论文信息 - Syntheses and single-crystal structures of novel soluble phosphonato- and phosphinato-bridged titanium oxo alkoxides

Syntheses and single-crystal structures of novel soluble phosphonato- and phosphinato-bridged titanium oxo alkoxides

The reactions of PhP(O)(OH)2 or Ph2P(O)OH with Ti(OPri)4 in DMSO give the soluble tetranuclear complexes [Ti4(µ3-O)(OPri)5(µ-OPri)3(PhPO3)3]·DMSO 1 or [Ti(µ3-O)(OPri)(Ph2PO2)]4·0.5DMSO 2, the first examples of phosphonato- and phosphinato-bridged titanium oxo alkoxides, which have been characterised by single-crystal X-ray diffraction.

M. Mehring | P. Mutin | F. Dahan | A. Vioux | G. Guerrero

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