Fiber-Optical Sensors: Basics and Applications in Multiphase Reactors

This work presents a brief introduction on the basics of fiber-optical sensors and an overview focused on the applications to measurements in multiphase reactors. The most commonly principle utilized is laser back scattering, which is also the foundation for almost all current probes used in multiphase reactors. The fiber-optical probe techniques in two-phase reactors are more developed than those in three-phase reactors. There are many studies on the measurement of gas holdup using fiber-optical probes in three-phase fluidized beds, but negative interference of particles on probe function was less studied. The interactions between solids and probe tips were less studied because glass beads etc. were always used as the solid phase. The vision probes may be the most promising for simultaneous measurements of gas dispersion and solids suspension in three-phase reactors. Thus, the following techniques of the fiber-optical probes in multiphase reactors should be developed further: (1) online measuring techniques under nearly industrial operating conditions; (2) corresponding signal data processing techniques; (3) joint application with other measuring techniques.

[1]  Aniruddha B. Pandit,et al.  Review on Mixing Characteristics in Solid‐Liquid and Solid‐Liquid‐Gas Reactor Vessels , 2008 .

[2]  Carolyn A. Koh,et al.  Measurement and Calibration of Droplet Size Distributions in Water-in-Oil Emulsions by Particle Video Microscope and a Focused Beam Reflectance Method , 2010 .

[3]  Dominique Toye,et al.  Imaging of liquid distribution in reactive distillation packings with a new high-energy x-ray tomograph , 2005 .

[4]  M. Pons,et al.  Using image analysis in the study of multiphase gas absorption , 2005 .

[5]  R. Braatz,et al.  Measurement of particle size distribution in suspension polymerization using in situ laser backscattering , 2003 .

[6]  Chao Yang,et al.  Numerical Simulation of Liquid-Solid Flow in an Unbaffled Stirred Tank with a Pitched-Blade Turbine Downflow , 2008 .

[7]  Hooman Nabovati,et al.  Fiber Optic Sensors , 2008 .

[8]  Maurice A. Bergougnou,et al.  Bubble measurement in three-phase fluidized beds using a u-shaped optical fiber , 1984 .

[9]  Paulo L.C. Lage,et al.  Experimental determination of bubble size distributions in bubble columns : prediction of mean bubble diameter and gas hold up , 1999 .

[10]  Kenneth T. V. Grattan,et al.  Fiber optic sensor technology: an overview , 2000 .

[11]  Hanning Li,et al.  Influence of slurry concentrations on bubble population and their rise velocities in a three-phase slurry bubble column , 2000 .

[12]  Mamoru Ishii,et al.  Local formulation and measurements of interfacial area concentration in two-phase flow , 1986 .

[13]  C. Bellefon,et al.  Solid effects on gas-liquid mass transfer in three-phase slurry catalytic hydrogenation of adiponitrile over raney nickel , 1996 .

[14]  Sang D. Kim,et al.  Bubble characteristics in the radial direction of three-phase fluidized beds , 1988 .

[15]  V. Thompson,et al.  Phase holdup, liquid dispersion, and gas-to-liquid mass transfer measurements in a three-phase magnetofluidized bed , 1997 .

[16]  Christophe Guy,et al.  Local measurements for the study of external loop airlift hydrodynamics , 1999 .

[17]  Liang-Shih Fan,et al.  Bubble characteristics in three-phase systems used for pulp and paper processing , 1996 .

[18]  Alvin W. Nienow,et al.  Mixing in large-scale vessels stirred with multiple radial or radial and axial up-pumping impellers: modelling and measurements , 2000 .

[19]  A. Pacek,et al.  Video technique for measuring dynamics of liquid‐liquid dispersion during phase inversion , 1994 .

[20]  E. Hurlburt,et al.  Measurement of drop size in horizontal annular flow with the immersion method , 2002 .

[21]  Liang-Shih Fan,et al.  Measurement of real-time flow structures in gas–liquid and gas–liquid–solid flow systems using electrical capacitance tomography (ECT) , 2001 .

