A ratiometric and colorimetric luminescent thermometer over a wide temperature range based on a lanthanide coordination polymer.

A lanthanide coordination polymer Tb0.957Eu0.043cpda was synthesized as a ratiometric and colorimetric luminescent thermometer. The high triplet excited state energy of a linker enables Tb0.957Eu0.043cpda to detect and visualize temperature over a wide range from cryogenic to room temperature (40-300 K).

[1]  L. Carlos,et al.  Lanthanide-based luminescent molecular thermometers , 2011 .

[2]  Yanfeng Yue,et al.  Luminescent functional metal-organic frameworks. , 2012, Chemical Reviews.

[3]  S. Chong,et al.  A guest-responsive fluorescent 3D microporous metal-organic framework derived from a long-lifetime pyrene core. , 2010, Journal of the American Chemical Society.

[4]  Zhiyong Guo,et al.  A luminescent mixed-lanthanide metal-organic framework thermometer. , 2012, Journal of the American Chemical Society.

[5]  Qiang Xu,et al.  Non-, micro-, and mesoporous metal-organic framework isomers: reversible transformation, fluorescence sensing, and large molecule separation. , 2010, Journal of the American Chemical Society.

[6]  M. Allendorf,et al.  Luminescent metal-organic frameworks. , 2009, Chemical Society reviews.

[7]  Zhiyu Wang,et al.  Second-order nonlinear optical activity induced by ordered dipolar chromophores confined in the pores of an anionic metal-organic framework. , 2012, Angewandte Chemie.

[8]  M. Dincǎ,et al.  Turn-on fluorescence in tetraphenylethylene-based metal-organic frameworks: an alternative to aggregation-induced emission. , 2011, Journal of the American Chemical Society.

[9]  J. Laird,et al.  Highly luminescent metal-organic frameworks through quantum dot doping. , 2012, Small.

[10]  Jian-Han Zhang,et al.  Luminescent lanthanide metal-organic frameworks with a large SHG response. , 2012, Chemical communications.

[11]  Qiang Xu,et al.  Porous metal-organic frameworks as platforms for functional applications. , 2011, Chemical communications.

[12]  Guodong Qian,et al.  Metal-organic frameworks with functional pores for recognition of small molecules. , 2010, Accounts of chemical research.

[13]  Francisco Sanz-Rodríguez,et al.  Temperature sensing using fluorescent nanothermometers. , 2010, ACS nano.

[14]  José A Fernandes,et al.  Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties. , 2013, Chemical communications.

[15]  Koen Binnemans,et al.  Lanthanide-based luminescent hybrid materials. , 2009, Chemical reviews.

[16]  Yu Yang,et al.  Luminescent Open Metal Sites within a Metal–Organic Framework for Sensing Small Molecules , 2007 .

[17]  Luís D Carlos,et al.  A Luminescent Molecular Thermometer for Long‐Term Absolute Temperature Measurements at the Nanoscale , 2010, Advanced materials.

[18]  Luís D. Carlos,et al.  Luminescent multifunctional lanthanides-based metal-organic frameworks. , 2011, Chemical Society reviews.

[19]  Guodong Qian,et al.  A luminescent microporous metal-organic framework for the recognition and sensing of anions. , 2008, Journal of the American Chemical Society.

[20]  Yuanjing Cui,et al.  Synthesis, Structures and Luminescent Properties of Two Coordination Polymers Based on 5‐(4‐Carboxyphenyl)‐2, 6‐Pyr­idinedicarboxylic Acid , 2013 .

[21]  Yi Wang,et al.  Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation. , 2012, Nature chemistry.

[22]  V. de Zea Bermudez,et al.  Progress on lanthanide-based organic-inorganic hybrid phosphors. , 2011, Chemical Society reviews.

[23]  Zhigang Xie,et al.  Porous phosphorescent coordination polymers for oxygen sensing. , 2010, Journal of the American Chemical Society.

[24]  Gregory S Harms,et al.  Upconverting nanoparticles for nanoscale thermometry. , 2011, Angewandte Chemie.

[25]  Shuangqing Wang,et al.  A triarylboron-based fluorescent thermometer: sensitive over a wide temperature range. , 2011, Angewandte Chemie.

[26]  Luís D Carlos,et al.  Thermometry at the nanoscale. , 2015, Nanoscale.

[27]  Yuanjing Cui,et al.  A luminescent metal-organic framework with Lewis basic pyridyl sites for the sensing of metal ions. , 2009, Angewandte Chemie.

[28]  Otto S. Wolfbeis,et al.  Luminescent Europium(III) Nanoparticles for Sensing and Imaging of Temperature in the Physiological Range , 2010, Advanced materials.