colin J. R. Sheppard,et al.  Three-dimensional Optical Transfer Function for Weak Aberrations , 1995 .

[9]  S C Esener,et al.  Three-dimensional optical data storage in a fluorescent dye-doped photopolymer. , 2000, Applied optics.

[10]  Carol J. Cogswell,et al.  Confocal differential interference contrast (DIC) microscopy: including a theoretical analysis of conventional and confocal DIC imaging , 1992 .

[11]  B. Frieden,et al.  Effects of third-order spherical aberration on the 3-D incoherent optical transfer function. , 1990, Applied Optics.

[12]  M. Gu,et al.  Advanced Optical Imaging Theory , 1999 .

[13]  W E Moerner,et al.  Electric-field-switchable stratified volume holograms in photorefractive polymers. , 1994, Optics letters.

[14]  Hiroaki Misawa,et al.  Three-dimensional photonic crystal structures achieved with two-photon-absorption photopolymerization of resin , 1999 .

[15]  W H Yeh,et al.  Evanescent coupling in magneto-optical and phase-change disk systems based on the solid immersion lens (SIL) , 1999, Optical Data Storage.

[16]  J. P. Callan,et al.  Three-dimensional optical storage inside transparent materials. , 1996, Optics letters.

[17]  B. Javidi,et al.  A polymeric optical pattern-recognition system for security verification , 1996, Nature.

[18]  J. Strickler,et al.  Three-dimensional optical data storage in refractive media by two-photon point excitation. , 1991, Optics letters.

[19]  P. M. Lundquist,et al.  Organic Glasses: A New Class of Photorefractive Materials , 1996, Science.

[20]  Colin J. R. Sheppard,et al.  THREE-DIMENSIONAL OPTICAL TRANSFER FUNCTION FOR CIRCULAR AND ANNULAR LENSES WITH SPHERICAL ABERRATION AND DEFOCUS , 1994 .

[21]  A. Jen,et al.  Design and synthesis of chromophores and polymers for electro-optic and photorefractive applications , 1997, Nature.

[22]  S Kawata,et al.  Three-dimensional coherent transfer function for reflection confocal microscopy in the presence of refractive-index mismatch. , 2001, Journal of the Optical Society of America. A, Optics, image science, and vision.

[23]  Emil Wolf,et al.  Principles of Optics: Contents , 1999 .

[24]  D. K. Hamilton,et al.  Differential phase contrast in scanning optical microscopy , 1984 .

[25]  C Saloma,et al.  Monte carlo analysis of two-photon fluorescence imaging through a scattering medium. , 1998, Applied optics.

[26]  G. Manivannan,et al.  New azo-dye-doped polymer systems as dynamic holographic recording media , 1995 .

[27]  Y. Kawata,et al.  Reflection-type confocal readout for multilayered optical memory. , 1998, Optics letters.

[28]  S Kawata,et al.  Readout of three-dimensional optical memories. , 1996, Optics letters.

[29]  Henk J. Bolink,et al.  EFFECT OF PLASTICIZATION ON THE PERFORMANCE OF A PHOTOREFRACTIVE POLYMER , 1996 .

[30]  S Kawata,et al.  Nondestructive readout of a three-dimensional photochromic optical memory with a near-infrared differential phase-contrast microscope. , 1997, Optics letters.

[31]  S Kawata,et al.  Use of two-photon absorption in a photorefractive crystal for three-dimensional optical memory. , 1998, Optics letters.

[32]  W. E. Moerner,et al.  Orientationally enhanced photorefractive effect in polymers , 1994 .

[33]  S Kawata,et al.  Reflection confocal microscope readout system for three-dimensional photochromic optical data storage. , 1998, Optics letters.

[34]  F. S. Chen,et al.  A Laser‐Induced Inhomogeneity of Refractive Indices in KTN , 1967 .

[35]  Seth R. Marder,et al.  Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication , 1999, Nature.

[36]  M. Minsky Memoir on inventing the confocal scanning microscope , 1988 .

[37]  N. Peyghambarian,et al.  A photorefractive polymer with high optical gain and diffraction efficiency near 100% , 1994, Nature.

[38]  Allison James,et al.  Pump Up the Volume , 1999 .

[39]  J P Huignard,et al.  Experimental holographic read-write memory using 3-d storage. , 1974, Applied optics.

[40]  W. E. Moerner,et al.  POLYMERIC PHOTOREFRACTIVE MATERIALS , 1994 .

[41]  Nonvolatile holographic storage in iron-doped lithium tantalate with continuous-wave laser light. , 1999, Optics letters.

[42]  S W Hell,et al.  Two-photon near- and far-field fluorescence microscopy with continuous-wave excitation. , 1998, Optics letters.

[43]  W. Denk,et al.  Two-photon laser scanning fluorescence microscopy. , 1990, Science.

[44]  P P Banerjee,et al.  Multiwave coupling in a high-gain photorefractive polymer. , 1999, Optics letters.

[45]  Satoshi Kawata,et al.  Comparison of recording densities in three-dimensional optical storage systems: multilayered bit recording versus angularly multiplexed holographic recording , 1996 .

[46]  Pekka Hänninen,et al.  Continuous wave excitation two‐photon fluorescence microscopy , 1994 .

[47]  T. Galstyan,et al.  Thick dye-doped poly(methyl methacrylate) films for real-time holography. , 1998, Applied optics.