[22]  Chao Yang,et al.  Experimental determination and numerical simulation of mixing time in a gas–liquid stirred tank , 2009 .

[23]  John R. Grace,et al.  Novel multifunctional optical‐fiber probe: II. High‐density CFB measurements , 2003 .

[24]  Yong Jin,et al.  Radial nonuniformity of flow structure in a liquid-solid circulating fluidized bed , 1996 .

[25]  Yousuk Cho,et al.  Bubble properties and pressure fluctuations in pressurized bubble columns , 2000 .

[26]  Cedric Briens,et al.  Application of fiber optic reflection probes to the measurement of local particle velocity and concentration in gas—solid flow , 1994 .

[27]  M. Ishii,et al.  Local two-phase flow measurements using sensor techniques , 1997 .

[28]  Sebastian Maaß,et al.  Experimental comparison of measurement techniques for drop size distributions in liquid/liquid dispersions , 2011 .

[29]  Panagiota Angeli,et al.  Drop size distribution in highly concentrated liquid–liquid dispersions using a light back scattering method , 2005 .

[30]  J. Chaouki,et al.  Noninvasive Tomographic and Velocimetric Monitoring of Multiphase Flows , 1997 .

[31]  J. R. Bourne,et al.  Homogeneous particle suspension in propeller-agitated flat bottomed tanks , 1974 .

[32]  M. Kraume,et al.  On-line measurement technique for drop size distributions in liquid/liquid systems at high dispersed phase fractions , 2000 .

[33]  A. Cartellier,et al.  Measurement of gas phase characteristics using a monofibre optical probe in a three-phase flow , 2008 .

[34]  Pentti Saarenrinne,et al.  Digital imaging measurement of dense multiphase flows in industrial processes , 2010 .

[35]  Ibrahim Hassan,et al.  Two-phase bubbly flow structure in large-diameter vertical pipes , 2008 .

[36]  Zai-Sha Mao,et al.  Experimental Study on Liquid-Liquid Macromixing in a Stirred Tank , 2011 .

[37]  François Puel,et al.  Study of droplet size distribution during an emulsification process using in situ video probe coupled with an automatic image analysis , 2010 .

[38]  R. F. Mudde,et al.  Application of LDA to bubbly flows , 1998 .

[39]  W. K. Harteveld,et al.  Bubble columns : Structures or stability? , 2005 .

[40]  P Angeli,et al.  Scale-down studies on the hydrodynamics of two-liquid phase biocatalytic reactors , 2002, Bioprocess and biosystems engineering.

[41]  Hiroyuki Kage,et al.  The use of optic fiber probes for the measurement of dilute particle concentrations: calibration and application to gas-fluidized bed carryover , 1983 .

[42]  John R. Grace,et al.  Voidage profiles in a circulating fluidized bed of square cross-section , 1994 .

[43]  David Wong,et al.  Bubble Behaviour in Three Phase Capillary Microreactors , 2003 .

[44]  Chao Yang,et al.  CFD-PBE simulation of premixed continuous precipitation incorporating nucleation, growth and aggregation in a stirred tank with multi-class method , 2012 .

[45]  S. Guet,et al.  Bubble size effect on the gas-lift technique , 2004 .

[46]  Alvin W. Nienow,et al.  On the structure of turbulent liquid—liquid dispersed flows in an agitated vessel , 1994 .

[47]  Chao Yang,et al.  Large eddy simulation of liquid flow in a stirred tank with improved inner-outer iterative algorithm , 2006 .

[48]  S. M. Ghiaasiaan,et al.  Flow regimes and gas holdup in paper pulp–water–gas three-phase slurry flow , 2003 .

[49]  Nigel N. Clark,et al.  Chord length distributions related to bubble size distributions in multiphase flows , 1988 .

