Protonic nonvolatile field effect transistor memories in Si/SiO/sub 2//Si structures

A low-voltage, radiation-tolerant, nonvolatile field effect transistor (NVFET) memory involving proton motion in SiO/sub 2/ is illustrated in both bulk Si and silicon-on-insulator devices. We discuss a mechanism by which the protons are created in the oxide layer by a forming gas anneal. At low temperature (T<250/spl deg/C), the H/sup +/ is largely "imprisoned" in the buried SiO/sub 2/ layer; i.e., the ions are sandwiched between the two encapsulating Si layers. The Si layers can be either c-Si or poly-Si, thus the technology is compatible with standard Si processing. The protons can be reliably and controllably drifted from one interface to another without any noticeable degradation in the signal past 10/sup 6/ cycles. Under an unbiased condition, the net proton density is not significantly affected by radiation up to at least 100 krad (SiO/sub 2/). Last, we compare many of the properties of the NVFET to commercial flash nonvolatile memories.

[1]  Shashi P. Karna,et al.  Irradiation response of mobile protons in buried SiO/sub 2/ films , 1997 .

[2]  Daniel M. Fleetwood,et al.  1/f noise, hydrogen transport, and latent interface-trap buildup in irradiated MOS devices , 1997 .

[3]  Hydrogen in crystalline semiconductors , 1987 .

[4]  Tetsuo Endoh,et al.  Reliability issues of flash memory cells , 1993, Proc. IEEE.

[5]  Daniel M. Fleetwood,et al.  Border traps: issues for MOS radiation response and long-term reliability , 1995 .

[6]  P. S. Winokur,et al.  Field- and Time-Dependent Radiation Effects at the SiO2/Si Interface of Hardened MOS Capacitors , 1977, IEEE Transactions on Nuclear Science.

[7]  D. Dimaria,et al.  Temperature dependence of trap creation in silicon dioxide , 1990 .

[8]  D. Fleetwood,et al.  Non-volatile memory device based on mobile protons in SiO2 thin films , 1997, Nature.

[9]  P. S. Winokur,et al.  The Role of Hydrogen in Radiation-Induced Defect Formation in Polysilicon Gate MOS Devices , 1987, IEEE Transactions on Nuclear Science.

[10]  T. F. Wrobel Radiation characterization of a 28C256 EEPROM , 1989 .

[11]  B. Aspar,et al.  O interstitial generation and diffusion in high temperature annealed Si/SiO2/Si structures , 1996 .

[12]  P. Fazan Trends in the development of ULSI DRAM capacitors , 1994 .

[13]  S. R. Hofstein Proton and sodium transport in SiO 2 films , 1967 .

[14]  A. Stesmans,et al.  Positive charging of buried SiO2 by hydrogenation , 1994 .

[15]  James H. Stathis,et al.  Passivation and depassivation of silicon dangling bonds at the Si/SiO2 interface by atomic hydrogen , 1993 .

[16]  Brower Dissociation kinetics of hydrogen-passivated (111) Si-SiO2 interface defects. , 1990, Physical review. B, Condensed matter.

[17]  F. B. McLean A Framework for Understanding Radiation-Induced Interface States in SiO2 MOS Structures , 1980, IEEE Transactions on Nuclear Science.

[18]  E. Poindexter,et al.  MOS interface states: overview and physicochemical perspective , 1989 .

[19]  J. Leray,et al.  Ultraviolet radiation induced defect creation in buried SiO2 layers , 1991 .

[20]  N. Saks,et al.  Time-dependence of the interface trap build-up in deuterium-annealed oxides after irradiation , 1992 .

[21]  Radiation-Induced Paramagnetic Defects in MOS Structures , 1982, IEEE Transactions on Nuclear Science.

[22]  C. H. Seager,et al.  The diffusion of hydrogen in silicon and mechanisms for “unintentional” hydrogenation during ion beam processing , 1987 .

[23]  B. J. Mrstik,et al.  Model for Si–SiO2 interface state formation during irradiation and during post‐irradiation exposure to hydrogen environment , 1991 .

[24]  S. Fonash,et al.  Hydrogen anneal of E′ centers in thermal SiO2 on Si , 1990 .

[25]  Johnson,et al.  Interstitial hydrogen and neutralization of shallow-donor impurities in single-crystal silicon. , 1986, Physical review letters.

[26]  G. Smolinsky,et al.  Detection of water‐related charge in electronic dielectrics , 1989 .

[27]  Arthur H. Edwards,et al.  Post‐irradiation cracking of H2 and formation of interface states in irradiated metal‐oxide‐semiconductor field‐effect transistors , 1993 .

[28]  J. F. Conley,et al.  Molecular hydrogen, E' center hole traps, and radiation induced interface traps in MOS devices , 1993 .

[29]  T. A. Dellin,et al.  Radiation response of floating gate EEPROM memory cells , 1989 .

[30]  Daniel M. Fleetwood,et al.  Mechanism for anneal‐induced interfacial charging in SiO2 thin films on Si , 1996 .

[31]  John F. Conley,et al.  Room temperature reactions involving silicon dangling bond centers and molecular hydrogen in amorphous SiO2 thin films on silicon , 1993 .