Stability and Instability in Disperse Systems

Abstract The balance of the forces of interaction between colloidal particles determines, in general, whether a colloidal dispersion remains stable or undergoes coagulation or flocculation. A review of interaction forces is given and it is then shown how such forces can be measured experimentally using either macroscopic systems or particulate dispersions. Particular attention is given to the repulsive forces which arise from electrostatic charges and/or adsorbed layers. From an understanding of these forces some rationalization can be made of the many phenomena which constitute colloid and interface science.

[1]  E. Matijević,et al.  Aluminum hydrous oxide solsISpherical particles of narrow size distribution , 1973 .

[2]  J. D. Bernal,et al.  X-RAY AND CRYSTALLOGRAPHIC STUDIES OF PLANT VIRUS PREPARATIONS : I. INTRODUCTION AND PREPARATION OF SPECIMENS II. MODES OF AGGREGATION OF THE VIRUS PARTICLES. , 1941 .

[3]  K. E. J. Barrett,et al.  Dispersion polymerization in organic media , 1974 .

[4]  H. Olphen An Introduction to Clay Colloid Chemistry , 1977 .

[5]  Irving Langmuir,et al.  The Role of Attractive and Repulsive Forces in the Formation of Tactoids, Thixotropic Gels, Protein Crystals and Coacervates , 1938 .

[6]  P. Pusey The dynamics of interacting Brownian particles , 1975 .

[7]  J. Overbeek,et al.  Stability and electrophoretic deposition of suspensions in non-aqueous media , 1954 .

[8]  N. Fuchs Über die Stabilität und Aufladung der Aerosole , 1934 .

[9]  E. L. Mackor,et al.  The statistics of the adsorption of rod-shaped molecules in connection with the stability of certain colloidal dispersions , 1952 .

[10]  R. Ottewill,et al.  The influence of non-ionic surface active agents on the stability of polystyrene latex dispersions , 1968 .

[11]  D. Tabor,et al.  Van der Waals Forces: Theory and Experiment , 1973 .

[12]  Pranab Bagchi On the assumption of a step function for the adsorption-layer thickness in the nonionic stabilization of dispersions , 1975 .

[13]  W. Ostwald ELECTROLYTE COAGULATION AND COEFFICIENT OF ELECTROLYTE ACTIVITY1 , 1937 .

[14]  J. Overbeek,et al.  The rate of coagulation as a measure of the stability of silver iodide sols , 1954 .

[15]  L. Spielman Viscous interactions in Brownian coagulation , 1970 .

[16]  R. Ottewill,et al.  Studies on the preparation and properties of latices in nonpolar media , 1976 .

[17]  T. L. Pugh,et al.  ``Steric Protection'' of Hydrophobic Colloidal Particles by Adsorption of Flexible Macromolecules , 1954 .

[18]  K. Furusawa,et al.  Colloid chemical studies of polystyrene latices polymerized without any surfaceactive agents , 1970 .

[19]  P. Wiersema,et al.  Effect of hydrodynamic interaction on the coagulation rate of hydrophobic colloids , 1971 .

[20]  I. Snook,et al.  Microscopic approach to colloid stability , 1975 .

[21]  C. Radke,et al.  Thermodynamics of the effects of adsorption on interparticle forces , 1973 .

[22]  E. Matijević,et al.  Ferric hydrous oxide sols I. Monodispersed basic iron(III) sulfate particles , 1975 .

[23]  G. J. Fleer,et al.  Polymer adsorption and its effect on the stability of hydrophobic colloids , 1972 .

[24]  R. Ottewill Colloid Chemistry — today and tomorrow , 1976 .

[25]  Yoko Kobayashi,et al.  Phase separation in monodisperse latexes , 1973 .

[26]  J. Overbeek,et al.  Theory of the stabilization of dispersions by adsorbed macromolecules. II. Interaction between two flat particles , 1971 .

[27]  William J. Pangonis,et al.  Light Scattering of Spherical Colloidal Particles , 1954 .

[28]  E. Matijević,et al.  Precipitation and characterization of colloidal copper hydrous oxide sols , 1973 .

[29]  Pranab Bagchi Theory of stabilization of spherical colloidal particles by nonionic polymers , 1974 .

[30]  W. Hardy A preliminary investigation of the conditions which determine the stability of irreversible hydrosols , 1900, Proceedings of the Royal Society of London.

[31]  A. Doroszkowski,et al.  A viscometric technique for determining the layer thickness of polymer adsorbed on titanium dioxide , 1968 .

