Organic compounds on comet 67P/Churyumov-Gerasimenko revealed by COSAC mass spectrometry

Comets harbor the most pristine material in our solar system in the form of ice, dust, silicates, and refractory organic material with some interstellar heritage. The evolved gas analyzer Cometary Sampling and Composition (COSAC) experiment aboard Rosetta’s Philae lander was designed for in situ analysis of organic molecules on comet 67P/Churyumov-Gerasimenko. Twenty-five minutes after Philae’s initial comet touchdown, the COSAC mass spectrometer took a spectrum in sniffing mode, which displayed a suite of 16 organic compounds, including many nitrogen-bearing species but no sulfur-bearing species, and four compounds—methyl isocyanate, acetone, propionaldehyde, and acetamide—that had not previously been reported in comets.

[1]  M. E. Rudd,et al.  New model for electron-impact ionization cross sections of molecules , 1996 .

[2]  J. Oró,et al.  Comets and the formation of biochemical compounds on the primitive Earth – A review , 1991, Origins of life and evolution of the biosphere.

[3]  Cyril Szopa,et al.  Cosac, The Cometary Sampling and Composition Experiment on Philae , 2007 .

[4]  E. Jones,et al.  TOTAL CROSS SECTIONS FOR IONIZATION BY ELECTRON IMPACT , 1966 .

[5]  L. Orgel,et al.  Prebiotic chemistry and the origin of the RNA world. , 2004, Critical reviews in biochemistry and molecular biology.

[6]  S. Tegler,et al.  Nitrogen abundance in comet Halley , 1991 .

[7]  W. Irvine Extraterrestrial Organic Matter: A review , 1998, Origins of life and evolution of the biosphere.

[8]  David T. Young,et al.  Ion densities and composition of Titan's upper atmosphere derived from the Cassini Ion Neutral Mass Spectrometer: Analysis methods and comparison of measured ion densities to photochemical model simulations , 2012 .

[9]  Mark S. Gordon,et al.  General atomic and molecular electronic structure system , 1993, J. Comput. Chem..

[10]  M. DiSanti,et al.  Reservoirs for Comets: Compositional Differences Based on Infrared Observations , 2008 .

[11]  E. Kührt,et al.  Time variability and heterogeneity in the coma of 67P/Churyumov-Gerasimenko , 2015, Science.

[12]  W. Ip,et al.  Cassini Ion and Neutral Mass Spectrometer: Enceladus Plume Composition and Structure , 2006, Science.

[13]  Bruce Block,et al.  Ion Neutral Mass Spectrometer Results from the First Flyby of Titan , 2005, Science.

[14]  J. Sutherland,et al.  Prebiotic synthesis of simple sugars by photoredox systems chemistry. , 2012, Nature chemistry.

[15]  F. Scholten,et al.  The landing(s) of Philae and inferences about comet surface mechanical properties , 2015, Science.

[16]  C. Crestini,et al.  Formamide Chemistry and the Origin of Informational Polymers , 2007, Chemistry & biodiversity.

[17]  D. Lis,et al.  The Chemical Diversity of Comets: Synergies Between Space Exploration and Ground-based Radio Observations , 2009, 0901.2205.

[18]  J. Oró,et al.  Comets and the Formation of Biochemical Compounds on the Primitive Earth , 1961, Nature.

[19]  Rudd,et al.  Binary-encounter-dipole model for electron-impact ionization. , 1994, Physical review. A, Atomic, molecular, and optical physics.

[20]  D. J. Andrews,et al.  CHO-bearing organic compounds at the surface of 67P/Churyumov-Gerasimenko revealed by Ptolemy , 2015, Science.

[21]  Steven B. Charnley,et al.  The Chemical Composition of Comets—Emerging Taxonomies and Natal Heritage , 2011 .

[22]  Robert C. Wolpert,et al.  A Review of the , 1985 .

[23]  J. Greenberg Making a comet nucleus , 1998 .

[24]  J. Cernicharo,et al.  INVESTIGATION OF HNCO ISOMER FORMATION IN ICE MANTLES BY UV AND THERMAL PROCESSING: AN EXPERIMENTAL APPROACH , 2014, 1407.1242.

[25]  R. Kaiser,et al.  ON THE FORMATION OF AMINES (RNH2) AND THE CYANIDE ANION (CN−) IN ELECTRON-IRRADIATED AMMONIA–HYDROCARBON INTERSTELLAR MODEL ICES , 2011 .

[26]  U. Fink,et al.  The organic-rich surface of comet 67P/Churyumov-Gerasimenko as seen by VIRTIS/Rosetta , 2015, Science.

[27]  U. Meierhenrich,et al.  Competence evaluation of COSAC flight spare model mass spectrometer: In preparation of arrival of Philae lander on comet 67P/Churyumov–Gerasimenko , 2015 .

[28]  J. Bredehöft,et al.  Interpretation of COSAC mass spectrometer data acquired during Rosetta's Lutetia fly-by 10 July 2010 , 2012 .