Assessing the Suitability of Biomass Ashes from Combustion in Boilers as Soil Fertilizers: Statistical Entropy Analysis and Introduction of the Potassium Utilization Potential Factor

Utilizing agricultural residues for energy and heating purposes is gaining momentum in the EU and even more in areas where biomass is a fundamental pillar of the economy like, e.g. South Tyrol in Northern Italy. In previous studies, the authors studied the combustion, in a commercial boiler of four different types of agricultural residues that were previously pelletized. This study has the scope to assess the suitability of the deriving biomass ashes as soil fertilizers. In this analysis potassium is identified as a key indicator for the nutrient content of biomass residue ashes. Therefore, this study introduces a new factor for assessing the utilization potential of biomass residues ashes, which is defined as the “potassium utilization potential factor” or KUP factor (with K representing potassium). The analysis is based on combining the initial concentration of potassium in the feedstock and the efficiency of statistical entropy. Statistical entropy analysis showed that combustion had a diverse substance concentrating efficiency of potassium for the four different types of biomass, ranging from 25 to 40%. In total, apple logs and apple pruning had the best performance in respect to their suitability as soil fertilizer since these feedstocks had the highest KUP factors.

[1]  Martin Kaltschmitt,et al.  Classification of Solid Biofuels as a Tool for Market Development , 2005 .

[2]  A. Nzihou,et al.  The fate of heavy metals during combustion and gasification of contaminated biomass-a brief review. , 2013, Journal of hazardous materials.

[3]  S. Mekhilef,et al.  A review on biomass as a fuel for boilers , 2011 .

[4]  Helmut Rechberger,et al.  A new, entropy based method to support waste and resource management decisions. , 2002, Environmental science & technology.

[5]  Fabrizio Mazzetto,et al.  Assessment of different feedstocks in South Tyrol (Northern Italy): Energy potential and suitability for domestic pellet boilers , 2016 .

[6]  T. Graedel,et al.  The contemporary European copper cycle: statistical entropy analysis , 2002 .

[7]  S. Orecchio,et al.  II) Wood pellets for home heating can be considered environmentally friendly fuels? Heavy metals determination by inductively coupled plasma-optical emission spectrometry (ICP-OES) in their ashes and the health risk assessment for the operators , 2016 .

[8]  Stefan Zerbe,et al.  Life cycle assessment of bioenergy production from orchards woody residues in Northern Italy , 2016 .

[9]  N. Scarlat,et al.  Assessment of the availability of agricultural crop residues in the European Union: potential and limitations for bioenergy use. , 2010, Waste management.

[10]  Lars J Nilsson,et al.  Assessment of the potential biomass supply in Europe using a resource-focused approach , 2004 .

[11]  Matthias Zessner,et al.  The Extension of Statistical Entropy Analysis to Chemical Compounds , 2012, Entropy.

[12]  J. Werther,et al.  Combustion of agricultural residues , 2000 .

[13]  E. Robert,et al.  Indirect Land Use Change From Increased Biofuels Demand - Comparison of Models and Results for Marginal Biofuels Production from Different Feedstocks , 2010 .

[14]  P. Jansens,et al.  Biomass combustion in fluidized bed boilers: Potential problems and remedies , 2009 .

[15]  Helmut Rechberger,et al.  Practical handbook of material flow analysis , 2003 .

[16]  K. Ericsson,et al.  The introduction and expansion of biomass use in Swedish district heating systems , 2016 .

[17]  Wei Xu,et al.  Information Entropy Evolution for Groundwater Flow System: A Case Study of Artificial Recharge in Shijiazhuang City, China , 2014, Entropy.

[18]  C. Lanzerstorfer Grate-Fired Biomass Combustion Plants Using Forest Residues as Fuel: Enrichment Factors for Components in the Fly Ash , 2016, Waste and biomass valorization.

[19]  Walter Haslinger,et al.  Performance of a pellet boiler fired with agricultural fuels , 2013 .

[20]  J. Catalão,et al.  Biomass combustion systems: A review on the physical and chemical properties of the ashes , 2016 .

[21]  Marco Baratieri,et al.  State-of-the-Art of Small Scale Biomass Gasifiers in the Region of South Tyrol , 2015 .