Modeling of Nanotips Fabricated by Local Electron Bombardment

Nanotips have attracted increasing interest in several aspects of nanotechnology, particularly in nanotip-based microscopy and nano-characterization. Therefore, fabricating nanotips with well-defined shapes and in a highly controlled process is vital for these applications. Here, we present some characterization analysis of nanotips fabricated by the recently developed local electron bombardment method. We highlight the importance of using spherical crystal models to reproduce the nanotip atomic structure as a way to estimate the nanotip size, rather than using the conventional ring counting method. The nanotip shape is modeled by building the crystal structure of the nanotip apex to estimate its size. Then, the overall nanotip shape is estimated by sequentially destructing the entire nanotip and utilizing finite element simulation tools to build the nanotip model. The simulation model is made in a way to generate the same threshold electric field, in the field ion microscope, before and after the nanotip destruction.

[1]  P. Grütter,et al.  Minimum threshold for incipient plasticity in the atomic-scale nanoindentation of Au(111). , 2013, Physical review letters.

[2]  C. Wilbertz,et al.  Field electron emission properties of a supertip , 1996 .

[3]  F. Feschet,et al.  Nanotips and nanomagnetism , 1998 .

[4]  M. Rezeq,et al.  Nanotips with a single atom end as ideal sources of electron and ion beams: Modeling of the nanotip shape , 2013 .

[5]  P. Avouris Manipulation of Matter at the Atomic and Molecular Levels , 1995 .

[6]  Ing-Shouh Hwang,et al.  Preparation and Characterization of Single-Atom Tips , 2004 .

[7]  R. Nichols,et al.  Molecular wire formation from viologen assemblies. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[8]  R. Nichols,et al.  Measurement of single molecule conductivity using the spontaneous formation of molecular wires , 2004 .

[9]  Michael K Miller,et al.  Atom Probe Field Ion Microscopy , 1996 .

[10]  T. Tsong,et al.  A single-atom sharp iridium tip as an emitter of gas field ion sources , 2009, Nanotechnology.

[11]  Jason Pitters,et al.  Tungsten nanotip fabrication by spatially controlled field-assisted reaction with nitrogen. , 2006, The Journal of chemical physics.

[12]  Ahmed Ali,et al.  Fabrication of nano ion–electron sources and nano-probes by local electron bombardment , 2015 .

[13]  Fang,et al.  Reversible, nanometer-scale conductance transitions in an organic complex , 2000, Physical review letters.

[14]  Robert A. Wolkow,et al.  Field regulation of single-molecule conductivity by a charged surface atom , 2005, Nature.

[15]  Peter H. Bartels,et al.  Field ion microscopy;: Principles and applications, , 1969 .

[16]  N. Motta,et al.  Copper phthalocyanine on Si(111)-7 × 7 and Si(001)-2 × 1: an XPS/AES and STM study , 1994 .

[17]  H. Hölscher,et al.  Field ion microscopy characterized tips in noncontact atomic force microscopy: Quantification of long-range force interactions , 2013 .

[18]  Joachim,et al.  Electronic transparence of a single C60 molecule. , 1995, Physical review letters.

[19]  H-W Fink Mono-atomic tips for scanning tunneling microscopy , 1986, IBM J. Res. Dev..

[20]  Kazuya Yuasa,et al.  Modified Fowler-Nordheim field emission formulae from a nonplanar emitter model , 2002 .

[21]  Vu Thien Binh,et al.  Characterization of microtips for scanning tunneling microscopy , 1988 .

[22]  FIM tips in SPM: Apex orientation and temperature considerations on atom transfer and diffusion , 2013, 1308.0714.