[48]  Keiji Sasaki,et al.  Three-dimensional Potential Analysis Of Radiation Pressure Exerted On A Single Microparticle , 1997, QELS '97., Summaries of Papers Presented at the Quantum Electronics and Laser Science Conference.

[49]  Kurt Sutter,et al.  Photorefractive gratings in the organic crystal 2-cyclooctylamino-5-nitropyridine doped with 7,7,8,8-tetracyanoquinodimethane , 1990, Optics & Photonics.

[50]  K. König,et al.  Cell damage by near-IR microbeams , 1995, Nature.

[51]  P. Varga,et al.  Electromagnetic diffraction of light focused through a stratified medium. , 1997, Applied optics.

[52]  Yan Zhang,et al.  Near-field phase-change optical recording using a GaP hemispherical lens , 1999, Optical Data Storage.

[53]  C. Sheppard,et al.  Effects of specimen refractive index on confocal imaging , 1997 .

[54]  M Gu,et al.  Aberration compensation in confocal microscopy. , 1991, Applied optics.

[55]  E. Wolf,et al.  Electromagnetic diffraction in optical systems, II. Structure of the image field in an aplanatic system , 1959, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[56]  Peter Török,et al.  Electromagnetic diffraction of light focused through a planar interface between materials of mismatched refractive indices: an integral representation , 1995 .

[57]  F B McCormick,et al.  Experimental characterization of a two-photon memory. , 1997, Optics letters.

[58]  S Kawata,et al.  Three-dimensional optical bit-memory recording and reading with a photorefractive crystal: analysis and experiment. , 1996, Applied optics.

[59]  E. Mazur,et al.  Ultrafast-laser driven micro-explosions in transparent materials , 1997 .

[60]  A. Garito,et al.  Nonlinear Optics of Organic and Polymer Materials , 1994 .

[61]  C. Sheppard,et al.  Effects of defocus and primary spherical aberration on three-dimensional coherent transfer functions in confocal microscopes. , 1992, Applied optics.

[62]  Satoshi Kawata,et al.  Optical recording of reversed domains in a Ce-doped SBN:75 crystal for bit-oriented three-dimensional optical memory , 2000 .

[63]  S Kawata,et al.  Three-dimensional optical memory with a photorefractive crystal. , 1995, Applied optics.

[64]  S Kawata,et al.  Three-dimensional phase contrast imaging by an annular illumination microscope. , 1990, Applied optics.

[65]  Tomas D. Milster,et al.  Pupil plane filtering for improved signal detection in an optical data storage system incorporating a solid immersion lens , 1999, Optical Data Storage.

[66]  M Gu,et al.  Influence of spherical aberration on axial imaging of confocal reflection microscopy. , 1994, Applied optics.

[67]  W. E. Moerner,et al.  Polymeric Photorefractive Materials , 1994 .

[68]  M. Teich,et al.  Fundamentals of Photonics , 1991 .

[69]  C. Sheppard,et al.  Theory and practice of scanning optical microscopy , 1984 .

[70]  Saulius Juodkazis,et al.  Transmission and photoluminescence images of three-dimensional memory in vitreous silica , 1999 .

[71]  J. Bhawalkar,et al.  Three-dimensional laser scanning two-photon fluorescence confocal microscopy of polymer materials using a new, efficient upconverting fluorophore. , 2006, Scanning.

[72]  Daniel Day,et al.  Rewritable 3D Bit Optical Data Storage in a PMMA‐Based Photorefractive Polymer , 2001 .

[73]  S Kawata,et al.  Differential phase-contrast microscope with a split detector for the readout system of a multilayered optical memory. , 1996, Applied optics.

[74]  C. Bosshard,et al.  Organic Nonlinear Optical Materials , 2001, CLEO/Europe Conference on Lasers and Electro-Optics.

[75]  M Gu,et al.  Effects of refractive-index mismatch on three-dimensional optical data-storage density in a two-photon bleaching polymer. , 1998, Applied optics.

[76]  D A Parthenopoulos,et al.  Three-Dimensional Optical Storage Memory , 1989, Science.

[77]  Colin J. R. Sheppard,et al.  Axial imaging through an aberrating layer of water in confocal microscopy , 1992 .

[78]  Daniel Day,et al.  High-density erasable three-dimensional optical bit data storage in a photorefractive polymer using two-photon excitation , 1999, Optical Data Storage.

[79]  Daniel Day,et al.  Two-photon multilayer bit data storage by use of continuous-wave illumination , 1999, Other Conferences.

[80]  Focusing of electromagnetic waves through a dielectric interface by lenses of finite Fresnel number , 1998 .

[81]  C. Bräuchle,et al.  Influence of the Glass-Transition Temperature and the Chromophore Content on the Grating Buildup Dynamics of poly(N-vinylcarbazole)-based Photorefractive Polymers. , 1998, Applied optics.

[82]  Z. Kam,et al.  Absorption and Scattering of Light by Small Particles , 1998 .

[83]  Saulius Juodkazis,et al.  Two-photon readout of three-dimensional memory in silica , 2000 .

[84]  C. Sheppard,et al.  Image Formation in the Scanning Microscope , 1977 .

[85]  Partha P Banerjee,et al.  Principles of Nonlinear Optics , 1989 .

[86]  D L Snyder,et al.  Theoretical development and experimental evaluation of imaging models for differential-interference-contrast microscopy. , 1999, Journal of the Optical Society of America. A, Optics, image science, and vision.

[87]  M Gu,et al.  Use of continuous-wave illumination for two-photon three-dimensional optical bit data storage in a photobleaching polymer. , 1999, Optics letters.