Synthesis and characterisation of new pyrazole–phosphinite ligands and their ruthenium(II) arene complexes

[1]  J. Pons,et al.  Stereochemical structure determination of p-cymene Ru(II) complexes containing the PPh2Py ligand with 2-D NOESY and HMQC NMR experiments , 2005 .

[2]  C. Claver,et al.  Carbohydrate derivative ligands in asymmetric catalysis , 2004 .

[3]  P. Braunstein Functional Ligands and Complexes for New Structures, Homogeneous Catalysts and Nanomaterials , 2004 .

[4]  S. J. Simpson,et al.  Synthesis and characterisation of [(η6-cymene)Ru(L)X2] compounds: single crystal X-ray structure of [(η6-cymene)Ru(P{OPh}3)Cl2] at 203 K , 2004 .

[5]  B. Manzano,et al.  Ruthenium Arene Derivatives with PN Hemilabile Ligands. P−C Cleavage and Phosphine to Phosphinite Transformation , 2004 .

[6]  A. Lledós,et al.  Unexpected Influence of the Counteranion in the κ2 vs κ3 Hapticity of Polydentate N-Donor Ligands in [RhI(N-ligand)L2]+ Complexes , 2004 .

[7]  J. Pons,et al.  Reactivity of the ligand bis[2-(3,5-dimethyl-1-pyrazolyl)ethyl]ether (L1) with Pd(II) and Pt(II): crystal structure of cis-[PtCl2(L1)] , 2004 .

[8]  J. Pons,et al.  Synthesis and characterisation of pyrazolic palladium compounds containing alcohol functionality: rotation around the Pd-N bond , 2004 .

[9]  J. Pons,et al.  Reactivity of [PdCl(μ-med)]2 with monodentate or bidentate ligands. Structure of the dinuclear complexes [Pd(μ-med)(PPh3)]2(BF4)2 and [Pd(μ-med)(bpy)]2(BF4)2. [Hmed = N-(2-mercaptoethyl)-3,5-dimethylpyrazole] , 2004 .

[10]  Pascale Crochet,et al.  Ruthenium(II) complexes containing 2-diphenylphosphinobenzaldehyde: synthesis and catalytic activity in transfer hydrogenation § , 2003 .

[11]  Ioannis D. Kostas Synthesis of new nitrogen-containing phosphinite and phosphine–phosphinite ligands. Application to rhodium-catalyzed hydroformylation of styrene , 2003 .

[12]  J. Pons,et al.  Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni(II), Pd(II) and Pt(II) complexes of didentate ligands with NS-donor set , 2003 .

[13]  J. Pons,et al.  Reaction of platinum(II) derivatives with 1-hydroxyalkyl-3,5-dimethylpyrazole ligands. Cleavage of the N(pz)C(sp3) bond. X-ray crystal structure of cis-[PtCl2(HL2)2] (HL2=1-(2-hydroxyethyl)-3,5-dimethylpyrazole) and trans-[PtCl2(dmpz)2] (dmpz=3,5-dimethylpyrazole) , 2003 .

[14]  J. Pons,et al.  Synthesis of New PdII Complexes Containing a Thioether‐Pyrazole Hemilabile Ligand − Structural Analysis by 1H, 13C NMR Spectroscopy and Crystal Structure of [PdCl(bdtp)]BF4 [bdtp = 1,5‐Bis(3,5‐dimethyl‐1‐pyrazolyl)‐3‐thiapentane] , 2003 .

[15]  J. Pons,et al.  Study of the bonding properties of the bis[2-(3,5-dimethyl-1-pyrazolyl)ethyl]ether toward Rh(I): an hemilabile ligand exhibiting κ3N, N, O meridional or facial coordination mode , 2003 .

[16]  J. Pons,et al.  Synthesis, Characterisation, and X‐ray Crystal Structure of New NiII, PdII, and PtII Complexes of Tridentate Pyrazole‐Based Ligands with an NOS‐Donor Set , 2003 .

[17]  J. Pons,et al.  New stable cyclopentadienyl iron(II) complexes containing 3,5-dimethylpyrazolyl phosphine: X-ray structure of [FeCp(CO)2PPh2(Me2Pz)]BF4 , 2003 .

[18]  B. R. Steele,et al.  A palladium complex with a new hemilabile amino- and sulfur-containing phosphinite ligand as an efficient catalyst for the Heck reaction of aryl bromides with styrene. The effect of the amino group , 2003 .

[19]  S. García‐Granda,et al.  Ruthenium(II) and ruthenium(IV) complexes containing kappa1-P-, kappa2-P,O-, and kappa3-P,N,O-iminophosphorane-phosphine ligands Ph2PCH2P[=NP(=O)(OR)2]Ph2 (R = Et, Ph): synthesis, reactivity, theoretical studies, and catalytic activity in transfer hydrogenation of cyclohexanone. , 2003, Inorganic chemistry.

[20]  J. Pons,et al.  Synthesis and characterisation of palladium compounds with new polyetherpyrazole ligands , 2003 .

