Recovery, separation, and identification of organic pesticides from natural and potable waters.

Organic pesticides have been reported in drinking, recreational, irrigational, fish, and shellfish waters of the United States wherefrom the evidence was obtained mostly from physiological responses of aquatic organisms. More recently, however, direct analyses by gas-liquid chromatography indicate that most surface waters and some ground waters contain trace amounts of organic pesticides. Consequently, these raw water supplies may have to be monitored in order to avoid adverse effects from their ultimate domestic use as drinking water. These treated waters would have to be monitored, therefore, in order to evaluate effectivenss of removal processes. Adverse effects may arise also from ancillary uses of potable waters; namely, irrigation of lawns and shrubs and filling of home aquaria.

[1]  H. Habgood,et al.  Programmed temperature gas chromatography , 1966 .

[2]  Jesse M. Cohen,et al.  Effect of Fish Poisons on Water Supplies Part 1. Removal of Toxic Materials , 1960 .

[3]  L. C. Mitchell The Separation and Identification of Chlorinated Organic Pesticides By Paper Chromatography , 1953 .

[4]  W. A. Bosin Analysis of Pesticide Residues Using Microcoulometric Temperature-Programmed Gas Chromatography. , 1963 .

[5]  John A. Carollo,et al.  The Removal of DDT From Water Supplies , 1945 .

[6]  J. J. Lichtenberg,et al.  CHLORINATED HYDROCARBON PESTICIDES IN MAJOR U.S. RIVER BASINS. , 1965, Public health reports.

[7]  L. Davies,et al.  Improvement of identification in the gas-liquid chromatographic analysis of agricultural samples for residues of some chlorinated pesticides. Part II. A halogen-sensitive detector in complementary or alternative use to an electron-capture ionisation detector , 1963 .

[8]  K. Mccully,et al.  Determination of Chlorinated Pesticide Residues in Fat by Electron Capture Gas Chromatography , 1964 .

[9]  J. Casida,et al.  Mode of Action of Insecticides, Metabolism and Selectivity of O,O-Dimethyl 2,2,2-Trichloro-1-hydroxyethyl Phosphonate and Its Acetyl and Vinyl Derivatives , 1957 .

[10]  H. Egan,et al.  The analysis of organo-phosphorus pesticide residues by gas chromatography , 1964 .

[11]  Alfred R. Grzenda,et al.  WATER POLLUTION BY INSECTICIDES IN AN AGRICULTURAL RIVER .BASIN. I. OCCURRENCE OF INSECTICIDES IN RIVER AND TREATED MUNICIPAL WATER , 1964 .

[12]  R. Muehlmann,et al.  Hydrolyse der insektiziden Phosphorsäureester , 1957 .

[13]  James R. Thomas,et al.  Decomposition of 2,4-dichlorophenoxyacetic Acid in Soil and Liquid Media1 , 1950 .

[14]  C. Wayman,et al.  Apparatus for Continuous Extraction of Nonpolar Compounds from Water Applied to Determination of Chlorinated Pesticides and Intermediates. , 1964 .

[15]  L. Davies,et al.  Improvement of identification in the gas-liquid chromatographic analysis of agricultural samples for residues of some chlorinated pesticides. Part I. Improvement of resolution on single columns and application of the multi-column “spectrochromatogram” , 1963 .

[16]  Francis M. Middleton,et al.  Chlorine Derivatives of Phenol Causing Taste and Odor , 1959 .

[17]  Alfred R. Grzenda,et al.  DDT Residues in Mountain Stream Water as Influenced by Treatment Practices , 1964 .

[18]  P. Bunyan The detection of organo-phosphorus pesticides on thin-layer chromatograms , 1964 .

[19]  J. Bunting,et al.  The thin-layer chromatographic determination of triazine herbicides in soil and water , 1965 .

[20]  Residue analytical limit of detectability. , 1965, Residue reviews.

[21]  F. M. Middleton,et al.  Chlorinated Insecticides in Surface Waters , 1959 .

