Green analytical chemistry: Social dimension and teaching

Green Analytical Chemistry (GAC) is the idea which every analytical chemist should be familiar of. Due to continuous improvement in the subject both from the aspects of theory and experimentation, the dynamic way analytical chemistry studies are evolving in the frame of chemistry degrees should not be surprising. Recently, many efforts have been made in order to include Green Chemistry principles to Education, also in the field of analytical chemistry, where twelve GAC principles play a main role. The understanding and awareness of these principles and other evolving related concepts requires special teaching of GAC as a part of curriculum at undergraduate and graduate levels. This article is focused on the main concepts and challenges of teaching GAC and also presents the current accomplishment in this field. In addition, teaching social responsibility in GAC is discussed. Several case studies are also presented as an example for the learners.

[1]  H. Zaazaa,et al.  Just-Dip-It (Potentiometric Ion-Selective Electrode): An Innovative Way of Greening Analytical Chemistry , 2016 .

[2]  John Andraos,et al.  Green chemistry teaching in higher education: a review of effective practices , 2012 .

[3]  Farid Chemat,et al.  Green Extraction of Natural Products: Concept and Principles , 2012, International journal of molecular sciences.

[4]  S. Shinn,et al.  How to recognize success and failure: practical assessment of an evolving, first-semester laboratory program using simple, outcome-based tools , 2013 .

[5]  Miguel de la Guardia,et al.  Challenges in Green Analytical Chemistry , 2020, Green Chemistry Series.

[6]  Patricia R. Todd CORPORATE SOCIAL RESPONSIBILITY AND GLOBAL STANDARDIZATION: SUSTAINABLE ENVIRONMENTAL MANAGEMENT IN THE CHEMICAL INDUSTRY , 2009 .

[7]  F. Pena-Pereira,et al.  A Solvent Microextraction Approach for Environmental Analysis: Colorimetric Assay for Phosphorus Determination in Natural Waters , 2014 .

[8]  M. de la Guardia,et al.  Handbook of green analytical chemistry , 2012 .

[9]  Siglinda Perathoner,et al.  From Green to Sustainable Industrial Chemistry , 2009 .

[10]  Laura B. Zimmerman,et al.  Analysis of Whiskey by Dispersive Liquid–Liquid Microextraction Coupled with Gas Chromatography/Mass Spectrometry: An Upper Division Analytical Chemistry Experiment Guided by Green Chemistry , 2016 .

[11]  J. Namieśnik,et al.  Solid Phase Microextraction: Apparatus, Sorbent Materials, and Application , 2019, Critical reviews in analytical chemistry.

[12]  H. Buckley,et al.  Fitting It All In: Adapting a Green Chemistry Extraction Experiment for Inclusion in an Undergraduate Analytical Laboratory , 2013 .

[13]  Franz Rauch,et al.  Education for Sustainable Development (ESD) and chemistry education , 2012 .

[14]  Arabinda Das,et al.  Green Analytical Laboratory Experiments , 2012 .

[15]  Miguel de la Guardia,et al.  An integrated approach of analytical chemistry , 1999 .

[16]  M Valcárcel,et al.  Teaching social responsibility in analytical chemistry. , 2013, Analytical chemistry.

[17]  A. Cavicchioli,et al.  Green analytical chemistry in undergraduate labs: flow-injection determination of creatinine in urine with photochemical treatment of waste , 2004 .

[18]  S. Garrigues,et al.  Green strategies for decontamination of analytical wastes , 2010 .

[19]  M. Tobiszewski,et al.  Green Chemistry in Higher Education: State of the Art, Challenges, and Future Trends. , 2018, ChemSusChem.

[20]  L. H. Keith,et al.  Green analytical methodologies. , 2007, Chemical reviews.

[21]  Inamuddin,et al.  Green Chromatographic Techniques: Separation and Purification of Organic and Inorganic Analytes , 2014 .

[22]  S. Garrigues,et al.  Education in Green Analytical Chemistry , 2012 .

[23]  P. Bühlmann,et al.  Minimizing Hazardous Waste in the Undergraduate Analytical Laboratory: A Microcell for Electrochemistry , 2010 .

[24]  Jean Mane,et al.  GREEN MOTION: a new and easy to use green chemistry metric from laboratories to industry , 2015 .