[50]  Marek C. Ruzicka,et al.  EFFECT OF SOLIDS ON HOMOGENEOUS-HETEROGENEOUS FLOW REGIME TRANSITION IN BUBBLE COLUMNS , 2005 .

[51]  A. Kersey A Review of Recent Developments in Fiber Optic Sensor Technology , 1996 .

[52]  Jam Hans Kuipers,et al.  Measurements of solids concentration and axial solids velocity in gas-solid two-phase flows. , 1996 .

[53]  H. H. Bruun,et al.  Hot-Wire Anemometry: Principles and Signal Analysis , 1996 .

[54]  Z. C. Liu,et al.  A backlighted imaging technique for particle size measurements in two-phase flows , 1998 .

[55]  Wen Jianping,et al.  Local hydrodynamics in a gas-liquid-solid three-phase bubble column reactor , 1998 .

[56]  Geoffrey F. Hewitt,et al.  Measurement of bubble size distribution using a flying optical probe technique: Application in the highly turbulent region above a distillation plate , 2007 .

[57]  Shahzad Barghi,et al.  Phase holdup measurement in a gas–liquid–solid circulating fluidized bed (GLSCFB) riser using electrical resistance tomography and optical fibre probe , 2009 .

[58]  S. L. McKee,et al.  Development of solid—liquid mixing models using tomographic techniques , 1995 .

[59]  Mingzhong Li,et al.  Determination of non-spherical particle size distribution from chord length measurements. Part 1: Theoretical analysis , 2005 .

[60]  Hideo Nakamura,et al.  Methodological improvement of an intrusive four-sensor probe for the multi-dimensional two-phase flow measurement , 2005 .

[61]  R. F. Mudde,et al.  Time dependent behaviour of the flow in a bubble column , 1995 .

[62]  Ying Zheng,et al.  Radial Distribution of Liquid Velocity in a Liquid-Solids Circulating Fluidized Bed , 2003 .

[63]  J. Joshi,et al.  CFD simulations of gas-liquid-solid stirred reactor: prediction of critical impeller speed for solid suspension , 2007 .

[64]  Aniruddha B. Pandit,et al.  Mixing in mechanically agitated gas-liquid contactors, bubble columns and modified bubble columns , 1983 .

[65]  Hideo Nakamura,et al.  Error reduction, evaluation and correction for the intrusive optical four-sensor probe measurement in multi-dimensional two-phase flow , 2008 .

[66]  Zai-Sha Mao,et al.  CFD simulation of hydrodynamics and mass transfer in an internal airlift loop reactor using a steady two-fluid model , 2010 .

[67]  Ivan Fořt Comments to “CFD simulation of stirred tanks: Comparison of turbulence models. Part I: Radial flow impellers” and “Part II: Axial flow impellers, multiple impellers and multiphase dispersions” , 2012 .

[68]  Andreas Lübbert,et al.  Flow structure of the dispersed gasphase in real multiphase chemical reactors investigated by a new ultrasound–doppler technique , 1991 .

[69]  Shahzad Barghi,et al.  Radial Distributions of Phase Holdups and Phase Propagation Velocities in a Three-Phase Gas−Liquid−Solid Fluidized Bed (GLSCFB) Riser , 2009 .

[70]  Joachim Werther,et al.  ANALYSIS OF THE LOCAL STRUCTURE OF THE TWO PHASE FLOW IN A FAST FLUIDIZED BED , 1986 .

[71]  J. Teixeira,et al.  Oxygen mass transfer in a high solids loading three-phase internal-loop airlift reactor , 2001 .

[72]  Mamoru Ishii,et al.  Local interfacial area measurement in bubbly flow , 1992 .

[73]  Doraiswami Ramkrishna,et al.  Droplet breakage in stirred dispersions. Breakage functions from experimental drop-size distributions , 1996 .

[74]  Carolyn A. Koh,et al.  Measuring the particle size of a known distribution using the focused beam reflectance measurement technique , 2008 .

