Influence of Zr content on immersion and electrochemical corrosion behavior of as-cast TiZr alloys

Purpose The purpose of this paper is to study the influence of Zr content on immersion and electrochemical corrosion behavior of Zr-containing Ti-based (TiZr) alloys. Design/methodology/approach The phase analysis of as-cast TχZAB alloys was carried out using X-ray diffraction. The microstructure of corrosion surfaces of the samples was observed using optical metallographic microscopy and scanning electron microscopy, equipped with energy dispersive spectroscopy. Findings The immersion test reveals that the corrosion is alleviated in the presence of a high amount of Zr, whereas pitting corrosion occurs when the Zr content is up to 40 Wt.%. Furthermore, the electrochemical analysis demonstrates that the corrosion resistance TiZr alloys is improved with increasing Zr content. Originality/value The TiZr alloys are promising candidates for high-end applications because of their excellent comprehensive properties. These alloys are usually used in marine or other harsh corrosive environments; therefore, it is essential to study their corrosion behavior.

[1]  Shaik Heruthunnisa,et al.  Investigations on the formability, tensile properties, TEM, 3D-surface roughness and corrosion behaviour on Ti–6Al–4V alloy sheets during single point and multi point incremental forming process , 2022, Anti-Corrosion Methods and Materials.

[2]  W. Hu,et al.  Electrochemical measurements used for assessment of corrosion and protection of metallic materials in the field: a critical review , 2021, Journal of Materials Science & Technology.

[3]  Chunbao Shi,et al.  Synergistic effect of Zr addition and grain refinement on corrosion resistance and pitting corrosion behavior of single α-phase Ti-Zr-based alloys , 2021, Journal of Alloys and Compounds.

[4]  C. Feng,et al.  Influence of micro-nano surface texture on the hydrophobicity and corrosion resistance of a Ti6Al4V alloy surface , 2021, Anti-Corrosion Methods and Materials.

[5]  F. Wang,et al.  Effect of Nb addition on the stability and biological corrosion resistance of Ti-Zr alloy passivation films , 2020 .

[6]  X. Zhang,et al.  Controlling the corrosion behavior of Ti-Zr alloy by tuning the α/β phase volume fraction and morphology of β phase , 2020 .

[7]  R. Jing,et al.  Mechanical properties and corrosion behavior of β-type Ti-Zr-Nb-Mo alloys for biomedical application , 2020 .

[8]  X. Zhang,et al.  Microstructure design and mechanical properties of annealed TiZrAlB alloys , 2020 .

[9]  M. Ma,et al.  Effect of microstructure evolution on mechanical properties of a TiZrAlB alloy rolled by different processes , 2019, Materials Science and Engineering: A.

[10]  C. Yang,et al.  Correlation between atomic diffusivity and densification mechanism during spark plasma sintering of titanium alloy powders , 2019, Journal of Alloys and Compounds.

[11]  F. Yin,et al.  Effects of Y addition on microstructure and mechanical properties of Ti-25Zr alloys , 2019, Materials Science and Engineering: A.

[12]  X. Zhang,et al.  Influence of phase composition and microstructure on mechanical properties of hot-rolled Ti-χZr-4Al-0.005B alloys , 2018, Journal of Alloys and Compounds.

[13]  Riping Liu,et al.  Anisotropic pitting of single-phase β-Zr alloy and isotropic pitting of α + β double-phase Zr alloy , 2017 .

[14]  X. Zhang,et al.  Study of microstructure evolution and strengthening mechanisms in novel TiZrAlB alloy , 2017 .

[15]  Riping Liu,et al.  Effect of zirconium content on the microstructure and corrosion behavior of Ti-6Al-4V-xZr alloys , 2016 .

[16]  X. Zhang,et al.  Effect of rolling temperature on microstructure and mechanical properties of a TiZrAl alloy , 2015 .

[17]  Shuichi Miyazaki,et al.  Superelastic properties of biomedical (Ti-Zr)-Mo-Sn alloys. , 2015, Materials science & engineering. C, Materials for biological applications.

[18]  M. Ma,et al.  The orthorhombic α″ martensite transformation during water quenching and its influence on mechanical properties of Ti-41Zr-7.3Al alloy , 2014 .

[19]  Yan Li,et al.  Shape memory behavior in Ti–Zr alloys , 2011 .

[20]  Ashutosh Kumar Singh,et al.  Effect of thermomechanical processing on evolution of various phases in Ti–Nb–Zr alloys , 2004 .

[21]  V. Stolyarov,et al.  Corrosion resistance of ultra fine-grained Ti , 2004 .

[22]  M. Buzalaf,et al.  The effect of the solute on the structure, selected mechanical properties, and biocompatibility of Ti-Zr system alloys for dental applications. , 2014, Materials science & engineering. C, Materials for biological applications.

[23]  Petrus Christiaan Pistorius,et al.  The nucleation and growth of corrosion pits on stainless steel , 1993 .