Ionic nanoparticle networks: development and perspectives in the landscape of ionic liquid based materials.

This feature article gives an overview of the research performed on ionic nanoparticle networks (INNs). These INNs are hybrid materials consisting of inorganic nanoparticles and ionic linkers, such as imidazolium, bisimidazolium or pyridinium. The synthesis and properties of INNs, for catalysis or sensorics, are presented. At each step INN materials are compared to other hybrid materials of similar composition such as ionogels or suspensions of imidazolium modified nanoparticles.

[1]  D. Guillon,et al.  Ionic liquid crystals bearing bipyridinium and pentaphenylene groups , 2010 .

[2]  Daxiang Cui,et al.  Dual Phase‐Controlled Synthesis of Uniform Lanthanide‐Doped NaGdF4 Upconversion Nanocrystals Via an OA/Ionic Liquid Two‐Phase System for In Vivo Dual‐Modality Imaging , 2011 .

[3]  L. Stievano,et al.  DFT study of the adsorption of microsolvated glycine on a hydrophilic amorphous silica surface. , 2008, Physical chemistry chemical physics : PCCP.

[4]  J. Akbarzadeh,et al.  Tailoring photoluminescence properties in ionic nanoparticle networks. , 2014, Chemistry.

[5]  P. Hesemann,et al.  i-Silica: Nanostructured silica hybrid materials containing imidazolium groups by hydrolysis-polycondensation of disilylated bis-N,N′-alkyl-imidazolium halides , 2011 .

[6]  A. Eychmüller,et al.  CdTe nanocrystals capped with a tetrazolyl analogue of thioglycolic acid: aqueous synthesis, characterization, and metal-assisted assembly. , 2010, ACS nano.

[7]  I. Gascón,et al.  Influence of the liquid crystal behaviour on the Langmuir and Langmuir-Blodgett film supramolecular architecture of an ionic liquid crystal. , 2012, Journal of colloid and interface science.

[8]  Francesco Mauri,et al.  Ab Initio Study of the Hydroxylated Surface of Amorphous Silica: A Representative Model , 2008 .

[9]  J. Le Bideau,et al.  Lanthanide-doped luminescent ionogels. , 2009, Dalton transactions.

[10]  A. Eychmüller,et al.  Quantum-Dot-Based (Aero)gels: Control of the Optical Properties. , 2012, The journal of physical chemistry letters.

[11]  G. Kickelbick,et al.  Effect of interparticle interactions on size determination of zirconia and silica based systems – A comparison of SAXS, DLS, BET, XRD and TEM , 2012, Chemical physics letters.

[12]  D. Diamond,et al.  Magnetic Ionogels (MagIGs) Based on Iron Oxide Nanoparticles, Poly(N‐isopropylacrylamide), and the Ionic Liquid Trihexyl(tetradecyl)phosphonium Dicyanamide , 2012 .

[13]  F. Mauri,et al.  Investigation of the interface in silica-encapsulated liposomes by combining solid state NMR and first principles calculations. , 2011, Journal of the American Chemical Society.

[14]  Andrew G. Glen,et al.  APPL , 2001 .

[15]  A. Taubert,et al.  Imidazolium-based liquid crystals: a modular platform for versatile new materials with finely tuneable properties and behaviour , 2011 .

[16]  E. Hagaman,et al.  Synthesis and characterization of periodic mesoporous organosilicas as anion exchange resins for perrhenate adsorption. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[17]  K. Hata,et al.  Colloidal interaction in ionic liquids: effects of ionic structures and surface chemistry on rheology of silica colloidal dispersions. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[18]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[19]  D. Costa,et al.  Characterization of supported vanadium oxide species on silica: a periodic DFT investigation , 2009 .

[20]  Jiajian Peng,et al.  Ionic liquid functionalized silica gel : novel catalyst and fixed solvent , 2006 .

[21]  E. Bertagnolli,et al.  Layer-by-layer assembly of titania nanoparticles based ionic networks. , 2011, Chemical communications.