[75]  Juan C. Lasheras,et al.  On the breakup of an air bubble injected into a fully developed turbulent flow. I - Breakup frequency , 1999 .

[76]  John R. Grace,et al.  Flow regime identification in gas-liquid flow and three-phase fluidized beds , 1997 .

[77]  M. Assirelli,et al.  Mixing Study in Batch Stirred Vessels using a Fibre-Optic UV-VIS Monitoring Technique , 2007 .

[78]  Vivek V. Ranade,et al.  Gas–liquid flow generated by a Rushton turbine in stirred vessel: CARPT/CT measurements and CFD simulations , 2005 .

[79]  Zai-Sha Mao,et al.  Experimental Studies on Suspension of Solid Particles in a Low‐Shear Stirred Vessel , 2011 .

[80]  Pui Shan Chow,et al.  Interpretation of Focused Beam Reflectance Measurement (FBRM) Data via Simulated Crystallization , 2008 .

[81]  Barry J. Azzopardi,et al.  Comparison of laser-based drop-size measurement techniques and their application to dispersed liquid-liquid pipe flow , 2000 .

[82]  Mamoru Ishii,et al.  Local measurement of interfacial area, interfacial velocity and liquid turbulence in two-phase flow , 1998 .

[83]  Liang-Shih Fan,et al.  ECT imaging of three-phase fluidized bed based on three-phase capacitance model , 2003 .

[84]  H. de Lasa,et al.  Gas holdups and bubble characteristics in a bubble column operated at high temperature , 1993 .

[85]  Frederic Augier,et al.  On the reliability of an optical fibre probe in bubble column under industrial relevant operating conditions , 2007 .

[86]  M. Louge,et al.  Optical fiber measurements of particle concentration in dense suspensions: calibration and simulation. , 1992, Applied optics.

[87]  Reinhard Polke,et al.  Laser Diffraction Spectrometers/Experience in Particle Size Analysis , 1984 .

[88]  Yoshinori Kawase,et al.  Suspension of solid particles in multi‐impeller three‐phase stirred tank reactors , 2001 .

[89]  Jacques Bouillard,et al.  Liquid flow velocity measurements in stirred tanks by ultra-sound Doppler velocimetry , 2001 .

[90]  Tao Wang,et al.  Numerical and Experimental Studies on Multiphase Flow in Stirred Tanks , 2012 .

[91]  J. Pereira,et al.  The prediction of distillation plate efficiencies from froth properties , 1977 .

[92]  William B. Spillman,et al.  Fiber optic sensors : an introduction for engineers and scientists , 2011 .

[93]  Marco Mazzotti,et al.  Restoration of PSD from Chord Length Distribution Data using the Method of Projections onto Convex Sets , 2005 .

[94]  Shahzad Barghi,et al.  Electrical resistance tomography for flow characterization of a gas–liquid–solid three-phase circulating fluidized bed , 2007 .

[95]  Alvin W. Nienow,et al.  On impeller circulation and mixing effectiveness in the turbulent flow regime , 1997 .

[96]  Panagiota Angeli,et al.  Evaluation of drop size distribution from chord length measurements , 2006 .

[97]  Yuichi Murai,et al.  Inverse Energy Cascade Structure of Turbulence in a Bubbly Flow. PIV Measurement and Results. , 2000 .

[98]  Keith J. Carpenter,et al.  Process Development: Physicochemical Concepts , 2000 .

[99]  Gabriel Wild,et al.  Liquid Distribution in Trickle-Bed Reactor , 2000 .

[100]  R. F. Mudde,et al.  Experimental investigation of three-phase flow in a vertical pipe: Local characteristics of the gas phase for gas-lift conditions , 2007 .

[101]  Chinmay V. Rane,et al.  CFD simulation of stirred tanks: Comparison of turbulence models. Part I: Radial flow impellers , 2011 .

[102]  L. Musil,et al.  Suspending solid particles in an agitated conical-bottom tank , 1978 .

[103]  A. Selvarajan,et al.  Fiber optic sensors and their applications , 2012 .

