Sensor for Determining Single Droplet Acidities in the Venusian Atmosphere

The cloud layers of Venus are known to have pressures and temperatures comparable to those on Earth, but, at the same time, many details about the environment inside them are unknown. The early consensus was that Venusian clouds are composed of droplets of near concentrated sulfuric acid with very limited water availability; newer models, however, suggest a pH range between −1 and 1, and these imply some form of a neutralizing agent and potentially complex chemical cycles. It is also possible that different populations of cloud particles have different acidities. To answer these questions, we propose an in situ acidity sensor that can statistically determine the acidities of individual cloud droplets from concentrated sulfuric acid (18 M) to deionized water, based on the fluorescence of a pigment that is immobilized in a film and read out using a set of excited LEDs and a camera. Here, we present the preliminary research and prototyping results and suggest a possible design for this sensor.

[1]  D. Baumgardner,et al.  Rocket Lab Mission to Venus , 2022, Aerospace.

[2]  J. Longuski,et al.  Aerial Platform Design Options for a Life-Finding Mission at Venus , 2022, Aerospace.

[3]  J. Longuski,et al.  Mission Architecture to Characterize Habitability of Venus Cloud Layers via an Aerial Platform , 2022, Aerospace.

[4]  W. Bains,et al.  Production of ammonia makes Venusian clouds habitable and explains observed cloud-level chemical anomalies , 2021, Proceedings of the National Academy of Sciences.

[5]  S. P. Worden,et al.  Venus Life Finder Mission Study , 2021, 2112.05153.

[6]  Marcus K. Dymond,et al.  Water activity in Venus’s uninhabitable clouds and other planetary atmospheres , 2021, Nature Astronomy.

[7]  M. Rottman,et al.  Fluorescein Derivatives as Fluorescent Probes for pH Monitoring along Recent Biological Applications , 2020, International journal of molecular sciences.

[8]  W. Bains,et al.  The Venusian Lower Atmosphere Haze as a Depot for Desiccated Microbial Life: A Proposed Life Cycle for Persistence of the Venusian Aerial Biosphere. , 2020, Astrobiology.

[9]  Nuonuo Zhang,et al.  A simple acidic ‘turn-on’ fluorescent pH probe based on BOPYIN and its visual detection and cellular imaging , 2020, Dyes and Pigments.

[10]  Ravindra V. Gadhave,et al.  Study of Cross-Linking between Boric Acid and Different Types of Polyvinyl Alcohol Adhesive , 2019, Open Journal of Polymer Chemistry.

[11]  Hans-Peter Klenk,et al.  Picrophilus oshimae and Picrophilus torridus fam. nov., gen. nov., sp. nov., Two Species of Hyperacidophilic, Thermophilic, Heterotrophic, Aerobic Archaea , 1996 .

[12]  L. Lindqvist,et al.  The pH dependence of fluorescein fluorescence , 1975 .

[13]  L. Lindqvist THE TRIPLET STATE OF FLUORESCEIN IN SULFURIC ACID1 , 1963 .