[22]  K. Ho,et al.  Binary room-temperature ionic liquids based electrolytes solidified with SiO2 nanoparticles for dye-sensitized solar cells , 2009 .

[23]  K. Driesen,et al.  Luminescent Ionogels Based on Europium-Doped Ionic Liquids Confined within Silica-Derived Networks , 2006 .

[24]  Kerem Cagatay Icli,et al.  Photovoltaic performance of bifacial dye sensitized solar cell using chemically healed binary ionic liquid electrolyte solidified with SiO2 nanoparticles , 2013 .

[25]  Arne Thomas,et al.  Ionic Nanoparticle Networks as Solid State Catalysts , 2012 .

[26]  Marco Litschauer,et al.  Confinement of 1-butyl-3-methylimidazolium nitrate in metallic silver. , 2008, The journal of physical chemistry. B.

[27]  Marco Litschauer,et al.  Photoluminescence as Complementary Evidence for Short-Range Order in Ionic Silica Nanoparticle Networks , 2010, The journal of physical chemistry. C, Nanomaterials and interfaces.

[28]  Lydie Viau,et al.  Ionogels, ionic liquid based hybrid materials. , 2011, Chemical Society reviews.

[29]  T. Welton,et al.  Competitive pi interactions and hydrogen bonding within imidazolium ionic liquids. , 2014, Physical chemistry chemical physics : PCCP.

[30]  M. Antonietti,et al.  Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures. , 2004, Angewandte Chemie.

[31]  H. Peterlik,et al.  Porous titania ionic nanoparticle networks. , 2011, Langmuir.

[32]  J. Moreau,et al.  New mixed organic-inorganic polymers: hydrolysis and polycondensation of bis(trimethoxysilyl)organometallic precursors , 1992 .

[33]  J. Eckert,et al.  Multimetallic Aerogels by Template-Free Self-Assembly of Au, Ag, Pt, and Pd Nanoparticles , 2014 .

[34]  Kevin Barraclough,et al.  I and i , 2001, BMJ : British Medical Journal.

[35]  M. Hasegawa,et al.  Full-color tunable photoluminescent ionic liquid crystals based on tripodal pyridinium, pyrimidinium, and quinolinium salts. , 2012, Journal of the American Chemical Society.

[36]  A. Mudring,et al.  Lanthanide containing ionic liquid crystals: EuBr2, SmBr3, TbBr3 and DyBr3 in C12mimBr , 2010 .

[37]  J. Morrey,et al.  Thermochromism in copper(II) chlorides. Coordination geometry changes in tetrachlorocuprate(2-)anions , 1974 .

[38]  Long Zhang,et al.  Magnetic nanoparticle supported ionic liquid catalysts for CO2cycloaddition reactions , 2009 .

[39]  J. M. de la Fuente,et al.  Ionic liquid mediated synthesis and surface modification of multifunctional mesoporous Eu:GdF3 nanoparticles for biomedical applications. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[40]  Marco Litschauer,et al.  Nanoparticles connected through an ionic liquid-like network , 2008 .

[41]  Markus Antonietti,et al.  Room-temperature ionic liquids as template to monolithic mesoporous silica with wormlike pores via a sol-gel nanocasting technique , 2004 .

[42]  Usman Ali Rana,et al.  Toward protic ionic liquid and organic ionic plastic crystal electrolytes for fuel cells , 2012 .

[43]  A. Mudring,et al.  Switchable Green and White Luminescence in Terbium‐Based Ionic Liquid Crystals , 2011 .

[44]  C. Belin,et al.  Fluorescence Amplification in Self-Assembled Organic Nanoparticles by Excitation Energy Migration and Transfer , 2010 .

[45]  A. Ouadi,et al.  Comparison of uranyl extraction mechanisms in an ionic liquid by use of malonamide or malonamide-functionalized ionic liquid. , 2012, Dalton transactions.

[46]  G. Wallace,et al.  Ion effects in REDOX cycling of conducting polymer based electrochromic materials , 2010 .

[47]  J. Akbarzadeh,et al.  Irreversible thermochromism in copper chloride Imidazolium Nanoparticle Networks. , 2013, Physical chemistry chemical physics : PCCP.

