Third-order nonlinear optical response of enzothiazole derivative doped Polymethyl methacrylate C18H15N3SFe

In this paper one novel conjugated enzothiazole derivative doped Polymethyl methacrylate C18H15N3SFe with D-π-A structures were synthesized to realize reverse saturable absorption (RSA) under femtosecond laser excitation resulting from two-photon absorption (TPA) and TPA-induced excited-state absorption (TPA−ESA). we describe the linear and nonlinear optical (NLO) properties of enzothiazole derivative doped Polymethyl methacrylate C18H15N3SFe. The nonlinear absorption of Polymethyl methacrylate can be enhanced by enzothiazole derivative doped. The Z-scan results revealed that C18H15N3SFe/PMMA showed RSA on the femtosecond time regions (532 nm). All the results indicate show that C18H15N3SFe /PMMA are promising candidates for future optoelectronic and RSA applications.

[1]  C. Spangler Recent development in the design of organic materials for optical power limiting , 1999 .

[2]  P. S. Patil,et al.  Two-photon-induced excited-state absorption: Theory and experiment , 2008 .

[3]  H. Kasai,et al.  Design and synthesis of a new chromophore, 2-(4-nitrophenyl)benzofuran, for two-photon uncaging using near-IR light. , 2016, Chemical communications.

[4]  G. Umesh,et al.  Investigation of third-order nonlinear and optical power limiting properties of terphenyl derivatives , 2014 .

[5]  Yinglin Song,et al.  Ultrafast Broad-Band Optical Limiting in Simple Hydrazone Derivatives with a Π-Conjugated System: Effect of Two-Photon-Induced Singlet-State Absorption , 2018, The Journal of Physical Chemistry C.

[6]  Jean-Michel Nunzi,et al.  Multiphoton absorption in organic dye solutions , 1998 .

[7]  E. W. Stryland,et al.  Sensitive Measurement of Optical Nonlinearities Using a Single Beam Special 30th Anniversary Feature , 1990 .

[8]  Canbin Ouyang,et al.  Preparation of Main-Chain Polymers Based on Novel Monomers with D-π-A Structure for Application in Organic Second-Order Nonlinear Optical Materials with Good Long-Term Stability. , 2017, ACS applied materials & interfaces.

[9]  A. Jayarama,et al.  Growth, characterization and structural investigation of a novel nonlinear optical crystal , 2013 .

[10]  J. Zyss,et al.  Generation of high-peak-power tunable infrared femtosecond pulses in an organic crystal: application to time resolution of weak infrared signals , 1987 .

[11]  Yinglin Song,et al.  Direct observation of the transient thermal-lensing effect using the phase-object Z-scan technique. , 2009, Optics letters.