[25]  Y. Yamini,et al.  Supramolecular solvent-based hollow fiber liquid phase microextraction of benzodiazepines. , 2013, Analytica chimica acta.

[26]  David J. C. Constable,et al.  Metrics to ‘green’ chemistry—which are the best? , 2002 .

[27]  M. Guardia,et al.  Guest editorial. Towards environmentally conscientious analytical chemistry through miniaturization, containment and reagent replacement , 1995 .

[28]  Juan C. Garibay,et al.  STEM students’ social agency and views on working for social change: Are STEM disciplines developing socially and civically responsible students? , 2015 .

[29]  M. A. Ragab,et al.  Green chemistry: Analytical and chromatography , 2017 .

[30]  M. Sajid,et al.  Ultrasound-assisted solvent extraction of porous membrane packed solid samples: A new approach for extraction of target analytes from solid samples , 2019, Microchemical Journal.

[31]  Miguel Valcárcel,et al.  Social responsibility in analytical chemistry , 2012 .

[32]  João G. Crespo,et al.  Green Separation Processes: Fundamentals and Applications , 2005 .

[33]  A. S. Boparai,et al.  Waste minimization in analytical methods , 1995 .

[34]  Liz U. Gron Green Analytical Chemistry: Application and Education , 2009 .

[35]  A. Baranger,et al.  Extraction and Antibacterial Properties of Thyme Leaf Extracts: Authentic Practice of Green Chemistry , 2016 .

[36]  M. T. Fernández-Abedul,et al.  Bioelectroanalysis in a Drop: Construction of a Glucose Biosensor , 2017 .

[37]  E. Woodhouse,et al.  Green Chemistry as Social Movement? , 2005 .

[38]  Marek Tobiszewski,et al.  Green analytical chemistry--theory and practice. , 2010, Chemical Society reviews.

[39]  M. Guardia,et al.  Determination of Mercury in Milk by Cold Vapor Atomic Fluorescence: A Green Analytical Chemistry Laboratory Experiment , 2011 .

[40]  M. de la Guardia,et al.  Green Spectroscopy: A Scientometric Picture , 2009 .

[41]  Yihua He,et al.  Spectroscopy: The Best Way Toward Green Analytical Chemistry? , 2007 .

[42]  M. Hartings,et al.  Communicating chemistry for public engagement. , 2011, Nature chemistry.

[43]  Z. Es’haghi,et al.  Synthesis and application of a novel solid-phase microextraction adsorbent: hollow fiber supported carbon nanotube reinforced sol-gel for determination of phenobarbital. , 2011, Analytica chimica acta.

[44]  F. Chemat,et al.  “In situ” extraction of essential oils by use of Dean–Stark glassware and a Vigreux column inside a microwave oven: a procedure for teaching green analytical chemistry , 2012, Analytical and Bioanalytical Chemistry.

[45]  S. Hartwell,et al.  Exploring the potential for using inexpensive natural reagents extracted from plants to teach chemical analysis , 2012 .

[46]  Fabrizio Passarini,et al.  Life cycle inventory improvement in the pharmaceutical sector: assessment of the sustainability combining PMI and LCA tools , 2015 .

[47]  Jacek Namieśnik,et al.  The 12 principles of green analytical chemistry and the SIGNIFICANCE mnemonic of green analytical practices , 2013 .

[48]  M. Tobiszewski Metrics for green analytical chemistry , 2016 .

[49]  Joseph Wang,et al.  Real-time electrochemical monitoring: toward green analytical chemistry. , 2002, Accounts of chemical research.

[50]  M. Guardia,et al.  Origins of Green Analytical Chemistry , 2011 .

[51]  N. Simcox,et al.  Social and Environmental Justice in the Chemistry Classroom , 2017 .

[52]  Flemming Besenbacher,et al.  Scientific social responsibility: a call to arms. , 2011, Angewandte Chemie.

[53]  Jacek Namieśnik,et al.  Analytical eco-scale for assessing the greenness of analytical procedures , 2012 .

[54]  J. Namieśnik Green analytical chemistry – Some remarks , 2001 .

[55]  J. Płotka-Wasylka,et al.  A new tool for the evaluation of the analytical procedure: Green Analytical Procedure Index. , 2018, Talanta.