Quick and low cost synthesis of sulphur doped carbon dots by simple acidic carbonization of sucrose for the detection of Fe3+ ions in highly acidic environment

Abstract An easy, facile, low cost and quick synthesis of sulphur doped carbon dots (S-C-dots) was carried out by acidic carbonization of sucrose (carbohydrate) without using any sophisticated instrument. The resultant S-C-dots shows excellent photoluminescent behaviour in highly acidic media with a quantum yield of 5.77%. Moreover, the as synthesized S-C-dots can be used as a dual probe for selective detection of Fe3+ ions in highly acidic conditions by Fluorescence as well as UV–vis spectroscopy. Also, the residual waste generated during the synthesis of S-C-dots can be used as an activated carbon (AC) for the application in dye adsorption from aqueous solutions.

[1]  Farid Nasir Ani,et al.  The development supercapacitor from activated carbon by electroless plating—A review , 2015 .

[2]  B. Girgis,et al.  Impact of surface characteristics of activated carbon on adsorption of BTEX , 2003 .

[3]  Yongming Guo,et al.  Fluorescent carbon nanoparticles for the fluorescent detection of metal ions. , 2015, Biosensors & bioelectronics.

[4]  Xueming Zhang,et al.  Simple Approach to Synthesize Amino-Functionalized Carbon Dots by Carbonization of Chitosan , 2016, Scientific Reports.

[5]  R. Singhal,et al.  Preparation of multicolor emitting carbon dots for HeLa cell imaging , 2014 .

[6]  Xingyuan Liu,et al.  Ratiometric fluorescent nanosensor based on water soluble carbon nanodots with multiple sensing capacities. , 2013, Nanoscale.

[7]  Mira Park,et al.  One-step synthesis of robust nitrogen-doped carbon dots: acid-evoked fluorescence enhancement and their application in Fe3+ detection , 2015 .

[8]  T.A. Kurniawan,et al.  Cr(VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan. , 2004, Chemosphere.

[9]  Haijuan Li,et al.  Ionic liquid-functionalized fluorescent carbon nanodots and their applications in electrocatalysis, biosensing, and cell imaging. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[10]  Zhiqiang Gao,et al.  Carbon quantum dots and their applications. , 2015, Chemical Society reviews.

[11]  H. Zeng,et al.  Carbon and Graphene Quantum Dots for Optoelectronic and Energy Devices: A Review , 2015 .

[12]  Ping Liu,et al.  An ionic liquid promoted microwave-hydrothermal route towards highly photoluminescent carbon dots for sensitive and selective detection of iron(III) , 2015 .

[13]  N. Zhu,et al.  Preparation of sludge-based activated carbon and its application in dye wastewater treatment. , 2008, Journal of hazardous materials.

[14]  Toyoko Imae,et al.  One-Pot Synthesis of Fluorescent Carbon Dots from Orange Waste Peels , 2013 .

[15]  D. Brasil,et al.  Surface Modification of Commercial Activated Carbon (CAG) for the Adsorption of Benzene and Toluene , 2015 .

[16]  C. Stoquart,et al.  Hybrid Membrane Processes using activated carbon treatment for drinking water: A review , 2012 .

[17]  Nikhil R. Jana,et al.  Carbon Nanoparticle-based Fluorescent Bioimaging Probes , 2013, Scientific Reports.

[18]  N. Adhoum,et al.  Modified activated carbon for the removal of copper, zinc, chromium and cyanide from wastewater , 2002 .

[19]  Xing Zhang,et al.  Ultra-sensitive and selective Hg2+ detection based on fluorescent carbon dots , 2013 .

[20]  H. Demiral Liquid Phase Adsorption of Phenol by Activated Carbon Derived From Hazelnut Bagasse , 2008 .

[21]  Jun-sheng Yu,et al.  Waste frying oil as a precursor for one-step synthesis of sulfur-doped carbon dots with pH-sensitive photoluminescence , 2014 .

[22]  Yi‐Jun Xu,et al.  Recent progress in carbon quantum dots: synthesis, properties and applications in photocatalysis , 2017 .

[23]  Jianrong Chen,et al.  Green preparation of carbon dots by Jinhua bergamot for sensitive and selective fluorescent detection of Hg2+ and Fe3+ , 2015 .

[24]  Shiguo Sun,et al.  Recent applications of carbon nanomaterials in fluorescence biosensing and bioimaging. , 2015, Chemical communications.

[25]  Jianji Wang,et al.  Simple and green synthesis of nitrogen-, sulfur-, and phosphorus-co-doped carbon dots with tunable luminescence properties and sensing application , 2014 .

[26]  Weijian Liu,et al.  The selectivity of the carboxylate groups terminated carbon dots switched by buffer solutions for the detection of multi-metal ions , 2017 .

[27]  Jian-Rong Zhang,et al.  Hair fiber as a precursor for synthesizing of sulfur- and nitrogen-co-doped carbon dots with tunable luminescence properties , 2013 .

[28]  K. Roh,et al.  Hierarchically structured activated carbon for ultracapacitors , 2016, Scientific Reports.

[29]  Su Yikun,et al.  Acidophilic S-doped carbon quantum dots derived from cellulose fibers and their fluorescence sensing performance for metal ions in an extremely strong acid environment , 2016 .

[30]  J. Mota,et al.  Adsorption of natural gas and biogas components on activated carbon , 2008 .