Highly efficient charge-carrier generation and collection in polymer/polymer blend solar cells with a power conversion efficiency of 5.7%

A polymer/polymer blend solar cell with an external quantum efficiency approaching 60% and the best power conversion efficiency of 5.73% is fabricated. The efficient charge-carrier generation and collection, comparable to those of polymer/fullerene solar cells, are found to be the main reasons for the superior device performance.

[1]  Alan J. Heeger,et al.  Intensity dependence of current-voltage characteristics and recombination in high-efficiency solution-processed small-molecule solar cells. , 2013, ACS nano.

[2]  Yong Cao,et al.  Simultaneous Enhancement of Open‐Circuit Voltage, Short‐Circuit Current Density, and Fill Factor in Polymer Solar Cells , 2011, Advanced materials.

[3]  Jian Pei,et al.  New polymer acceptors for organic solar cells: the effect of regio-regularity and device configuration , 2013 .

[4]  D. Gebeyehu,et al.  Highly efficient p-i-n type organic photovoltaic devices , 2003 .

[5]  Ingo Riedel,et al.  Effect of Temperature and Illumination on the Electrical Characteristics of Polymer–Fullerene Bulk‐Heterojunction Solar Cells , 2004 .

[6]  Kazuhito Hashimoto,et al.  Control of Miscibility and Aggregation Via the Material Design and Coating Process for High‐Performance Polymer Blend Solar Cells , 2013, Advanced materials.

[7]  Jenny Nelson,et al.  Diffusion-limited recombination in polymer-fullerene blends and its influence on photocurrent collection , 2003 .

[8]  W. Warta,et al.  Solar cell efficiency tables (version 43) , 2014 .

[9]  V. Mihailetchi,et al.  Compositional dependence of the performance of poly(p-phenylene vinylene) , 2005 .

[10]  D. Bradley,et al.  Organic Photovoltaic Devices Based on Blends of Regioregular Poly(3-hexylthiophene) and Poly(9,9-dioctylfluorene-co-benzothiadiazole) , 2004 .

[11]  V. Mihailetchi,et al.  Space-charge limited photocurrent. , 2005, Physical review letters.

[12]  Jian Tang,et al.  Recent progress in the design of narrow bandgap conjugated polymers for high-efficiency organic solar cells , 2012 .

[13]  Yu-Shan Cheng,et al.  Fullerene Derivative‐Doped Zinc Oxide Nanofilm as the Cathode of Inverted Polymer Solar Cells with Low‐Bandgap Polymer (PTB7‐Th) for High Performance , 2013, Advanced materials.

[14]  H. Ohkita,et al.  Polymer/polymer blend solar cells with 2.0% efficiency developed by thermal purification of nanoscale-phase-separated morphology. , 2011, ACS applied materials & interfaces.

[15]  Valentin D. Mihailetchi,et al.  Charge Transport and Photocurrent Generation in Poly(3‐hexylthiophene): Methanofullerene Bulk‐Heterojunction Solar Cells , 2006 .

[16]  Man Hoi Wong,et al.  How to make ohmic contacts to organic semiconductors. , 2004, Chemphyschem : a European journal of chemical physics and physical chemistry.

[17]  Yongfang Li Molecular design of photovoltaic materials for polymer solar cells: toward suitable electronic energy levels and broad absorption. , 2012, Accounts of chemical research.

[18]  Alberto Salleo,et al.  High Performance All‐Polymer Solar Cell via Polymer Side‐Chain Engineering , 2014, Advanced materials.

[19]  O. Inganäs,et al.  Structure–property relationships of oligothiophene–isoindigo polymers for efficient bulk-heterojunction solar cells , 2014 .

[20]  Changduk Yang,et al.  High-efficiency polymer solar cells with a cost-effective quinoxaline polymer through nanoscale morphology control induced by practical processing additives , 2013 .

[21]  Daisuke Mori,et al.  Low‐Bandgap Donor/Acceptor Polymer Blend Solar Cells with Efficiency Exceeding 4% , 2014 .

[22]  A. Facchetti,et al.  A high-mobility electron-transporting polymer for printed transistors , 2009, Nature.

[23]  George G. Malliaras,et al.  Electrical characteristics and efficiency of single-layer organic light-emitting diodes , 1998 .

[24]  P. Blom,et al.  Origin of the Reduced Fill Factor and Photocurrent in MDMO‐PPV:PCNEPV All‐Polymer Solar Cells , 2007 .

[25]  H. Ohkita,et al.  Polymer/polymer blend solar cells improved by using high-molecular-weight fluorene-based copolymer as electron acceptor. , 2012, ACS applied materials & interfaces.

[26]  Samson A Jenekhe,et al.  All-polymer solar cells with 3.3% efficiency based on naphthalene diimide-selenophene copolymer acceptor. , 2013, Journal of the American Chemical Society.

[27]  Long Ye,et al.  Binary additives synergistically boost the efficiency of all-polymer solar cells up to 3.45% , 2014 .

[28]  Robert P. H. Chang,et al.  Morphology‐Performance Relationships in High‐Efficiency All‐Polymer Solar Cells , 2014 .

[29]  Miao Xu,et al.  Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure , 2012, Nature Photonics.

[30]  Shijun Jia,et al.  Polymer–Fullerene Bulk‐Heterojunction Solar Cells , 2009, Advanced materials.

[31]  Feng Xu,et al.  Replacing alkoxy groups with alkylthienyl groups: a feasible approach to improve the properties of photovoltaic polymers. , 2011, Angewandte Chemie.

[32]  Gang Li,et al.  Highly efficient solar cell polymers developed via fine-tuning of structural and electronic properties. , 2009, Journal of the American Chemical Society.

[33]  P. Blom,et al.  Charge transport in MDMO-PPV:PCNEPV all-polymer solar cells , 2007 .

[34]  Antonio Facchetti,et al.  Polymer donor–polymer acceptor (all-polymer) solar cells , 2013 .

[35]  Meng-Huan Jao,et al.  Additives for morphology control in high-efficiency organic solar cells , 2013 .

[36]  Christoph J. Brabec,et al.  Recombination and loss analysis in polythiophene based bulk heterojunction photodetectors , 2002 .

[37]  Gang Li,et al.  For the Bright Future—Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% , 2010, Advanced materials.

[38]  Kazuhito Hashimoto,et al.  All-polymer solar cells from perylene diimide based copolymers: material design and phase separation control. , 2011, Angewandte Chemie.

[39]  Yang Yang,et al.  Polymer solar cells with enhanced open-circuit voltage and efficiency , 2009 .