[104]  Song Qin,et al.  Direct measurements of particle velocities in gas–solids suspension flow using a novel five-fiber optical probe , 2001 .

[105]  Kai Zhang,et al.  Gas holdup and bubble dynamics in a three-phase internal loop reactor with external slurry circulation , 2010 .

[106]  Rogerio T. Ramos,et al.  Multi-phase-fluid discrimination with local fibre-optical probes : I. Liquid/liquid flows , 1999 .

[107]  Michael Yianneskis,et al.  Dynamic tracking of fast liquid-liquid dispersion processes with a real-time in-situ optical technique , 2004 .

[108]  Alan M. O’Rourke,et al.  A comparison of measurement techniques used in the analysis of evolving liquid–liquid dispersions , 2005 .

[109]  Filip Johnsson,et al.  Radial voidage profiles in fast fluidized beds of different diameters , 1991 .

[110]  Uwe Hampel,et al.  Application of high-resolution gamma ray tomography to the measurement of gas hold-up distributions in a stirred chemical reactor , 2007 .

[111]  O. M. Ilyas,et al.  The application of electrical impedance tomography to mixing in stirred vessels , 1992 .

[112]  Nobuya Fujiwara,et al.  Gas-liquid mass transfer characteristics in a bubble column with suspended sparingly soluble fine particles , 1985 .

[113]  Frederic Augier,et al.  Application of the double optic probe technique to distorted tumbling bubbles in aqueous or organic liquid , 2005 .

[114]  P. H. Calderbank Limitations of Burgess-Calderbank probe technique for characterization of gas liquid dispersions on sieve trays , 1978 .

[115]  Juan C. Lasheras,et al.  On the breakup of an air bubble injected into a fully developed turbulent flow. Part 1. Breakup frequency , 1999, Journal of Fluid Mechanics.

[116]  Maurice A. Bergougnou,et al.  A U-SHAPED FIBER OPTIC PROBE TO STUDY THREE-PHASE FLUIDIZED BEDS , 1986 .

[117]  L. Musil THE HYDRODYNAMICS OF MIXED CRYSTALLIZERS , 1976 .

[118]  Maurice A. Bergougnou,et al.  A novel calibration procedure for a fiber optic solids concentration probe , 1998 .

[119]  Franco Magelli,et al.  Solids concentration profiles in a mechanically stirred and staged column slurry reactor , 1985 .

[120]  Jesse Zhu,et al.  Axial and radial solids distribution in a long and high‐flux CFB riser , 2001 .

[121]  H. de Lasa,et al.  Phase holdups in three‐phase fluidized beds , 1987 .

[122]  Judy A Raper,et al.  Limitations of the Burgess-Calderbank Probe Technique for Characterisation of Gas-Liquid Dispersions on Sieve Trays , 1978 .

[123]  Shigeo Uchida,et al.  Cross-sectional distributions of gas and solid holdups in slurry bubble column investigated by ultrasonic computed tomography , 1999 .

[124]  Christophe Gourdon,et al.  Experimental study of drop size distributions at high phase ratio in liquid–liquid dispersions , 2003 .

[125]  Yong Jin,et al.  Experimental study on bubble behavior in gas-liquid-solid three-phase circulating fluidized beds , 2003 .

[126]  Lawrence L. Tavlarides,et al.  Laser capillary spectrophotometry for drop-size concentration measurements , 1989 .

[127]  J. J. Frijlink Physical aspects of gassed suspension reactors , 1987 .

[128]  Gabriel Wild,et al.  Measuring techniques in gas–liquid and gas–liquid–solid reactors , 2002 .

[129]  E. L. Paul,et al.  Handbook of Industrial Mixing , 2003 .

[130]  Byoungho Lee,et al.  Review of the present status of optical fiber sensors , 2003 .

[131]  Jesse Zhu,et al.  Particle velocity and flow development in a long and high-flux circulating fluidized bed riser , 2001 .