[48]  Haoshen Zhou,et al.  Preparation of Nanohybrid Solid-State Electrolytes with Liquidlike Mobilities by Solidifying Ionic Liquids with Silica Particles , 2007 .

[49]  J. Fraser Stoddart,et al.  π–π INTERACTIONS IN SELF‐ASSEMBLY , 1997 .

[50]  T. Lodge,et al.  Morphology, Modulus, and Conductivity of a Triblock Terpolymer/Ionic Liquid Electrolyte Membrane , 2014 .

[51]  Marie-Alexandra Néouze About the interactions between nanoparticles and imidazolium moieties: emergence of original hybrid materials , 2010 .

[52]  Bruno Scrosati,et al.  Ionic-liquid materials for the electrochemical challenges of the future. , 2009, Nature materials.

[53]  M. Toprak,et al.  Microwave assisted synthesis of ZnS quantum dots using ionic liquids , 2012 .

[54]  Marie-Alexandra Néouze Nanoparticle assemblies: main synthesis pathways and brief overview on some important applications , 2013, Journal of Materials Science.

[55]  Y. Iwasawa,et al.  Immobilized metal ion-containing ionic liquids: preparation, structure and catalytic performance in Kharasch addition reaction. , 2005, Chemical communications.

[56]  W. Marsden I and J , 2012 .

[57]  Edward F. Valeev,et al.  Estimates of the Ab Initio Limit for π−π Interactions: The Benzene Dimer , 2002 .

[58]  D. Costa,et al.  The amorphous silica–liquid water interface studied by ab initio molecular dynamics (AIMD): local organization in global disorder , 2014, Journal of physics. Condensed matter : an Institute of Physics journal.

[59]  T. Lodge,et al.  High-modulus, high-conductivity nanostructured polymer electrolyte membranes via polymerization-induced phase separation. , 2014, Nano letters.

[60]  H. Peterlik,et al.  Anion metathesis in ionic silica nanoparticle networks , 2010 .

[61]  B. Han,et al.  CO(2) cycloaddition reactions catalyzed by an ionic liquid grafted onto a highly cross-linked polymer matrix. , 2007, Angewandte Chemie.

[62]  Florence Babonneau,et al.  A Molecular Picture of the Adsorption of Glycine in Mesoporous Silica through NMR Experiments Combined with DFT-D Calculations , 2013 .

[63]  A. Taubert,et al.  Surprisingly high, bulk liquid-like mobility of silica-confined ionic liquids. , 2009, Physical chemistry chemical physics : PCCP.

[64]  Peter Wasserscheid,et al.  Ionic Liquids in Synthesis , 2002 .

[65]  J. Moreau,et al.  Design of porous silica from hybrid organic–inorganic precursors , 1998 .

[66]  H. Luo,et al.  Synthesis and characterization of organic-inorganic hybrid mesoporous silica materials with new templates. , 2004, Chemical communications.

[67]  G. Strasser,et al.  Analyzing Imidazolium Bridging in Nanoparticle Networks Covalently Linked to Silicon Substrates , 2012 .

[68]  Kun Dong,et al.  Insights into quaternary ammonium salts-catalyzed fixation carbon dioxide with epoxides , 2012 .

[69]  D. Guillon,et al.  From tectons to luminescent supramolecular ionic liquid crystals. , 2011, Chemical communications.

[70]  Arne Thomas,et al.  Imidazolium functionalized SBA-15 type silica: efficient organocatalysts for Henry and cycloaddition reactions , 2013 .

[71]  A. Taubert,et al.  Inorganic materials from ionic liquids. , 2007, Dalton transactions.

[72]  T. Ying,et al.  Template-free solution approach to synthesize CdS dendrites with SCN based ionic liquid , 2011 .

[73]  U. Schubert,et al.  Retro-crosslinking of cluster-based hybrid polymers , 2008 .

[74]  R. Dey,et al.  Synthesis, crystal structure and thermochromism of benzimidazolium tetrachlorocuprate: (C7H7N2)2[CuCl4] , 2002 .