Magnetic polyurethane elastomers with wide range modulation of elasticity

A new magnetorheological elastomer that demonstrates drastic and reversible changes in dynamic modulus in air was obtained. The magnetic elastomer consists of polyurethane and carbonyl iron particles. The magnetic elastomer with a volume fraction of 0.29 exhibited a reversible increase by factors of 277 of the storage modulus and 96 of the loss modulus upon a magnetic field of 500 mT. The elastomer underwent high mechanical toughness with a braking strain exceeding 0.8, and demonstrates the giant magnetorheological behavior for half a year after the synthesis without degradation.

[1]  Mattias Lokander,et al.  Improving the magnetorheological effect in isotropic magnetorheological rubber materials , 2003 .

[2]  J. Gong,et al.  Magnetism and compressive modulus of magnetic fluid containing gels , 1999 .

[3]  Albert Einstein,et al.  Berichtigung zu meiner Arbeit: „Eine neue Bestimmung der Moleküldimensionen”︁ [AdP 34, 591 (1911)] , 2005, Annalen der Physik.

[4]  Georges Bossis,et al.  FIELD DEPENDENCE OF VISCOELASTIC PROPERTIES OF MR ELASTOMERS , 2002 .

[5]  John Matthew Ginder,et al.  MAGNETOSTRICTIVE PHENOMENA IN MAGNETORHEOLOGICAL ELASTOMERS , 2002 .

[6]  J. Takimoto,et al.  Giant Complex Modulus Reduction of κ-Carrageenan Magnetic Gels , 2005 .

[7]  Eduardo Mendes,et al.  Enhanced hardening of soft self-assembled copolymer gels under homogeneous magnetic fields , 2010 .

[8]  Miklós Zrínyi,et al.  Novel highly elastic magnetic materials for dampers and seals: Part I. Preparation and characterization of the elastic materials , 2007 .

[9]  Jun-ichi Takimoto,et al.  Giant Reduction in Dynamic Modulus of κ-Carrageenan Magnetic Gels , 2006 .

[10]  T. Reitberger,et al.  Oxidation of natural rubber-based magnetorheological elastomers , 2004 .

[11]  Mattias Lokander,et al.  Performance of isotropic magnetorheological rubber materials , 2003 .

[12]  T. Mitsumata,et al.  Magnetization-Induced Reduction in Dynamic Modulus of Polyurethane Elastomers Loaded with Ferrite , 2007 .

[13]  T. Mitsumata,et al.  Magnetic-field Sensitive Gels with Wide Modulation of Dynamic Modulus , 2009 .

[14]  Weihua Li,et al.  Study on the damping properties of magnetorheological elastomers based on cis-polybutadiene rubber , 2008 .

[15]  Mark R. Jolly,et al.  The Magnetoviscoelastic Response of Elastomer Composites Consisting of Ferrous Particles Embedded in a Polymer Matrix , 1996 .

[16]  A. R. Payne A note on the existence of a yield point in the dynamic modulus of loaded vulcanizates , 1960 .

[17]  M. Zrínyi,et al.  Magnetic field sensitive functional elastomers with tuneable elastic modulus , 2006 .

[18]  Miklós Zrínyi,et al.  Novel highly elastic magnetic materials for dampers and seals: part II. Material behavior in a magnetic field , 2007 .

[19]  Toshio Kurauchi,et al.  Magnetroviscoelastic behavior of composite gels , 1995 .

[20]  Takashi Wakabayashi,et al.  Particle dispersibility and giant reduction in dynamic modulus of magnetic gels containing barium ferrite and iron oxide particles. , 2008, The journal of physical chemistry. B.