[21]  J. Pons,et al.  Synthesis of Ru(II) complexes of the new 1-[(P-diphenyl)-2-phosphinoethyl]-3,5-dimethylpyrazole ligand and study of their reactivity toward terminal alkynes , 2003 .

[22]  J. Pons,et al.  Synthesis of New PdII Complexes Containing Thioether−Pyrazole Hemilabile Ligands − Structural Analysis by 1H and 13C NMR Spectroscopy and Crystal Structures of [PdCl2(bddo)] and [Pd(bddo)](BF4)2 [bddo = 1,8‐Bis(3,5‐dimethyl‐1‐pyrazolyl)‐3,6‐dithiaoctane] , 2002 .

[23]  J. Pons,et al.  Pyrazolic palladium compounds containing alcohol functionality: hindered rotation around PdN bond , 2002 .

[24]  J. Pons,et al.  Synthesis of a New Potentially Hemilabile Ligand: 1‐[2‐(Diphenylphosphanyl)ethyl]‐3,5‐dimethylpyrazole, and Comparison of Its Bonding Properties with the Related 1‐[2‐(Ethylamino)ethyl]‐3,5‐dimethylpyrazole Ligand toward RhI , 2002 .

[25]  U. Schubert,et al.  Transformations of organosilanes by Pt(II) complexes with hemilabile P,N-chelating ligands , 2002 .

[26]  J. Pons,et al.  Bis[(3,5‐dimethyl‐1‐pyrazolyl)methyl]ethylamine − A Versatile Ligand for Complexation in RhI Cationic Complexes , 2001 .

[27]  Ioannis D. Kostas Synthesis of new rhodium complexes with a hemilabile nitrogen-containing bis(phosphinite) or bis(phosphine) ligand. Application to hydroformylation of styrene , 2001 .

[28]  Fr'ed'eric Naud,et al.  Hemilability of Hybrid Ligands and the Coordination Chemistry of Oxazoline-Based Systems. , 2001, Angewandte Chemie.

[29]  J. Pons,et al.  Organometallic rhodium (I) complexes with 1-alkylaminopyrazole ligands , 2001 .

[30]  J. Pons,et al.  The formation of [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (Me2HPz=3, 5-dimethylpyrazole; R=H, Me and p-Tol) complexes from the cleavage of the P–N bond of a P-coordinated P(Me2Pz)Ph2 ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene)(Me2HPz)(PPh2OH)]Cl , 2000 .

[31]  K. K. Hii,et al.  SYNTHESES AND PROPERTIES OF PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN-PHOSPHORUS LIGANDS WITH A TUNABLE HEMILABILE SITE , 1999 .

[32]  J. Ros,et al.  Ruthenium(II) complexes containing both arene and functionalized phosphines. Synthesis and catalytic activity for the hydrogenation of styrene and phenylacetylene , 1998 .

[33]  P. Gendre,et al.  New optically active amido-phosphinite ligand and ruthenium complexes , 1998 .

[34]  Hong Yang,et al.  Ruthenium(II) Complexes Containing Optically Active Hemilabile P,N,O-Tridentate Ligands. Synthesis and Evaluation in Catalytic Asymmetric Transfer Hydrogenation of Acetophenone by Propan-2-ol , 1997 .

[35]  E. Lindner,et al.  DYNAMIC, REACTIVITY AND CATALYTIC BEHAVIOR OF PSEUDO-UNDERCOORDINATED RUTHENIUM AND RHODIUM COMPLEXES STABILIZED BY INTRAMOLECULAR SOLVENTS , 1996 .

[36]  Zhengxing Zhang,et al.  Chemistry of 2-(diphenylphosphino)pyridine , 1996 .

[37]  E. Lindner,et al.  Coordination chemistry and catalysis with hemilabile oxygen-phosphorus ligands , 1991 .

[38]  W. Haanstra,et al.  Unusual chelating properties of the ligand 1,8-bis(3,5-dimethyl-1-pyrazolyl)-3,6-dithiaoctane (bddo). Crystal structures of Ni(bddo)(NCS)2, Zn(bddo)(NCS)2 and Cd2(bddo)(NCS)4 , 1989 .

[39]  L. Prati,et al.  Synthesis and stereochemical studies of the chiral ruthenium complexes [Ru(?-C5H5){(S)dpompyr-PP?}X][dpompyr =N-diphenylphosphino-2-(diphenylphosphinoxymethyl)pyrrolidine, X = H or Cl]. Crystal structure of [(S)Ru(?-C5H5){(S)dpompyr-PP?}Cl] , 1987 .

[40]  T. Rauchfuss,et al.  Metal complexes of hemilabile ligands. Reactivity and structure of dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II) , 1980 .

[41]  M. A. Bennett,et al.  Divalent ruthenium complexes containing non-planar hexahapto-benzene , 1972 .

[42]  M. C. Baird,et al.  Reactions of benzene complexes of ruthernium(II) , 1972 .

[43]  F. S. Mathews,et al.  A semi-empirical method of absorption correction , 1968 .

[44]  G. H. Richter,et al.  FORMALDEHYDE CONDENSATION IN THE PYRAZOLE SERIES , 1950 .