Ion transport phenomena in polymeric electrolytes

The aim of the present work is to generalize an ion transport phenomena observed in composite polymeric electrolytes using the previously developed models as well as design a new approach which would be helpful in describing changes in conductivity and lithium ion transference numbers occurring upon addition of fillers to polymeric electrolytes. The concept is based on the observation of changes in ionic associations in the polymeric electrolytes studied in a wide salt concentration range. The idea is illustrated by the results coming from a variety of electrochemical and structural data obtained for composite electrolytes containing specially designed inorganic and organic fillers.

[1]  S. Greenbaum,et al.  Electrical, thermal and NMR investigation of composite solid electrolytes based on PEO, LiI and high surface area inorganic oxides , 1998 .

[2]  W. Wieczorek,et al.  Blend-based and composite polymer solid electrolytes , 1991 .

[3]  B. Scrosati,et al.  Anion-Binding Calixarene Receptors: Synthesis, Microstructure, and Effect on Properties of Polyether Electrolytes , 2005 .

[4]  B. Steele,et al.  Effects of inert fillers on the mechanical and electrochemical properties of lithium salt-poly(ethylene oxide) polymer electrolytes , 1982 .

[5]  P. Bruce,et al.  Steady state current flow in solid binary electrolyte cells , 1987 .

[6]  Bruno Scrosati,et al.  Applications of electroactive polymers , 1993 .

[7]  J. Płcharski,et al.  PEO based composite solid electrolyte containing nasicon , 1988 .

[8]  B. Scrosati,et al.  Properties and applications of lithium ion-conducting polymers , 1990 .

[9]  B. Scrosati,et al.  Properties of mixed polymer and crystalline ionic conductors , 1989 .

[10]  Joachim Maier,et al.  Second Phase Effects on the Conductivity of Non‐Aqueous Salt Solutions: “Soggy Sand Electrolytes” , 2004 .

[11]  D. Macfarlane,et al.  Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes , 2003 .

[12]  B. Scrosati,et al.  Ionic conductivity and 7Li NMR Study of Poly(ethylene glycol) complexed with lithium salts , 1992 .

[13]  B. Scrosati,et al.  Nanocomposite polymer electrolytes for lithium batteries , 1998, Nature.

[14]  E. Wachsman,et al.  Solid-State Ionic Devices , 2007 .

[15]  G. Nagasubramanian,et al.  Composite solid electrolyte for Li battery applications , 1993 .

[16]  Colin A. Vincent,et al.  An investigation of the conducting species in polymer electrolytes , 1986 .

[17]  Bruno Scrosati,et al.  Physical and chemical properties of nanocomposite polymer electrolytes , 1999 .

[18]  B. Scrosati,et al.  The lithium polymer electrolyte battery V. The roles of the composition and morphology of the positive electrode , 1990 .

[19]  Xiao‐Qing Yang,et al.  A Novel Lithium Battery Electrolyte Based on Lithium Fluoride and a Tris(pentafluorophenyl) Borane Anion Receptor in DME , 1999 .

[20]  B. Scrosati,et al.  Comparison of NMR and conductivity in (PEP)8LiClO4+γ-LiAlO2 , 1992 .

[21]  Bruno Scrosati,et al.  Composite Polymer Electrolytes , 1991 .

[22]  W. Wieczorek,et al.  Modifications of crystalline structure of peo polymer electrolytes with ceramic additives , 1989 .

[23]  K. West,et al.  Mixed phase solid electrolytes with nonconducting polymer binder , 1990 .

[24]  W. Wieczorek,et al.  Temperature dependence of conductivity of mixed-phase composite polymer solid electrolytes , 1992 .

[25]  H. Marczewska,et al.  Acidity of sulfated oxides: Al2O3, TiO2 and SiO2. Application of test reactions , 2004 .

[26]  J. R. Stevens,et al.  Poly(ethylene oxide)-alkali metal-silver halide salt systems with high ionic conductivity at room temperature , 1986 .

[27]  Bruno Scrosati,et al.  Novel Solid Polymer Electrolytes with Single Lithium-Ion Transport , 2004 .

[28]  B. Scrosati.  Electrode and electrolyte materials for polymer-based lithium batteries , 1989 .

[29]  Jingyu Xi,et al.  Nanocomposite polymer electrolyte based on Poly(ethylene oxide) and solid super acid for lithium polymer battery , 2004 .

[30]  James McBreen,et al.  The Synthesis of a New Family of Boron‐Based Anion Receptors and the Study of Their Effect on Ion Pair Dissociation and Conductivity of Lithium Salts in Nonaqueous Solutions , 1996 .

[31]  B. Scrosati,et al.  Advanced, lithium batteries based on high-performance composite polymer electrolytes , 2006 .

[32]  R. Sarma,et al.  Materials for Solid State Batteries , 1991 .

[33]  B. Scrosati,et al.  Effect of calixpyrrole in PEO–LiBF4 polymer electrolytes , 2005 .

[34]  W. Wieczorek,et al.  PEO-based polymer blends as materials for solid electrolytes , 1990 .

[35]  M. Marcinek,et al.  Effect of Filler Surface Group on Ionic Interactions in PEG−LiClO4−Al2O3 Composite Polyether Electrolytes , 2000 .

[36]  W. Wieczorek,et al.  Effective medium theory in studies of conductivity of composite polymeric electrolytes , 1995 .

[37]  S. Skaarup.  Mixed phase solid electrolytes , 1988 .

[38]  P. Bruce,et al.  Solid State Electrochemistry , 1997 .

[39]  M. Siekierski,et al.  Modeling of conductivity in composites with random resistor networks , 2005 .

[40]  Mixed solid electrolytes based on poly(ethylene oxide) , 1989 .

[41]  B. Scrosati,et al.  The lithium polymer electrolyte battery IV. Use of composite electrolytes , 1990 .

[42]  J. R. Stevens,et al.  Composite polyether based solid electrolytes , 1995 .

[43]  B. Scrosati,et al.  Electrochemical and spectroscopic study of the transport properties of composite polymer electrolytes , 1992 .

[44]  B. Scrosati,et al.  Superacid ZrO2-added, composite polymer electrolytes with improved transport properties , 2006 .

[45]  C. Liang.  Conduction Characteristics of the Lithium Iodide‐Aluminum Oxide Solid Electrolytes , 1973 .

[46]  A. Zalewska,et al.  Physico-and electrochemistry of composite electrolytes based on PEODME-LiTFSI with TiO2 , 2006 .