[32]  F. Eirich The Conformational States of Macromolecules Adsorbed at Solid–Liquid Interfaces , 1977 .

[33]  R. S. Bradley,et al.  LXXIX. The cohesive force between solid surfaces and the surface energy of solids , 1932 .

[34]  S. Linder,et al.  LVII.—Solution and pseudo-solution. Part III. The electrical convection of certain dissolved substances , 1897 .

[35]  E. Matijević The Role of Chemical Complexing in the Formation and Stability of Colloidal Dispersions , 1977 .

[36]  Herbert Freundlich,et al.  Colloid and capillary chemistry , 1922 .

[37]  J. Overbeek,et al.  Recent developments in the understanding of colloid stability , 1977 .

[38]  V. K. Mer Filtration of colloidal dispersions flocculated by anionic and cationic polyelectrolytes , 1966 .

[39]  R. Ottewill,et al.  Influence of particle size on the stability of polystyrene latices with an adsorbed layer of nonionic surface active agent , 1974 .

[40]  H. Schulze Schwefelarsen in wässriger Lösung , 1882 .

[41]  J. C. Brown,et al.  Light scattering study of dynamic and time-averaged correlations in dispersions of charged particles , 1975 .

[42]  J. D. Bernal,et al.  X-RAY AND CRYSTALLOGRAPHIC STUDIES OF PLANT VIRUS PREPARATIONS. III , 1941, The Journal of general physiology.

[43]  D. Tabor,et al.  The extrusion of liquids between highly elastic solids , 1971, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[44]  R. Ottewill,et al.  Measurement of forces between colloidal particles , 1970 .

[45]  E. W. Fischer Elektronenmikroskopische Untersuchungen zur Stabilität von Suspensionen in makromolekularen Lösungen , 1958 .

[46]  E. Verwey,et al.  Theory of the stability of lyophobic colloids. , 1955, The Journal of physical and colloid chemistry.

[47]  H. Schulze Antimontrisulfid in wässeriger Lösung , 1883 .

[48]  W. Luck,et al.  Über Bragg‐Reflexe mit sichtbarem Licht an monodispersen Kunststofflatices. I , 1963 .

[49]  D. J. Walbridge,et al.  Measurement of steric stabilizer barrier thickness in dispersions of poly(methyl methacrylate) in aliphatic hydrocarbon , 1971 .

[50]  F. Hesselink Theory of the stabilization of dispersions by adsorbed macromolecules. I. Statistics of the change of some configurational properties of adsorbed macromolecules on the approach of an impenetrable interface , 1971 .

[51]  Thomas Graham,et al.  X. Liquid diffusion applied to analysis , 1861, Philosophical Transactions of the Royal Society of London.

[52]  S. Edwards,et al.  Theory of the stabilization of colloids by adsorbed polymer , 1974, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[53]  M. E. Jones,et al.  Characterization and stability of chromium hydroxide sols of narrow size distributions , 1971 .

[54]  R. Ottewill,et al.  An Ellipsometric Study of the Adsorption of Gelatin on Silver Bromide , 1974 .

[55]  R. Zsigmondy Die hochrothe Goldlösung als Reagens auf Colloide , 1901 .

[56]  P. Flory Thermodynamics of High Polymer Solutions , 1941 .

[57]  R. Ottewill,et al.  Interparticle forces in montmorillonite gels , 1974 .

[58]  I. Krieger,et al.  Diffraction of light by ordered suspensions , 1969 .

[59]  R. Ottewill,et al.  Stability of monodisperse polystyrene latex dispersions of various sizes , 1966 .

[60]  H. C. Hamaker The London—van der Waals attraction between spherical particles , 1937 .

[61]  J. Kitchener Principles of action of polymeric flocculants , 1972 .

[62]  F. London,et al.  Zur Theorie und Systematik der Molekularkräfte , 1930 .

[63]  R. Ottewill,et al.  The measurement of forces between particles in disperse systems , 1972 .

[64]  J. Boer The influence of van der Waals' forces and primary bonds on binding energy, strength and orientation, with special reference to some artificial resins , 1936 .

[65]  E. L. Mackor A theoretical approach of the colloid-chemical stability of dispersions in hydrocarbons , 1951 .

[66]  S. Linder,et al.  XI.—Solution and pseudo-solution. Part I , 1892 .

[67]  J. W. Goodwin,et al.  Studies on the preparation and characterisation of monodisperse polystyrene laticee , 1974 .

[68]  Pranab Bagchi Nonionic denting and mixing potentials between two flat plates , 1974 .