[22]  W. Evans The paper-chromatographic separation and determination of chlorinated insecticide residues , 1962 .

[23]  Robert A. Baker Threshold Odors of Organic Chemicals , 1963 .

[24]  M. F. Kovacs Thin-Layer Chromatography for Organo Thiophosphate Pesticide Residue Determination , 1964 .

[25]  H. Page Nicholson,et al.  Insecticide Pollution of Water Resources , 1959 .

[26]  Jesse M. Cohen,et al.  Effect of Fish Poisons on Water Supplies Part 3. Field Study at Dickinson , 1961 .

[27]  J. Bates A general method for the determination of organophosphorus pesticide residues in foodstuffs. , 1965, In Analysis.

[28]  K. Dimick,et al.  Pesticide Analysis, Gas Chromatography Retention Times and Sensitivity Data for Insecticides and Herbicides , 1964 .

[29]  E. Hindin,et al.  Collection and analysis of synthetic organic pesticides from surface and ground water. , 1964, Residue reviews.

[30]  Jesse M. Cohen,et al.  Effect of Fish Poisons on Water Supplies Part 2. Odor Problems , 1961 .

[31]  M. Beroza,et al.  Thin-Layer Chromatography for Insecticide Analysis , 1963 .

[32]  J. A. Burke Programmed Temperature Gas Chromatography (PTGC) and Microcoulometric Detection of Chlorinated Insecticides , 1963 .

[33]  G. Zweig,et al.  SEPARATION AND DETERMINATION OF SEVERAL CHLORINATED PHENOXY-ACIDS BY GAS-LIQUID CHROMATOGRAPHY. , 1964, Journal of chromatography.

[34]  E. F. Williams Properties of O,O-Diethyl O-p-Nitrophenyl Thiophosphate and O,O-Diethyl O-p-Nitrophenyl Phosphate , 1951 .

[35]  B. Berck,et al.  Adsorption of DDT on Suspended Solids in River Water and its Role in Black-fly Control , 1953, Nature.

[36]  M. F. Kovacs Thin-Layer Chromatography for Chlorinated Pesticide Residue Analysis , 1963 .

[37]  I. West PESTICIDES AS CONTAMINANTS. , 1964, Archives of environmental health.

[38]  F. Middleton,et al.  Orangic Chemical Compounds in Raw and Filtered Surface Waters , 1951 .

[39]  B. Berck Microdetermination of DDT in River Water and suspended Solids. , 1953 .

[40]  A. P. Black,et al.  Chemical Characteristics of Fulvic Acids , 1963 .

[41]  Arnold E. Greenberg,et al.  Evaluation of the Carbon Adsorption Method , 1965 .

[42]  R. C. Blinn,et al.  Analysis of Insecticides and Acaricides , 1955 .

[43]  T. R. Walker,et al.  GROUND-WATER CONTAMINATION IN THE ROCKY MOUNTAIN ARSENAL AREA, DENVER, COLORADO , 1961 .

[44]  H. Egan,et al.  The chromatographic detection and determination of organo-chlorine herbicides in soil and water , 1964 .

[45]  A. Henglein,et al.  The New Insecticide O,O-Dimethyl 2,2,2-Trichloro-1-hydroxyethylphosphonate , 1955 .

[46]  Stephen L. Warnick,et al.  Determination of Pesticides by Electron Capture Gas Chromatography , 1965 .

[47]  R. Metcalf,et al.  Toxic Action of Dipterex and DDVP to the House Fly , 1959 .

[48]  Alfred R. Grzenda,et al.  Insecticide Contamination in a Farm Pond , 1962 .

[49]  J. Gillett,et al.  COLUMN PARTITION CHROMATOGRAPHY OF DDT AND RELATED COMPOUNDS. , 1964, Analytical biochemistry.

[50]  S. Faust,et al.  Herbicides in Surface Waters, Studies on Fate of 2,4-D and Ester Derivatives in Natural Surface Waters , 1964 .

