A case study of stratosphere‐troposphere exchange during the 1996 North Atlantic Regional Experiment

[1] Passive tracers are employed in a relatively high spatial and temporal resolution three-dimensional transport model to analyze a stratosphere-troposphere exchange (STE) event over the eastern United States and western North Atlantic Ocean. The model is validated against measurements taken on board the National Oceanic and Atmospheric Administration WP-3D Orion aircraft during the North Atlantic Regional Experiment study in the spring of 1996. Overall, the model reproduces the measurements well during the early part of the flight where there is indication of a small stratospheric intrusion. However, the very strong signatures of STE and mixing contained in the measurements later in the flight are not captured. Use of a finer horizontal resolution (20 km as opposed to 60 km) brings the model results closer to the aircraft measurements and yields higher values (50% at 7–8 km altitude) of ozone, O3, with a deeper penetration into the troposphere (20% at 80–120 ppbv levels).

[1]  L. Horowitz,et al.  On the life cycle of a stratospheric intrusion and its dispersion into polluted warm conveyor belts , 2004 .

[2]  J. G. Esler,et al.  Transport and mixing between airmasses in cold frontal regions during Dynamics and Chemistry of Frontal Zones (DCFZ) , 2003 .

[3]  M. Schoeberl,et al.  Estimating Downward Cross-Tropopause Ozone Flux using Column Ozone and Potential Vorticity , 2002 .

[4]  R. Martin,et al.  Stratospheric versus pollution influences on ozone at Bermuda: Reconciling past analyses , 2002 .

[5]  J. Lelieveld,et al.  High‐resolution measurements and simulation of stratospheric and tropospheric intrusions in the vicinity of the polar jet stream , 2002 .

[6]  J. Lelieveld,et al.  Synoptic tracer gradients in the upper troposphere over central Canada during the Stratosphere-Troposphere Experiments by Aircraft Measurements 1998 summer campaign , 2002 .

[7]  M. Beekmann,et al.  Tracer analysis of transport from the boundary layer to the free troposphere , 2001 .

[8]  O. Cooper,et al.  Trace gas signatures of the airstreams within North Atlantic cyclones: Case studies from the North Atlantic Regional Experiment (NARE ’97) aircraft intensive , 2001 .

[9]  J. Lelieveld,et al.  On the origin of elevated surface ozone concentrations at Izana Observatory, Tenerife during late March 1996 , 2000 .

[10]  J. Drummond,et al.  Airborne intercomparison of vacuum ultraviolet fluorescence and tunable diode laser absorption measurements of tropospheric carbon monoxide , 2000 .

[11]  O. Cooper,et al.  Mixing of anthropogenic pollution with stratospheric ozone: A case study from the North Atlantic wintertime troposphere , 2000 .

[12]  J. Lelieveld,et al.  Simulation of Extratropical Synoptic-Scale Stratosphere–Troposphere Exchange Using a Coupled Chemistry GCM: Sensitivity to Horizontal Resolution , 2000 .

[13]  B. Doddridge,et al.  Transport of ozone and pollutants from North America to the North Atlantic Ocean during the 1996 Atmosphere/Ocean Chemistry Experiment (AEROCE) intensive , 1999 .

[14]  P. Rasch,et al.  MOZART, a global chemical transport model for ozone , 1998 .

[15]  B. Jobson,et al.  Emissions lifetimes and ozone formation in power plant plumes , 1998 .

[16]  P. Shepson,et al.  Influence of springtime weather systems on vertical ozone distributions over three North American sites , 1998 .

[17]  John S. Holloway,et al.  Relationships between ozone and carbon monoxide at surface sites in the North Atlantic region , 1998 .

[18]  M. Trainer,et al.  A modeling study of tropospheric species during the North Atlantic Regional Experiment (NARE) , 1998 .

[19]  Jos Lelieveld,et al.  A three-dimensional chemistry/general circulation model simulation of anthropogenically derived ozone in the troposphere and its radiative climate forcing , 1997 .

[20]  J. Lelieveld,et al.  Ozone production and transports in the tropical Atlantic region during the biomass burning season , 1997 .

[21]  Stuart A. Penkett,et al.  North Atlantic Regional Experiment 1993 Summer Intensive: Foreword , 1996 .

[22]  J. Holton,et al.  Stratosphere‐troposphere exchange , 1995 .

[23]  S. Oltmans,et al.  Transport climatology of tropospheric ozone: Bermuda, 1988–1991 , 1995 .

[24]  F. Fehsenfeld,et al.  Parameterization of subgrid scale convective cloud transport in a mesoscale regional chemistry model , 1994 .

[25]  D. Fahey,et al.  Reactive nitrogen and its correlation with ozone in the lower stratosphere and upper troposphere , 1993 .

[26]  F. Fehsenfeld,et al.  Export of North American Ozone Pollution to the North Atlantic Ocean , 1993, Science.

[27]  S. Oltmans,et al.  Seasonal cycle of surface ozone over the western North Atlantic , 1992, Nature.

[28]  Stuart A. McKeen,et al.  A regional model study of the ozone budget in the eastern United States , 1991 .

[29]  David R. Stauffer,et al.  Use of Four-Dimensional Data Assimilation in a Limited-Area Mesoscale Model Part II: Effects of Data Assimilation within the Planetary Boundary Layer , 1991 .

[30]  J. Dudhia Numerical Study of Convection Observed during the Winter Monsoon Experiment Using a Mesoscale Two-Dimensional Model , 1989 .

[31]  E. Browell,et al.  Tropopause fold structure determined from airborne lidar and in situ measurements , 1987 .

[32]  G. Sachse,et al.  Three-dimensional analysis of potential vorticity associated with tropopause folds and observed variations of ozone and carbon monoxide , 1987 .

[33]  Hendrik Feldmann,et al.  The influence of stratospheric intrusions on alpine ozone concentrations , 2000 .

[34]  G. Grell,et al.  A description of the fifth-generation Penn State/NCAR Mesoscale Model (MM5) , 1994 .

[35]  Y. Kuo,et al.  Simulation of ozone intrusion caused by a tropopause fold and cut-off low , 1991 .

[36]  A. Blackadar,et al.  High resolution models of the planetary boundary layer , 1979 .