Superhydrophobic surfaces fabricated by microstructuring of stainless steel using a femtosecond laser

Fabrication of superhydrophobic surfaces induced by femtosecond laser is a research hotspot of superhydrophobic surface studies nowadays. We present a simple and easily-controlled method for fabricating stainless steel-based superhydrophobic surfaces. The method consists of microstructuring stainless steel surfaces by irradiating samples with femtosecond laser pulses and silanizing the surfaces. By low laser fluence, we fabricated typical laser-induced periodic surface structures (LIPSS) on the submicron level. The apparent contact angle (CA) on the surface is 150.3°. With laser fluence increasing, we fabricated periodic ripples and periodic cone-shaped spikes on the micron scale, both covered with LIPSS. The stainless steel-based surfaces with micro- and submicron double-scale structure have higher apparent CAs. On the surface of double-scale structure, the maximal apparent CA is 166.3° and at the same time, the sliding angle (SA) is 4.2°.

[1]  Xiaolong Wang,et al.  Superhydrophobic surface from Cu-Zn alloy by one step O2 concentration dependent etching. , 2008, Journal of colloid and interface science.

[2]  Zhiguang Guo,et al.  Effects of system parameters on making aluminum alloy lotus. , 2006, Journal of colloid and interface science.

[3]  R. N. Wenzel RESISTANCE OF SOLID SURFACES TO WETTING BY WATER , 1936 .

[4]  Jin Zhai,et al.  Super-hydrophobic surfaces: From natural to artificial , 2002 .

[5]  Qinmin Pan,et al.  Separating small amount of water and hydrophobic solvents by novel superhydrophobic copper meshes , 2008 .

[6]  K. Hashimoto,et al.  Binary cooperative complementary nanoscale interfacial materials , 2000 .

[7]  Robert N. Wenzel,et al.  Surface Roughness and Contact Angle. , 1949 .

[8]  Chunlei Guo,et al.  Femtosecond laser structuring of titanium implants , 2007 .

[9]  Masoud Farzaneh,et al.  Superhydrophobic properties of ultrathin rf-sputtered Teflon films coated etched aluminum surfaces , 2008 .

[10]  Shaojun Guo,et al.  Facile electrochemical approach to fabricate hierarchical flowerlike gold microstructures: Electrodeposited superhydrophobic surface , 2008 .

[11]  Feng Zhou,et al.  Superhydrophobic zinc oxide surface by differential etching and hydrophobic modification , 2007 .

[12]  Costas Fotakis,et al.  Biomimetic Artificial Surfaces Quantitatively Reproduce the Water Repellency of a Lotus Leaf , 2008 .

[13]  G McHale,et al.  Wetting and wetting transitions on copper-based super-hydrophobic surfaces. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[14]  Abraham Marmur,et al.  The Lotus effect: superhydrophobicity and metastability. , 2004, Langmuir : the ACS journal of surfaces and colloids.

[15]  Xiao Wei Sun,et al.  Femtosecond laser-induced periodic surface structure on ZnO , 2008 .

[16]  F. Shi,et al.  Combining layer-by-layer assembly with electrodeposition of silver aggregates for fabricating superhydrophobic surfaces. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[17]  Yasukiyo Ueda,et al.  The Lowest Surface Free Energy Based on −CF3 Alignment , 1999 .

[18]  Ching-yue Wang,et al.  The effect of femtosecond laser micromachining on the surface characteristics and subsurface microstructure of amorphous FeCuNbSiB alloy , 2006 .

[19]  X. Xia,et al.  Semiconductor supported biomimetic superhydrophobic gold surfaces by the galvanic exchange reaction [rapid communication] , 2006 .

[20]  Wei Song,et al.  Large-area unmodified superhydrophobic copper substrate can be prepared by an electroless replacement deposition. , 2009, Journal of colloid and interface science.

[21]  A. Fujishima,et al.  Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces , 2000 .

[22]  Jin Zhai,et al.  A lotus-leaf-like superhydrophobic surface: a porous microsphere/nanofiber composite film prepared by electrohydrodynamics. , 2004, Angewandte Chemie.

[23]  Hui Yan,et al.  Fabrication of superhydrophobic ZnO/Zn surface with nanowires and nanobelts structures using novel plasma assisted thermal vapor deposition , 2008 .

[24]  Lin Chen,et al.  Fabrication of Superhydrophobic Surfaces on Engineering Materials by a Solution‐Immersion Process , 2007 .

[25]  A Amirfazli,et al.  A thermodynamic approach for determining the contact angle hysteresis for superhydrophobic surfaces. , 2005, Journal of colloid and interface science.

[26]  Peter Englezos,et al.  Patterned superhydrophobic metallic surfaces. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[27]  D. He,et al.  Fabrication of superhydrophobic surfaces on engineering material surfaces with stearic acid , 2008 .

[28]  T. Young III. An essay on the cohesion of fluids , 1805, Philosophical Transactions of the Royal Society of London.

[29]  Costas Fotakis,et al.  Bio-inspired water repellent surfaces produced by ultrafast laser structuring of silicon , 2009 .

[30]  Qinmin Pan,et al.  Superhydrophobic surfaces based on dandelion-like ZnO microspheres , 2009 .

[31]  Bao-jia Li,et al.  Fabrication of titanium-based microstructured surfaces and study on their superhydrophobic stability , 2008 .

[32]  Lei Jiang,et al.  A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water. , 2004, Angewandte Chemie.