[51]  R. A. Conkin THIN-LAYER CHROMATOGRAPHY IN THE DETERMINATION OF PESTICIDE RESIDUES. , 1964, Residue reviews.

[52]  J. Thomson,et al.  The application of thin-layer chromatographic techniques to the analysis of pesticide residues. , 1965, Residue reviews.

[53]  G. Yip Determination of 2,4-D and Other Chlorinated Phenoxy Alkyl Acids , 1962 .

[54]  S. Faust,et al.  Determination of Phenoxyacetic Acids with J and and Phenyl J Acids. , 1964 .

[55]  L. Giuffrida,et al.  Investigation of Two Gas Chromatographic Techniques for the Determination of Organophosphate Pesticide Residues , 1964 .

[56]  C. Chichester Research in pesticides. , 1965 .

[57]  N. Crosby,et al.  The use of infrared spectroscopy in the analysis of pesticide residues , 1964 .

[58]  William S. Cox,et al.  Determination of Pesticides in Water by Microcoulometric Gas Chromatography After Liquid‐Liquid Extraction , 1963 .

[59]  A. P. Black,et al.  Characteristics of Colored Surface Waters , 1963 .

[60]  B. Berck,et al.  Further Experiments With DDT in the Control of Simulium Arcticum Mall. In the North and South Saskatchewan Rivers1 , 1953 .

[61]  Samuel D. Faust,et al.  Chemical Methods for the Detection of Aquatic Herbicides , 1965 .

[62]  Walter H. Gutenmann,et al.  Gas Chromatographic Method for Silvex , 1964 .

[63]  O. B. Cope Effects of DDT Spraying for Spruce Budworm on Fish in the Yellowstone River System , 1961 .

[64]  Samuel D. Faust,et al.  Water Pollution by Organic Pesticides , 1964 .

[65]  P. W. West,et al.  Qualitative Microdetermination of Organic Phosphorous Compounds , 1957 .

[66]  S. Faust,et al.  Determination of 2,4‐Dichlorophenoxy Acetic Acid in Surface Waters , 1963 .

[67]  R. C. Blinn,et al.  The utilization of infrared and ultraviolet spectrophotometric procedures for assay of pesticide residues. , 1963, Residue reviews.

[68]  D. E. Coffix,et al.  Determination of Parathion, Methyl Parathion, EPN, and Their Oxons in Some Fruit and Vegetable Crops , 1963 .

[69]  W. Hayes,et al.  Insecticide Metabolism, The Detection of Dieldrin Metabolites in Human Urine , 1962 .

[70]  M. A. Millett,et al.  Techniques for Quantitative Thin Layer Chromatography. , 1964 .

[71]  W. Hancock,et al.  The determination of traces of benzene hexachloride in water and sewage effluents , 1955 .

[72]  S. Faust,et al.  Removal of 2,4‐Dichlorophenoxyacetic Acid Derivatives From Natural Waters , 1965 .

[73]  A. K. Andrews,et al.  Persistence of DDT and its Metabolites in a Farm Pond , 1963 .

[74]  DONALD E. Johnson,et al.  Selective Detection of Phosphorus, Sulfur, and Halogen Compounds in the Gas Chromatography of Drugs and Pesticides , 1965 .

[75]  Laupa Giuffrida A Flame Ionization Detector Highly Selective and Sensitive to Phosphorus—A Sodium Thermionic Detector , 1964 .

[76]  E. Sigworth Identification and Removal of Herbicides and Pesticides , 1965 .

[77]  J. J. Lichtenberg,et al.  DDT and Dieldrin in Rivers: A Report of the National Water Quality Network , 1963, Science.

[78]  Jesse M. Cohen,et al.  Effectiveness of Water Treatment Processes in Pesticide Removal , 1965 .

[79]  Robert A. Taft,et al.  INDUSTRIAL WASTES—Measurements of Organic Contaminants in the Nation's Rivers , 1960 .